Crystal and Molecular Structure of Platinum(II) trans-Bis-(1,1,1-trifluoro-4-iminopentan-2-onate) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-01

AUTHORS

I. A. Baidina, G. I. Zharkova, S. A. Gromilov

ABSTRACT

This paper describes a new method for the synthesis of the β-iminoketonate complex Pt(ktf)2 using 1,1,1-trifluoro-4-iminopentan-2-one as a bidentate ligand. An X-ray study has been performed on the polycrystals and single crystals of the compound. The single crystal X-ray diffraction analysis was carried out on a CAD-4 diffractometer (MoKα radiation, θ/2θ scan mode). Crystal data: a = 10.217(2), b = 10.231(2), c = 10.924(2) Å,α = 83.12(3), β = 63.38(3), γ = 70.77(3)°, V = 963.4(3) Å3, space group P1, Z = 2, dcalc = 1.721 g/cm3. The Pt atom has a distorted planar square environment; the average lengths of Pt–N and Pt–O coordination bonds coincide (1.97 Å). The mean value of the chelate angle is 94.2°. The environment of Pt is completed to bipyramid by the hydrogen atoms of the neighboring molecules. The structure of the compound is molecular. The differently oriented molecules of the complex are linked into chains down the x axis with Pt...Pt distances of 5.10 Å. A comparative crystal-chemical analysis of the structures of Pt(ktf)2 and Pd(ktf)2 and their O,O-chelate analogs — Pt(II) and Pd(II) trifluoroacetylacetonates — has been carried out. An X-ray study of Pt(tfa)2 and Pd(tfa)2 has been accomplished, and crystal data are given. More... »

PAGES

114-119

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1010432408608

DOI

http://dx.doi.org/10.1023/a:1010432408608

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009115794


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