Gravimetric And Quantum-chemical Study of Interaction of Monoethanolamine Vapor With Silica Surface View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-11

AUTHORS

V. V. Lobanov, A. A. Chuiko, N. A. Burlaenko, V. E. Klymenko, V. A. Tertykh, V. V. Yanishpolskii, M. I. Teretz

ABSTRACT

Kinetics of the monoethanolamine vapor adsorption on the surface of silica previously deposited onto quartz plate was examined by the piezoelectric microweighing. With the assumptions which are in accord with the experimental data, the kinetic equation of the process was obtained and thus the adsorption and desorption constants were found. The structure of the possible adsorption complexes was studied in the framework of the quantum-chemical MNDO method and the conclusion was made that the two-center adsorption of the monoethanolamine on the silica surface proceeds as a two-stage process with the participation of both functional groups. The bonding is mainly effected owing to the proton-acceptor properties of amine groups. More... »

PAGES

381-387

References to SciGraph publications

  • 1959-04. Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung in ZEITSCHRIFT FÜR PHYSIK A HADRONS AND NUCLEI
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1023/a:1010109309014

    DOI

    http://dx.doi.org/10.1023/a:1010109309014

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1027847796


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine", 
              "id": "http://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Lobanov", 
            "givenName": "V. V.", 
            "id": "sg:person.016020327543.29", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016020327543.29"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine", 
              "id": "http://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chuiko", 
            "givenName": "A. A.", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "L. V. Pisarzhevski Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine", 
              "id": "http://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "L. V. Pisarzhevski Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Burlaenko", 
            "givenName": "N. A.", 
            "id": "sg:person.013243774044.91", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013243774044.91"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine", 
              "id": "http://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Klymenko", 
            "givenName": "V. E.", 
            "id": "sg:person.012525542477.84", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012525542477.84"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine", 
              "id": "http://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Tertykh", 
            "givenName": "V. A.", 
            "id": "sg:person.051071574.49", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.051071574.49"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine", 
              "id": "http://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Yanishpolskii", 
            "givenName": "V. V.", 
            "id": "sg:person.013355164027.97", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013355164027.97"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine", 
              "id": "http://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Teretz", 
            "givenName": "M. I.", 
            "id": "sg:person.011321030164.03", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011321030164.03"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf01337937", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018027660", 
              "https://doi.org/10.1007/bf01337937"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2000-11", 
        "datePublishedReg": "2000-11-01", 
        "description": "Kinetics of the monoethanolamine vapor adsorption on the surface of silica previously deposited onto quartz plate was examined by the piezoelectric microweighing. With the assumptions which are in accord with the experimental data, the kinetic equation of the process was obtained and thus the adsorption and desorption constants were found. The structure of the possible adsorption complexes was studied in the framework of the quantum-chemical MNDO method and the conclusion was made that the two-center adsorption of the monoethanolamine on the silica surface proceeds as a two-stage process with the participation of both functional groups. The bonding is mainly effected owing to the proton-acceptor properties of amine groups.", 
        "genre": "article", 
        "id": "sg:pub.10.1023/a:1010109309014", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1294862", 
            "issn": [
              "1388-6150", 
              "1572-8943"
            ], 
            "name": "Journal of Thermal Analysis and Calorimetry", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "2", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "62"
          }
        ], 
        "keywords": [
          "quantum-chemical MNDO method", 
          "proton-acceptor properties", 
          "quantum chemical study", 
          "silica surface proceeds", 
          "surface of silica", 
          "adsorption complexes", 
          "silica surface", 
          "amine groups", 
          "surface proceeds", 
          "functional groups", 
          "vapor adsorption", 
          "MNDO method", 
          "piezoelectric microweighing", 
          "adsorption", 
          "quartz plate", 
          "desorption constants", 
          "gravimetric", 
          "kinetic equation", 
          "surface", 
          "two-stage process", 
          "bonding", 
          "silica", 
          "monoethanolamine", 
          "complexes", 
          "kinetics", 
          "experimental data", 
          "constants", 
          "vapor", 
          "proceeds", 
          "properties", 
          "structure", 
          "interaction", 
          "process", 
          "accord", 
          "group", 
          "method", 
          "study", 
          "framework", 
          "plate", 
          "equations", 
          "data", 
          "participation", 
          "conclusion", 
          "assumption"
        ], 
        "name": "Gravimetric And Quantum-chemical Study of Interaction of Monoethanolamine Vapor With Silica Surface", 
        "pagination": "381-387", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1027847796"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1023/a:1010109309014"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1023/a:1010109309014", 
          "https://app.dimensions.ai/details/publication/pub.1027847796"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-08-04T16:53", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_342.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1023/a:1010109309014"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1010109309014'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1010109309014'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1010109309014'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1010109309014'


