Crystal structure of 2,6-dimethylpyridinium hydrogen phthalate View Full Text


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Article Info

DATE

2000-02

AUTHORS

Zhi Min Jin, Yuan Jiang Pan, Duan Jun Xu, Yuan Zhi Xu

ABSTRACT

A new crystal of 2,6-dimethylpyridinium hydrogen phthalate (DPMHP) has been prepared and characterized by x-ray crystallography. DPMHP crystallizes in the monoclinic space group C2/c with a = 26.105(3), b = 8.2250(10), c = 13.8750(10) Å, β = 116.02(1)°, V = 2677.2(5) Å3, and Z = 8. The 2,6-dimethylpyridinium (DPM) is held with the hydrogen phthalate ion (HPI) by intermolecular hydrogen bond of N-H-O. A noncentered hydrogen atom is involved in the short intramolecular hydrogen of O-O [2.398(2) Å] between the neighboring carboxylic groups. The phenyl ring of the HPI appears to be deformed in comparison with the original. The entity of HPI in itself and DMPMHP as a whole are arranged in a rumple pattern. The geometrical arrangement in the crystal structure is characterized by the formation of laminar ribbons of DPMHP. More... »

PAGES

119-122

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1009521729823

DOI

http://dx.doi.org/10.1023/a:1009521729823

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003310609


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