NMR Spectra of Guest–Host Complexes of Boron and Silicon Fluorides with Crown Ethers in Nonaqueous Solutions View Full Text


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Article Info

DATE

2001-03

AUTHORS

V. O. Gel'mbol'dt, G. Selig, E. V. Ganin, M. S. Fonar', A. A. Ennan

ABSTRACT

19F, 11B, and 29Si NMR spectroscopy was used to examine the behavior of the guest–host complexes (BF3· H2O)2· 18-crown-6 · 2H2O, (BF3· H2O)2· DCH-6B, and (DCH-6A · H3O)SiF5in acetone (DCH-6B and DCH-6A are the cis-anti-cis- and cis-syn-cis-isomers of dicyclohexano-18-crown-6, respectively). It was shown that molecular boron fluoride complexes undergo partial solvolysis in acetone to yield BF3· acetone as the main product; the ionic pentafluorosilicate complex does not experience significant solvolysis transformations. More... »

PAGES

150-151

References to SciGraph publications

  • 1992-06. Synthesis and structure of (H2O·HBF4)2(18-crown-6) in JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
  • 1991-01. Stabilization of H2O ⁗ BF3 by hydrogen bonding to 18-crown-6 in JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
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    http://scigraph.springernature.com/pub.10.1023/a:1009585925859

    DOI

    http://dx.doi.org/10.1023/a:1009585925859

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