Separation of rosin acids by molecular recognition: crystal structure of the complex of neoabietic acid with 2-amino-6-methyl-pyridine View Full Text


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Article Info

DATE

2000-03

AUTHORS

Zhimin Jin, Yuanjiang Pan, Jiageng Liu, Duanjun Xu

ABSTRACT

Neoabietic acid has been separated from gum rosin mixture by the aid of molecular recognition using 2-amino-6-methyl-pyridine as recognition reagent. The complex of neoabietic acid with 2-amino-6-methy-pyridine crystallizes from ether solution in the monoclinic, space group P21 with cell parameters of a = 7.370(1), b = 8.692(1), c = 18.365(2) Å, β = 92.53(1)°,V = 1175.3(2) Å3 and Z = 2. X-ray structure analysis shows that an extensive H-bonding network exists between neoabietic acid and amino(methyl)pyridine, which is considered as one of the factors resulting in successfully separating the neoabietic acid from the gum rosin mixture. More... »

PAGES

195-198

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1009587232221

DOI

http://dx.doi.org/10.1023/a:1009587232221

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039414790


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