Thermal Decomposition Kinetics of Some Metal Complexes of N,N-diethyl-n '-benzoylthiourea View Full Text


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Article Info

DATE

2000-09

AUTHORS

N. Ózpozan, H. Arslan, T. Ózpozan, M. Merdivan, N. Külcü

ABSTRACT

Thermogravimetry (TG) and differential thermal analysis (DTA) were performed on the complexes with general formula (M(DEBT)n (where M =Fe, Co, Ni, Cu or Ru; n =2, or 3 and DEBT=N,N-diethyl-N'-benzoylthiourea). Derivative thermogravimetric (DTG) curves were also recorded in order to obtain decomposition data on the complexes. The complexes of Fe(III), Co(II), Ni(II), Cu(II) and Ru(III) displayed two- or three-stage decomposition patterns when heated in a dynamic nitrogen atmosphere. Mass loss considerations relating to the decomposition stages indicated the conversion of the complexes to the sulfides or to the corresponding metal alone (Cu, Ru, NiS, CoS or FeS). Mathematical analysis of the TG and DTG data showed that the order of reaction varied between 0.395 and 0.973. Kinetic parameters such as the decomposition energy, the entropy of activation and the pre-exponential factor are reported. More... »

PAGES

955-965

References to SciGraph publications

  • 1989-11. Kinetic analysis of thermogravimetric data on some nickel(II) N-alkyldithiocarbamates in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1964-01. Kinetic Parameters from Thermogravimetric Data in NATURE
  • 1990-01. The chromatography of metal chelates in JOURNAL OF ANALYTICAL CHEMISTRY
  • 1984-01. Zur Chromatographie von Metallchelaten in ANALYTICAL AND BIOANALYTICAL CHEMISTRY
  • 1992-10. Selective complexing agents for the trace enrichment of platinum metals in JOURNAL OF ANALYTICAL CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1023/a:1010171230450

    DOI

    http://dx.doi.org/10.1023/a:1010171230450

    DIMENSIONS

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