Molecular structure of P-(2,4,6-tri-tert-buthylphenyl)-phenylmethylene(phenylsulfonylimino)-σ3λ5-phosphorane View Full Text


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Article Info

DATE

1999-12

AUTHORS

Eduard B. Rusanov, Alexander N. Chernega, Mark I. Povolotskii

ABSTRACT

The crystal and molecular structure of P-(2,4,6-tri-tert-buthylphenyl)-phenylmethylene (phenylsulfonylimino)-σ3λ5-phosphorane, 2,4,6-But3-C6H2-P(=CHPh)(=N--SO2Ph), has been determined. Crystal data: triclinic, \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$P\bar 1$$ \end{document}, a = 9.472(5), b = 11.427(5), c = 13.684(5) Å, α = 90.61(3), β = 101.21(4), γ = 97.02(4)°, V = 1441.1 Å3, Z = 2, Dc = 1.20 g cm−3. The observed in 1 noticeable elongation of the P=N bond 1.563(3) Å and shortening of the P=C bond 1.617(3)Å have been discussed in terms of the electron withdrawing ability of substituents on the basis of ab initio (HF/6−31+G**) calculations of the model systems. More... »

PAGES

1277-1280

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1009509024333

DOI

http://dx.doi.org/10.1023/a:1009509024333

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005186901


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