Hydrolysis, Condensation, and Tetragonal Phase Formation in Sol-Gel Zirconia Prepared with Electron-Irradiated Alkoxide Solutions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-03

AUTHORS

Xim Bokhimi, Eduardo Muñoz, José Luis Boldú, Esbaide Adem, Octavio Novaro, Tessy López, Fernando Rojas, Ricardo Gómez, Amado García-Ruiz

ABSTRACT

Sol-gel zirconia precursor, zirconium n-butoxide in ter-butanol, was irradiated with 1.3 MeV electrons to a dose of 330 KGy. Gelling was instantaneously produced when an aqueous solution of sulfuric, hydrochloric or acetic acid was added to the irradiated solution; no hydrolysis catalyst was required. Samples were characterized with X-ray powder diffraction, infrared spectroscopy, and electron paramagnetic resonance. The electron irradiation accelerated hydrolysis and condensation, which avoided the stabilization of the tetragonal phase via carboxyls, and decreased the capability of sulfate ions to stabilize it. These results suggest that the stabilization of the tetragonal phase of sol-gel zirconia via carboxyl and sulfate ions depends on their diffusion in the sol. More... »

PAGES

219-225

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1008764005816

DOI

http://dx.doi.org/10.1023/a:1008764005816

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