Influence of the Media on the Activation Parameters of the Chain Propagation Step in the Liquid Phase Oxidation of Methyl ... View Full Text


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Article Info

DATE

2001-05

AUTHORS

I. A. Opeida, A. F. Dmitruk, O. M. Zarechnaya

ABSTRACT

The effect of solvation on the activation parameters of the reaction RH + ROO· → R· + ROOH, where RH is methyl ethyl ketone, has been studied. The increased enthalpy of activation of this reaction in water is not a result of specific solvation of the peroxy radical but is non-specific effect of the solvent as a dielectric continuum. More... »

PAGES

185-188

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1011984422425

DOI

http://dx.doi.org/10.1023/a:1011984422425

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008596372


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