Exploring Clathrate Formation with an Optically Resolved Host. X-Ray Crystal Structure of the Inclusion Compound between (11S,12S)-(-)-9,10-Dihydro-9,10-ethanoanthracene-11,12-dicarboxylic Acid and n-Hexane ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-01

AUTHORS

Olga Helmle, Ingeborg Csöregh, Edwin Weber, Thomas Hens

ABSTRACT

The crystal structure of the inclusion compound formed between (11S,12S)-(-)-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic acid, (1), and n-hexane (2:1) has been studied by X-ray diffraction. It crystallizes in the tetragonal space group P41 and represents a less common type of inclusion compound, which has helical and chiral structural elements. Helical chains, formed by hydrogen-bonded host molecules, wind around the 21 screw axes and encircle the guest molecules. Crystal data: a=b=17.478(1); c=12.021(1)Å, Z=4 host–guest 2:1 units, R=0.043, Rw=0.061 for 2225 observations with I > 3σ (I). The general shape and conformational flexibility of 1 with respect to the requirements of inclusion formation and crystal packing are discussed. More... »

PAGES

45-57

References to SciGraph publications

  • 1983-03. A proposal for the classification and nomenclature of host-guest-type compounds in JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1023/a:1007972317849

    DOI

    http://dx.doi.org/10.1023/a:1007972317849

    DIMENSIONS

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