Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-03

AUTHORS

Stephen J. Archibald, Nathaniel W. Alcock, Daryle H. Busch, David R. Whitcomb

ABSTRACT

N,N′−Diphenylamidines and the silver(I) complexes of their deprotonated anions have been synthesized. Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring resulted in a cationic silver trimer in which hydrogen bonding links silver(I)-bound water molecules to the methoxy substituents. The thermal stabilities of the tetrameric species vary with alkyl chain length. The new complexes are: tetrakis(N,N′-diphenylpropamidinato) tetra silver(I), 1, tetrakis(N,N′-diphenylbutamidinato) tetrasilver(I) 2, tetrakis(N,N′-diphenylpentamidinato) tetra silver(I) 3, (N,N′-diphenyloctamidinato)silver(I) 4, (tetrakis(N,N′-di(4-n-butyl)phenylpropamidinato)tetrasilver(I), 5, bis(N,N′-di(2-methoxy)phenylacetamidinato)diaquatrisilver(I) nitrate 6 and tetrakis(N,N′-di(4-methoxy)phenylacetamidinato) tetrasilver(I), 7. Compounds 1, 5, 6 and 7 were structurally characterized by X-ray methods. More... »

PAGES

261-283

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1009085319864

DOI

http://dx.doi.org/10.1023/a:1009085319864

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043760923


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of Kansas, 66045, Lawrence, KS, USA", 
          "id": "http://www.grid.ac/institutes/grid.266515.3", 
          "name": [
            "Department of Chemistry, University of Kansas, 66045, Lawrence, KS, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Archibald", 
        "givenName": "Stephen J.", 
        "id": "sg:person.01272127236.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01272127236.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of Warwick, CV4 7AL, Coventry, UK", 
          "id": "http://www.grid.ac/institutes/grid.7372.1", 
          "name": [
            "Department of Chemistry, University of Warwick, CV4 7AL, Coventry, UK"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Alcock", 
        "givenName": "Nathaniel W.", 
        "id": "sg:person.01145137433.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01145137433.39"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of Kansas, 66045, Lawrence, KS, USA", 
          "id": "http://www.grid.ac/institutes/grid.266515.3", 
          "name": [
            "Department of Chemistry, University of Kansas, 66045, Lawrence, KS, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Busch", 
        "givenName": "Daryle H.", 
        "id": "sg:person.016233633116.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016233633116.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Dry Media Systems Laboratory, Imation Corporation, 55144, St Paul, MN, USA", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Dry Media Systems Laboratory, Imation Corporation, 55144, St Paul, MN, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Whitcomb", 
        "givenName": "David R.", 
        "id": "sg:person.015262263463.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015262263463.15"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2000-03", 
    "datePublishedReg": "2000-03-01", 
    "description": "N,N\u2032\u2212Diphenylamidines and the silver(I) complexes of their deprotonated anions have been synthesized. Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring resulted in a cationic silver trimer in which hydrogen bonding links silver(I)-bound water molecules to the methoxy substituents. The thermal stabilities of the tetrameric species vary with alkyl chain length. The new complexes are: tetrakis(N,N\u2032-diphenylpropamidinato) tetra silver(I), 1, tetrakis(N,N\u2032-diphenylbutamidinato) tetrasilver(I) 2, tetrakis(N,N\u2032-diphenylpentamidinato) tetra silver(I) 3, (N,N\u2032-diphenyloctamidinato)silver(I) 4, (tetrakis(N,N\u2032-di(4-n-butyl)phenylpropamidinato)tetrasilver(I), 5, bis(N,N\u2032-di(2-methoxy)phenylacetamidinato)diaquatrisilver(I) nitrate 6 and tetrakis(N,N\u2032-di(4-methoxy)phenylacetamidinato) tetrasilver(I), 7. Compounds 1, 5, 6 and 7 were structurally characterized by X-ray methods.", 
    "genre": "article", 
    "id": "sg:pub.10.1023/a:1009085319864", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1130720", 
        "issn": [
          "1040-7278", 
          "1572-8862"
        ], 
        "name": "Journal of Cluster Science", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "11"
      }
    ], 
    "keywords": [
      "hydrogen bonding links", 
      "alkyl chain length", 
      "new complexes", 
      "water molecules", 
      "deprotonated anions", 
      "bonding links", 
      "functional groups", 
      "alkyl substituents", 
      "methoxy substituents", 
      "chain length", 
      "phenyl ring", 
      "silver trimer", 
      "tetrameric species", 
      "structural motifs", 
      "thermal stability", 
      "substituents", 
      "tetra", 
      "complexes", 
      "anions", 
      "molecules", 
      "trimer", 
      "carbon", 
      "ns", 
      "ring", 
      "stability", 
      "species", 
      "motif", 
      "addition", 
      "group", 
      "length", 
      "inclusion", 
      "link"
    ], 
    "name": "Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N\u2032-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs", 
    "pagination": "261-283", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1043760923"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1009085319864"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1009085319864", 
      "https://app.dimensions.ai/details/publication/pub.1043760923"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:21", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_322.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1023/a:1009085319864"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1009085319864'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1009085319864'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1009085319864'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1009085319864'