     

    This table displays all metadata directly associated to this object as RDF triples.

    148 TRIPLES      21 PREDICATES      70 URIs      61 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1023/a:1010109309014 schema:about anzsrc-for:03
    2 anzsrc-for:0306
    3 schema:author Naec4df1fcc85408c885efabc9f95dad3
    4 schema:citation sg:pub.10.1007/bf01337937
    5 schema:datePublished 2000-11
    6 schema:datePublishedReg 2000-11-01
    7 schema:description Kinetics of the monoethanolamine vapor adsorption on the surface of silica previously deposited onto quartz plate was examined by the piezoelectric microweighing. With the assumptions which are in accord with the experimental data, the kinetic equation of the process was obtained and thus the adsorption and desorption constants were found. The structure of the possible adsorption complexes was studied in the framework of the quantum-chemical MNDO method and the conclusion was made that the two-center adsorption of the monoethanolamine on the silica surface proceeds as a two-stage process with the participation of both functional groups. The bonding is mainly effected owing to the proton-acceptor properties of amine groups.
    8 schema:genre article
    9 schema:isAccessibleForFree false
    10 schema:isPartOf N84f30c12d0b943afa4b9c28f4261f346
    11 N9d60b7b2095a4118a8d67bac701fc6da
    12 sg:journal.1294862
    13 schema:keywords MNDO method
    14 accord
    15 adsorption
    16 adsorption complexes
    17 amine groups
    18 assumption
    19 bonding
    20 complexes
    21 conclusion
    22 constants
    23 data
    24 desorption constants
    25 equations
    26 experimental data
    27 framework
    28 functional groups
    29 gravimetric
    30 group
    31 interaction
    32 kinetic equation
    33 kinetics
    34 method
    35 monoethanolamine
    36 participation
    37 piezoelectric microweighing
    38 plate
    39 proceeds
    40 process
    41 properties
    42 proton-acceptor properties
    43 quantum chemical study
    44 quantum-chemical MNDO method
    45 quartz plate
    46 silica
    47 silica surface
    48 silica surface proceeds
    49 structure
    50 study
    51 surface
    52 surface of silica
    53 surface proceeds
    54 two-stage process
    55 vapor
    56 vapor adsorption
    57 schema:name Gravimetric And Quantum-chemical Study of Interaction of Monoethanolamine Vapor With Silica Surface
    58 schema:pagination 381-387
    59 schema:productId N279bb018cfce4b7ba4a31f6bd31cb4d4
    60 N989d390723b447c8b15946d5bca4dc81
    61 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027847796
    62 https://doi.org/10.1023/a:1010109309014
    63 schema:sdDatePublished 2022-08-04T16:53
    64 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    65 schema:sdPublisher Nd8020a794cc2465799815c457d87154c
    66 schema:url https://doi.org/10.1023/a:1010109309014
    67 sgo:license sg:explorer/license/
    68 sgo:sdDataset articles
    69 rdf:type schema:ScholarlyArticle
    70 N279bb018cfce4b7ba4a31f6bd31cb4d4 schema:name dimensions_id
    71 schema:value pub.1027847796
    72 rdf:type schema:PropertyValue
    73 N32ac752e11014e3bbc855e1a6c5ca44d rdf:first sg:person.012525542477.84
    74 rdf:rest Nb1f5cb25b7fb488ebcf1fc64a0a25b8e
    75 N61c44b1962d241ae8649d0e2837df85d rdf:first sg:person.013243774044.91
    76 rdf:rest N32ac752e11014e3bbc855e1a6c5ca44d
    77 N7045437266be4f9ca86360becac49cc8 rdf:first sg:person.011321030164.03
    78 rdf:rest rdf:nil
    79 N84f30c12d0b943afa4b9c28f4261f346 schema:issueNumber 2
    80 rdf:type schema:PublicationIssue
    81 N989d390723b447c8b15946d5bca4dc81 schema:name doi
