Synthesis of Precursors of Heterocyclic cis-β-Amino Alcohols by Intramolecular Amidoalkylation of 4-Hydroxyoxazolidin-2-ones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-10

AUTHORS

N. B. Chernysheva, A. A. Bogolyubov, V. V. Murav'ev, V. V. Elkin, V. V. Semenov

ABSTRACT

The reaction of intramolecular amidoalkylation of 4-hydroxyoxazolidin-2-ones leads to formation of novel and rare heterocyclic systems: substituted 1,5,6,10b-tetrahydro[1,3]oxazolo[4,3-a]isoquinolin-3-ones, 3a,4,5,10b-tetrahydro[1,3]dioxolo[4',5':6,7]naphtho[1,2-d][1,3]oxazol-2(1H)-ones, and 5,6,10,10a-tetrahydro-1H-di[1,3]oxazolo[3,4-d:4,3-g][1,4]diazepine-3,8-diones. Mild reaction conditions and the simplicity of isolation of the compounds formed make it possible to obtain the indicated heterocycles in high yields.

PAGES

1219-1225

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1002881002737

DOI

http://dx.doi.org/10.1023/a:1002881002737

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018656475


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chernysheva", 
        "givenName": "N. B.", 
        "id": "sg:person.01243505245.58", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01243505245.58"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bogolyubov", 
        "givenName": "A. A.", 
        "id": "sg:person.010746211321.95", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010746211321.95"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Murav'ev", 
        "givenName": "V. V.", 
        "id": "sg:person.014051561755.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014051561755.17"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Elkin", 
        "givenName": "V. V.", 
        "id": "sg:person.010533745023.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010533745023.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Semenov", 
        "givenName": "V. V.", 
        "id": "sg:person.0716636167.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716636167.19"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2000-10", 
    "datePublishedReg": "2000-10-01", 
    "description": "The reaction of intramolecular amidoalkylation of 4-hydroxyoxazolidin-2-ones leads to formation of novel and rare heterocyclic systems: substituted 1,5,6,10b-tetrahydro[1,3]oxazolo[4,3-a]isoquinolin-3-ones, 3a,4,5,10b-tetrahydro[1,3]dioxolo[4',5':6,7]naphtho[1,2-d][1,3]oxazol-2(1H)-ones, and 5,6,10,10a-tetrahydro-1H-di[1,3]oxazolo[3,4-d:4,3-g][1,4]diazepine-3,8-diones. Mild reaction conditions and the simplicity of isolation of the compounds formed make it possible to obtain the indicated heterocycles in high yields.", 
    "genre": "article", 
    "id": "sg:pub.10.1023/a:1002881002737", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1358699", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "10", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "36"
      }
    ], 
    "keywords": [
      "rare heterocyclic systems", 
      "mild reaction conditions", 
      "synthesis of precursors", 
      "reaction conditions", 
      "heterocyclic systems", 
      "amino alcohols", 
      "intramolecular amidoalkylation", 
      "high yield", 
      "amidoalkylation", 
      "heterocycles", 
      "simplicity of isolation", 
      "tetrahydro-1H", 
      "synthesis", 
      "compounds", 
      "reaction", 
      "precursors", 
      "alcohol", 
      "yield", 
      "formation", 
      "cis", 
      "lead", 
      "simplicity", 
      "conditions", 
      "isolation", 
      "system", 
      "Heterocyclic cis"
    ], 
    "name": "Synthesis of Precursors of Heterocyclic cis-\u03b2-Amino Alcohols by Intramolecular Amidoalkylation of 4-Hydroxyoxazolidin-2-ones", 
    "pagination": "1219-1225", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1018656475"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/a:1002881002737"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/a:1002881002737", 
      "https://app.dimensions.ai/details/publication/pub.1018656475"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:03", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_312.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1023/a:1002881002737"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/a:1002881002737'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/a:1002881002737'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/a:1002881002737'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/a:1002881002737'


 

This table displays all metadata directly associated to this object as RDF triples.