 

This table displays all metadata directly associated to this object as RDF triples.

117 TRIPLES      21 PREDICATES      58 URIs      50 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1009085319864 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author Na85b0ec9747845d1ae48a5f8c9257ecd
4 schema:datePublished 2000-03
5 schema:datePublishedReg 2000-03-01
6 schema:description N,N′−Diphenylamidines and the silver(I) complexes of their deprotonated anions have been synthesized. Previously uncharacterized tetrameric structural motifs were produced by the inclusion of alkyl substituents at the amidinate carbon. The addition of a 2-methoxy functional group to the phenyl ring resulted in a cationic silver trimer in which hydrogen bonding links silver(I)-bound water molecules to the methoxy substituents. The thermal stabilities of the tetrameric species vary with alkyl chain length. The new complexes are: tetrakis(N,N′-diphenylpropamidinato) tetra silver(I), 1, tetrakis(N,N′-diphenylbutamidinato) tetrasilver(I) 2, tetrakis(N,N′-diphenylpentamidinato) tetra silver(I) 3, (N,N′-diphenyloctamidinato)silver(I) 4, (tetrakis(N,N′-di(4-n-butyl)phenylpropamidinato)tetrasilver(I), 5, bis(N,N′-di(2-methoxy)phenylacetamidinato)diaquatrisilver(I) nitrate 6 and tetrakis(N,N′-di(4-methoxy)phenylacetamidinato) tetrasilver(I), 7. Compounds 1, 5, 6 and 7 were structurally characterized by X-ray methods.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N37eb5f891a0b4f42959910c7053a8f56
11 N844cb878fd444e449fac09086117ae17
12 sg:journal.1130720
13 schema:keywords addition
14 alkyl chain length
15 alkyl substituents
16 anions
17 bonding links
18 carbon
19 chain length
20 complexes
21 deprotonated anions
22 functional groups
23 group
24 hydrogen bonding links
25 inclusion
26 length
27 link
28 methoxy substituents
29 molecules
30 motif
31 new complexes
32 ns
33 phenyl ring
34 ring
35 silver trimer
36 species
37 stability
38 structural motifs
39 substituents
40 tetra
41 tetrameric species
42 thermal stability
43 trimer
44 water molecules
45 schema:name Synthesis and Characterization of Silver(I) Complexes with C-Alkyl Functionalized N,N′-Diphenylamidinates: Tetrameric and Trimeric Structural Motifs
46 schema:pagination 261-283
47 schema:productId Ncab04fb2cea740acae71d30b3694998c
48 Nf75feaf41909412a981513f3635e9008
49 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043760923
50 https://doi.org/10.1023/a:1009085319864
51 schema:sdDatePublished 2022-05-20T07:21
52 schema:sdLicense https://scigraph.springernature.com/explorer/license/
53 schema:sdPublisher N130ad2035f284e6fa06b0430c467dd51
54 schema:url https://doi.org/10.1023/a:1009085319864
55 sgo:license sg:explorer/license/
56 sgo:sdDataset articles
57 rdf:type schema:ScholarlyArticle
58 N130ad2035f284e6fa06b0430c467dd51 schema:name Springer Nature - SN SciGraph project
