Ontology type: schema:ScholarlyArticle
2001-04
AUTHORSMaija Nissinen, Antonella Dalla Cort, Stefania Amabile, Luigi Mandolini, Kari Rissanen
ABSTRACTThe synthesis and structural characterisation of three new macrocyclicbis-phenol A cyclophane ethers are described. The solid state structuresof two of the cyclophanes were determined by single crystal X-raydiffraction. Cyclophane 3 crystallises in the orthorhombic spacegroup Pbca with unit cell dimensions of a = 11.533(7), b = 29.383(8),c = 14.927(8) Å and cyclophane 4 in the monoclinic spacegroup P21/n with cell dimensions of a = 11.585(4), b = 11.839(2), c = 18.866(2) Å, β = 94.48(2)°.The X-ray crystalstructures reveal distorted conformations, thus supporting the weak bindingof quats in solution observed by the NMR studies. In the crystalline state bothmacrocycles were found to form self-complementary dimers held together byweak intermolecular π-π and CH-π interactions. The bindingbehaviour towards a series of tetralkylammonium cations was determinedby 1H NMR titration in CDCl3 solution. The interactions between the hosts and the quats were clearly detectable but too weak to be translated into meaningful equilibrium constants. More... »
PAGES229-234
http://scigraph.springernature.com/pub.10.1023/a:1011174213426
DOIhttp://dx.doi.org/10.1023/a:1011174213426
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1016294391
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "University of Jyv\u00e4skyl\u00e4",
"id": "https://www.grid.ac/institutes/grid.9681.6",
"name": [
"Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, 40351, Jyv\u00e4skyl\u00e4, Finland."
],
"type": "Organization"
},
"familyName": "Nissinen",
"givenName": "Maija",
"id": "sg:person.0724142607.12",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0724142607.12"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Sapienza University of Rome",
"id": "https://www.grid.ac/institutes/grid.7841.a",
"name": [
"Dipartimento di Chimica and Centro CNR di Studio sui Meccanismi di Reazione, Universit\u00e1 La Sapienza, Roma 62, Box 34, 00185, Roma, Italy."
],
"type": "Organization"
},
"familyName": "Dalla Cort",
"givenName": "Antonella",
"id": "sg:person.012031354535.71",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012031354535.71"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Sapienza University of Rome",
"id": "https://www.grid.ac/institutes/grid.7841.a",
"name": [
"Dipartimento di Chimica and Centro CNR di Studio sui Meccanismi di Reazione, Universit\u00e1 La Sapienza, Roma 62, Box 34, 00185, Roma, Italy."
],
"type": "Organization"
},
"familyName": "Amabile",
"givenName": "Stefania",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Sapienza University of Rome",
"id": "https://www.grid.ac/institutes/grid.7841.a",
"name": [
"Dipartimento di Chimica and Centro CNR di Studio sui Meccanismi di Reazione, Universit\u00e1 La Sapienza, Roma 62, Box 34, 00185, Roma, Italy."
],
"type": "Organization"
},
"familyName": "Mandolini",
"givenName": "Luigi",
"id": "sg:person.0736176657.11",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0736176657.11"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Jyv\u00e4skyl\u00e4",
"id": "https://www.grid.ac/institutes/grid.9681.6",
"name": [
"Department of Chemistry, University of Jyv\u00e4skyl\u00e4, P.O. Box 35, 40351, Jyv\u00e4skyl\u00e4, Finland."
],
"type": "Organization"
},
"familyName": "Rissanen",
"givenName": "Kari",
"id": "sg:person.01234776006.79",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01234776006.79"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1002/bscb.19900990903",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001335632"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/bscb.19900990903",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001335632"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/chem.19970030515",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1013385981"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0040-4020(94)00918-k",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020692460"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0040-4020(95)00207-o",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024536560"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0040-4039(00)82259-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026017088"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja981338k",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037050210"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0040-4020(97)00185-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040057631"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0040-4020(97)00185-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040057631"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cr9603744",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054053330"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cr9603744",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054053330"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja00077a096",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055704901"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja01606a049",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055811748"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jo00130a037",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055968658"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jo9615108",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056036513"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jo9615108",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056036513"
],
"type": "CreativeWork"
}
],
"datePublished": "2001-04",
"datePublishedReg": "2001-04-01",
"description": "The synthesis and structural characterisation of three new macrocyclicbis-phenol A cyclophane ethers are described. The solid state structuresof two of the cyclophanes were determined by single crystal X-raydiffraction. Cyclophane 3 crystallises in the orthorhombic spacegroup Pbca with unit cell dimensions of a = 11.533(7), b = 29.383(8),c = 14.927(8) \u00c5 and cyclophane 4 in the monoclinic spacegroup P21/n with cell dimensions of a = 11.585(4), b = 11.839(2), c = 18.866(2) \u00c5, \u03b2 = 94.48(2)\u00b0.The X-ray crystalstructures reveal distorted conformations, thus supporting the weak bindingof quats in solution observed by the NMR studies. In the crystalline state bothmacrocycles were found to form self-complementary dimers held together byweak intermolecular \u03c0-\u03c0 and CH-\u03c0 interactions. The bindingbehaviour towards a series of tetralkylammonium cations was determinedby 1H NMR titration in CDCl3 solution. The interactions between the hosts and the quats were clearly detectable but too weak to be translated into meaningful equilibrium constants.",
"genre": "research_article",
"id": "sg:pub.10.1023/a:1011174213426",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1119385",
"issn": [
"1388-3127",
"2212-1765"
],
"name": "Journal of Inclusion Phenomena and Macrocyclic Chemistry",
"type": "Periodical"
},
{
"issueNumber": "3-4",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "39"
}
],
"name": "Bis-phenol A Cyclophanes: Synthesis, Crystal Structures and Binding Studies",
"pagination": "229-234",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"4da3b2674262368627c33641efce87fb9cf41369d6079a431c0f848b3d833bea"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1023/a:1011174213426"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1016294391"
]
}
],
"sameAs": [
"https://doi.org/10.1023/a:1011174213426",
"https://app.dimensions.ai/details/publication/pub.1016294391"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T19:06",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8678_00000499.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1023/A:1011174213426"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1011174213426'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1011174213426'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1011174213426'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1011174213426'
This table displays all metadata directly associated to this object as RDF triples.
127 TRIPLES
21 PREDICATES
39 URIs
19 LITERALS
7 BLANK NODES