A Luminescent One-Dimensional Copper(I) Polymer View Full Text


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Article Info

DATE

2000-03

AUTHORS

Simon Parsons, Zoe Pikramenou, Gregory A. Solan, Richard E. P. Winpenny

ABSTRACT

The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4)n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state. More... »

PAGES

227-232

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1009077118047

DOI

http://dx.doi.org/10.1023/a:1009077118047

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032977874


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