112 TRIPLES      21 PREDICATES      52 URIs      44 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/a:1002881002737 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Ne0fdef445d3446f98b47020e9bdd0743
4 schema:datePublished 2000-10
5 schema:datePublishedReg 2000-10-01
6 schema:description The reaction of intramolecular amidoalkylation of 4-hydroxyoxazolidin-2-ones leads to formation of novel and rare heterocyclic systems: substituted 1,5,6,10b-tetrahydro[1,3]oxazolo[4,3-a]isoquinolin-3-ones, 3a,4,5,10b-tetrahydro[1,3]dioxolo[4',5':6,7]naphtho[1,2-d][1,3]oxazol-2(1H)-ones, and 5,6,10,10a-tetrahydro-1H-di[1,3]oxazolo[3,4-d:4,3-g][1,4]diazepine-3,8-diones. Mild reaction conditions and the simplicity of isolation of the compounds formed make it possible to obtain the indicated heterocycles in high yields.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N042419c9c19948fb9c5cc79368ac4649
11 Nb8f17c5eac2d465d970a363efd59dfef
12 sg:journal.1358699
13 schema:keywords Heterocyclic cis
14 alcohol
15 amidoalkylation
16 amino alcohols
17 cis
18 compounds
19 conditions
20 formation
21 heterocycles
22 heterocyclic systems
23 high yield
24 intramolecular amidoalkylation
25 isolation
26 lead
27 mild reaction conditions
28 precursors
29 rare heterocyclic systems
30 reaction
31 reaction conditions
32 simplicity
33 simplicity of isolation
34 synthesis
35 synthesis of precursors
36 system
37 tetrahydro-1H
38 yield
39 schema:name Synthesis of Precursors of Heterocyclic cis-β-Amino Alcohols by Intramolecular Amidoalkylation of 4-Hydroxyoxazolidin-2-ones
40 schema:pagination 1219-1225
41 schema:productId N2a29b421bb2547328135eba0f81e0528
42 N7ef4ca9f0122439abf840b82b2203bc9
43 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018656475
44 https://doi.org/10.1023/a:1002881002737
45 schema:sdDatePublished 2021-11-01T18:03
46 schema:sdLicense https://scigraph.springernature.com/explorer/license/
47 schema:sdPublisher N3d24aa912e6749469cc11f375b541c62
48 schema:url https://doi.org/10.1023/a:1002881002737
49 sgo:license sg:explorer/license/
50 sgo:sdDataset articles
51 rdf:type schema:ScholarlyArticle
52 N042419c9c19948fb9c5cc79368ac4649 schema:volumeNumber 36
53 rdf:type schema:PublicationVolume
54 N2a29b421bb2547328135eba0f81e0528 schema:name dimensions_id
55 schema:value pub.1018656475
56 rdf:type schema:PropertyValue
57 N3d24aa912e6749469cc11f375b541c62 schema:name Springer Nature - SN SciGraph project
58 rdf:type schema:Organization
59 N454d6d99ab06483c96a29c4cf0f3f656 rdf:first sg:person.010746211321.95
60 rdf:rest Ne6d4ba1a3a434dd1b30f97ead33c4805
61 N617400d1b4124e8c949ed548c1222cca rdf:first sg:person.010533745023.08
62 rdf:rest N841feae0ae1748d4af8e30baeb50eff2
63 N7ef4ca9f0122439abf840b82b2203bc9 schema:name doi
64 schema:value 10.1023/a:1002881002737
65 rdf:type schema:PropertyValue
66 N841feae0ae1748d4af8e30baeb50eff2 rdf:first sg:person.0716636167.19
67 rdf:rest rdf:nil
68 Nb8f17c5eac2d465d970a363efd59dfef schema:issueNumber 10
69 rdf:type schema:PublicationIssue
70 Ne0fdef445d3446f98b47020e9bdd0743 rdf:first sg:person.01243505245.58
71 rdf:rest N454d6d99ab06483c96a29c4cf0f3f656
72 Ne6d4ba1a3a434dd1b30f97ead33c4805 rdf:first sg:person.014051561755.17
73 rdf:rest N617400d1b4124e8c949ed548c1222cca
74 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
75 schema:name Chemical Sciences
76 rdf:type schema:DefinedTerm
77 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
78 schema:name Organic Chemistry
79 rdf:type schema:DefinedTerm
80 sg:journal.1358699 schema:issn 0132-6244
81 1573-8353
82 schema:name Chemistry of Heterocyclic Compounds
83 schema:publisher Springer Nature
84 rdf:type schema:Periodical
85 sg:person.010533745023.08 schema:affiliation grid-institutes:grid.439283.7
86 schema:familyName Elkin
87 schema:givenName V. V.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010533745023.08
89 rdf:type schema:Person
90 sg:person.010746211321.95 schema:affiliation grid-institutes:grid.439283.7
91 schema:familyName Bogolyubov
92 schema:givenName A. A.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010746211321.95
94 rdf:type schema:Person
95 sg:person.01243505245.58 schema:affiliation grid-institutes:grid.439283.7
96 schema:familyName Chernysheva
97 schema:givenName N. B.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01243505245.58
99 rdf:type schema:Person
100 sg:person.014051561755.17 schema:affiliation grid-institutes:grid.439283.7
101 schema:familyName Murav'ev
102 schema:givenName V. V.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014051561755.17
104 rdf:type schema:Person
105 sg:person.0716636167.19 schema:affiliation grid-institutes:grid.439283.7
106 schema:familyName Semenov
107 schema:givenName V. V.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716636167.19
109 rdf:type schema:Person
110 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia
111 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, Russia
112 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...