Scientific Bases for the Synthesis of Highly Dispersed Framework Zirconium Phosphate Catalysts for Paraffin Isomerization and Selective Oxidation View Full Text


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Article Info

DATE

2001-05

AUTHORS

V. A. Sadykov, S. N. Pavlova, G. V. Zabolotnaya, M. V. Chaikina, R. I. Maksimovskaya, S. V. Tsybulya, E. B. Burgina, V. I. Zaikovskii, G. S. Litvak, Yu. V. Frolova, D. I. Kochubei, V. V. Kriventsov, E. A. Paukshtis, V. N. Kolomiichuk, V. V. Lunin, N. N. Kuznetsova, D. Agrawal, R. Roy

ABSTRACT

Results of the systematic study of the synthesis of highly dispersed framework zirconium phosphates stabilized by ammonium, lanthanum, aluminum, manganese, and cobalt cations are summarized. The synthesis involves the mechanochemical activation of a mixture of solid reactants (salts) or the sol–gel process each followed by the hydrothermal treatment (HTT) of obtained precursors in the presence of surfactants. The genesis of dispersed systems under investigation is studied by modern physical methods providing information on the state of the bulk and surface of the systems. It is found that the local structure of sol nanoparticles and zirconium phosphate crystalline nuclei arising from mechanochemical activation products depends on the nature of initial substances. This, in its turn, makes different crystallization mechanisms possible during the HTT process: the dissolution/precipitation mechanism or the mechanism of oriented mating of primary particles. The crystallization mechanism in HTT and the reaction system composition influence the nature of resulting complex zirconium phosphate phases, their thermal stability, dispersity, and porous structure parameters. The relationship between the bulk structure parameters of framework zirconium phosphates, which are controlled by varying the chemical composition and conditions of synthesis, and the surface characteristics of the systems (the strength and concentration of different Lewis and Br@nsted sites) is studied. It is shown that systems based on framework zirconium phosphates are promising catalysts for paraffin (pentane and hexane) isomerization, the selective oxidation of methane by oxygen into synthesis gas at short contact times, and the oxidative dehydrogenation of propane into propylene. More... »

PAGES

390-398

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1010421500856

DOI

http://dx.doi.org/10.1023/a:1010421500856

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051831959


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11 schema:description Results of the systematic study of the synthesis of highly dispersed framework zirconium phosphates stabilized by ammonium, lanthanum, aluminum, manganese, and cobalt cations are summarized. The synthesis involves the mechanochemical activation of a mixture of solid reactants (salts) or the sol–gel process each followed by the hydrothermal treatment (HTT) of obtained precursors in the presence of surfactants. The genesis of dispersed systems under investigation is studied by modern physical methods providing information on the state of the bulk and surface of the systems. It is found that the local structure of sol nanoparticles and zirconium phosphate crystalline nuclei arising from mechanochemical activation products depends on the nature of initial substances. This, in its turn, makes different crystallization mechanisms possible during the HTT process: the dissolution/precipitation mechanism or the mechanism of oriented mating of primary particles. The crystallization mechanism in HTT and the reaction system composition influence the nature of resulting complex zirconium phosphate phases, their thermal stability, dispersity, and porous structure parameters. The relationship between the bulk structure parameters of framework zirconium phosphates, which are controlled by varying the chemical composition and conditions of synthesis, and the surface characteristics of the systems (the strength and concentration of different Lewis and Br@nsted sites) is studied. It is shown that systems based on framework zirconium phosphates are promising catalysts for paraffin (pentane and hexane) isomerization, the selective oxidation of methane by oxygen into synthesis gas at short contact times, and the oxidative dehydrogenation of propane into propylene.
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18 schema:keywords HTT process
19 Highly
20 Synthesis of Highly
21 activation
22 activation products
23 aluminum
24 ammonium
25 basis
26 bulk
27 catalyst
28 cations
29 characteristics
30 chemical composition
31 cobalt cations
32 composition
33 conditions
34 conditions of synthesis
35 contact time
36 crystalline nuclei
37 crystallization mechanism
38 dehydrogenation
39 different crystallization mechanisms
40 dispersity
41 dissolution/precipitation mechanism
42 framework zirconium phosphates
43 gas
44 genesis
45 hydrothermal treatment
46 information
47 initial substances
48 investigation
49 isomerization
50 lanthanum
51 local structure
52 manganese
53 mating
54 mechanism
55 mechanochemical activation
56 methane
57 method
58 mixture
59 modern physical methods
60 nanoparticles
61 nature
62 nucleus
63 oxidation
64 oxidative dehydrogenation
65 oxygen
66 paraffin isomerization
67 parameters
68 particles
69 phase
70 phosphate
71 phosphate catalysts
72 phosphate phases
73 physical methods
74 porous structure parameters
75 precipitation mechanism
76 precursors
77 presence
78 presence of surfactants
79 primary particles
80 process
81 products
82 propane
83 propylene
84 reactants
85 reaction system composition
86 relationship
87 results
88 scientific basis
89 selective oxidation
90 short contact time
91 sol nanoparticles
92 solid reactants
93 sol–gel process
94 stability
95 state
96 structure
97 structure parameters
98 study
99 substances
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101 surface characteristics
102 surfactants
103 synthesis
104 synthesis gas
105 system
106 system composition
107 systematic study
108 thermal stability
109 time
110 treatment
111 turn
112 zirconium
113 zirconium phosphate
114 zirconium phosphate catalyst
115 schema:name Scientific Bases for the Synthesis of Highly Dispersed Framework Zirconium Phosphate Catalysts for Paraffin Isomerization and Selective Oxidation
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