Thermally Stimulated Current Spectroscopy of Amorphous and Semi-Crystalline Polymers View Full Text


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Article Info

DATE

1999-11

AUTHORS

C. Bacharan, C. Dessaux, A. Bernès, C. Lacabanne

ABSTRACT

Thermally Stimulated Current (TSC) spectrometry has been applied to the characterization of polymeric materials. The study of a series of amorphous polymers having different physical structures has shown that the compensation parameters are independent of physical aging; contrarily, the activation enthalpy distribution reflects the evolution of the heterogeneity of the amorphous phase. In copolymers, TSC allows us to identify segregated amorphous phases. In semi-crystalline polymers, with semi-rigid chains, we have shown the existence of an amorphous crystalline interphase characterized by a plateau in the temperature distribution of activation enthalpy. More... »

PAGES

969-982

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Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1010111819229

DOI

http://dx.doi.org/10.1023/a:1010111819229

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020173084


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