59 rdf:type schema:Organization
60 N37eb5f891a0b4f42959910c7053a8f56 schema:volumeNumber 11
61 rdf:type schema:PublicationVolume
62 N7e84f8de39ff4491ba39be2a66627ae8 rdf:first sg:person.015262263463.15
63 rdf:rest rdf:nil
64 N844cb878fd444e449fac09086117ae17 schema:issueNumber 1
65 rdf:type schema:PublicationIssue
66 Na85b0ec9747845d1ae48a5f8c9257ecd rdf:first sg:person.01272127236.47
67 rdf:rest Nf9790fdd43d14dd2808fa2286e8dd882
68 Nc7136e56d6a3465eb71ea54cacc23d5f rdf:first sg:person.016233633116.55
69 rdf:rest N7e84f8de39ff4491ba39be2a66627ae8
70 Ncab04fb2cea740acae71d30b3694998c schema:name dimensions_id
71 schema:value pub.1043760923
72 rdf:type schema:PropertyValue
73 Nf75feaf41909412a981513f3635e9008 schema:name doi
74 schema:value 10.1023/a:1009085319864
75 rdf:type schema:PropertyValue
76 Nf9790fdd43d14dd2808fa2286e8dd882 rdf:first sg:person.01145137433.39
77 rdf:rest Nc7136e56d6a3465eb71ea54cacc23d5f
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
82 schema:name Inorganic Chemistry
83 rdf:type schema:DefinedTerm
84 sg:journal.1130720 schema:issn 1040-7278
85 1572-8862
86 schema:name Journal of Cluster Science
87 schema:publisher Springer Nature
88 rdf:type schema:Periodical
89 sg:person.01145137433.39 schema:affiliation grid-institutes:grid.7372.1
90 schema:familyName Alcock
91 schema:givenName Nathaniel W.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01145137433.39
93 rdf:type schema:Person
94 sg:person.01272127236.47 schema:affiliation grid-institutes:grid.266515.3
95 schema:familyName Archibald
96 schema:givenName Stephen J.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01272127236.47
98 rdf:type schema:Person
99 sg:person.015262263463.15 schema:affiliation grid-institutes:None
100 schema:familyName Whitcomb
101 schema:givenName David R.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015262263463.15
103 rdf:type schema:Person
104 sg:person.016233633116.55 schema:affiliation grid-institutes:grid.266515.3
105 schema:familyName Busch
106 schema:givenName Daryle H.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016233633116.55
108 rdf:type schema:Person
109 grid-institutes:None schema:alternateName Dry Media Systems Laboratory, Imation Corporation, 55144, St Paul, MN, USA
110 schema:name Dry Media Systems Laboratory, Imation Corporation, 55144, St Paul, MN, USA
111 rdf:type schema:Organization
112 grid-institutes:grid.266515.3 schema:alternateName Department of Chemistry, University of Kansas, 66045, Lawrence, KS, USA
113 schema:name Department of Chemistry, University of Kansas, 66045, Lawrence, KS, USA
114 rdf:type schema:Organization
115 grid-institutes:grid.7372.1 schema:alternateName Department of Chemistry, University of Warwick, CV4 7AL, Coventry, UK
116 schema:name Department of Chemistry, University of Warwick, CV4 7AL, Coventry, UK
117 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...