Polydentate coordination of the thallium atom in complexes with chiral amidinylcyclopentadienyl ligands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-05

AUTHORS

G. A. Dushenko, I. E. Mikhailov, G. Reck, B. Schulz, A. Zschunke, V. I. Minkin

ABSTRACT

The chiral thallium amidinium cyclopentadiene-N-ylide complexes [C5(CO2Me)4{ArNC(Ar")NAr}]Tl were synthesized and structurally characterized by X-ray diffraction analysis and NMR spectroscopy. In these complexes, an unusual mode of coordination of the thallium atom was found, viz., the thallium atom is coordinated by both the side-chain nitrogen atom (N—Tl, 2.833(6) Å) and the π system of the cyclopentadienyl ring (Tl—Cp, 2.887(4) Å η5-bonding). More... »

PAGES

890-894

Journal

TITLE

Russian Chemical Bulletin

ISSUE

5

VOLUME

50

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1011323629390

DOI

http://dx.doi.org/10.1023/a:1011323629390

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013938354


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