X-ray diffraction structure of the phosphido-bridged mixed-metal cluster Fe2(CO)6(μ3-PPh)2Pt(dppe) View Full Text


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Article Info

DATE

2000-04

AUTHORS

William H. Watson, Ante Nagl, Ming-Jaw Don, Michael G. Richmond

ABSTRACT

Treatment of Fe2(CO)6(μ2-PPhH)2 with BuLi (2 equiv.), followed by the addition of PtCl2 (dppe), affords the phosphido-bridged cluster Fe2(CO)6(μ3-PPh)2Pt(dppe). The Fe2Pt cluster was isolated and characterized in solution by IR and 31P NMR spectroscopy, and the molecular structure of Fe2(CO)6(μ3-PPh)2Pt(dppe) determined by X-ray diffraction analysis. Fe2(CO)6(μ3-PPh)2Pt(dppe) crystallizes in the orthorhombic space group Pbca, a = 17.539(3) Å, b = 21.490(2) Å, c = 22.959(3) Å, V = 8653.5(18) Å3, Z = 8, dcalc = 1.670 g cm−3; R = 0.0644, Rw = 0.0389 for 5040 observed reflections with I > 3σ(I). More... »

PAGES

233-236

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1009586921599

DOI

http://dx.doi.org/10.1023/a:1009586921599

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046245150


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