    82 schema:value 10.1023/a:1010109309014
    83 rdf:type schema:PropertyValue
    84 N9d60b7b2095a4118a8d67bac701fc6da schema:volumeNumber 62
    85 rdf:type schema:PublicationVolume
    86 N9efc260c44b2491db91640c1d3ae7540 schema:affiliation grid-institutes:grid.418751.e
    87 schema:familyName Chuiko
    88 schema:givenName A. A.
    89 rdf:type schema:Person
    90 Naec4df1fcc85408c885efabc9f95dad3 rdf:first sg:person.016020327543.29
    91 rdf:rest Nb89140877c5c446897dddc9040a954a4
    92 Nb1f5cb25b7fb488ebcf1fc64a0a25b8e rdf:first sg:person.051071574.49
    93 rdf:rest Nd862288c35e94be5a68b03ba704e635e
    94 Nb89140877c5c446897dddc9040a954a4 rdf:first N9efc260c44b2491db91640c1d3ae7540
    95 rdf:rest N61c44b1962d241ae8649d0e2837df85d
    96 Nd8020a794cc2465799815c457d87154c schema:name Springer Nature - SN SciGraph project
    97 rdf:type schema:Organization
    98 Nd862288c35e94be5a68b03ba704e635e rdf:first sg:person.013355164027.97
    99 rdf:rest N7045437266be4f9ca86360becac49cc8
    100 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    101 schema:name Chemical Sciences
    102 rdf:type schema:DefinedTerm
    103 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    104 schema:name Physical Chemistry (incl. Structural)
    105 rdf:type schema:DefinedTerm
    106 sg:journal.1294862 schema:issn 1388-6150
    107 1572-8943
    108 schema:name Journal of Thermal Analysis and Calorimetry
    109 schema:publisher Springer Nature
    110 rdf:type schema:Periodical
    111 sg:person.011321030164.03 schema:affiliation grid-institutes:grid.418751.e
    112 schema:familyName Teretz
    113 schema:givenName M. I.
    114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011321030164.03
    115 rdf:type schema:Person
    116 sg:person.012525542477.84 schema:affiliation grid-institutes:grid.418751.e
    117 schema:familyName Klymenko
    118 schema:givenName V. E.
    119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012525542477.84
    120 rdf:type schema:Person
    121 sg:person.013243774044.91 schema:affiliation grid-institutes:grid.418751.e
    122 schema:familyName Burlaenko
    123 schema:givenName N. A.
    124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013243774044.91
    125 rdf:type schema:Person
    126 sg:person.013355164027.97 schema:affiliation grid-institutes:grid.418751.e
    127 schema:familyName Yanishpolskii
    128 schema:givenName V. V.
    129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013355164027.97
    130 rdf:type schema:Person
    131 sg:person.016020327543.29 schema:affiliation grid-institutes:grid.418751.e
    132 schema:familyName Lobanov
    133 schema:givenName V. V.
    134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016020327543.29
    135 rdf:type schema:Person
    136 sg:person.051071574.49 schema:affiliation grid-institutes:grid.418751.e
    137 schema:familyName Tertykh
    138 schema:givenName V. A.
    139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.051071574.49
    140 rdf:type schema:Person
    141 sg:pub.10.1007/bf01337937 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018027660
    142 https://doi.org/10.1007/bf01337937
    143 rdf:type schema:CreativeWork
    144 grid-institutes:grid.418751.e schema:alternateName Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine
    145 L. V. Pisarzhevski Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine
    146 schema:name Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine
    147 L. V. Pisarzhevski Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauki 31, 03039, Kyiv, Ukraine
    148 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...