Gas-phase fragmentation of the Ag+—phenylalanine complex: Cation—π interactions and radical cation formation View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2002-04

AUTHORS

Tamer Shoeib, Alwin Cunje, Alan C. Hopkinson, K. W. Michael Siu

ABSTRACT

Collision-induced dissociation experiments on the Ag+-phenylalanine complex using several collision energies were shown to yield ten different fragment ions. Unambiguous assignment of these fragment ions were made by careful analysis of deuterium labeling experiments. The losses of H2O, CO, CO2, and AgH were commonly observed; also encountered were the losses of H2, Ag, and H. Deuterium labeling experiments and density functional calculations have been employed to probe fragmentation mechanisms that account for all experimental results. More... »

PAGES

408-416

References to SciGraph publications

  • 1997-07. C-C and C-H bond activation in the fragmentation of the [M + Ni]+ adducts of aliphatic amino acids in JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
  • 1998-08. Relative silver(I) ion binding energies of α-amino acids: A determination by means of the kinetic method in JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
  • 1996-08. The reactions of ground state Cu+ and Fe+ with the 20 common amino acids in JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
  • 1992-05. Electrospray mass spectrometry: a study on some aqueous solutions of metal salts in JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
  • 2001-02. Characterization of the product ions from the collision-induced dissociation of argentinated peptides in JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
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    http://scigraph.springernature.com/pub.10.1016/s1044-0305(02)00353-7

    DOI

    http://dx.doi.org/10.1016/s1044-0305(02)00353-7

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1016432164

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/11951979


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    N-Triples is a line-based linked data format ideal for batch operations.

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    Turtle is a human-readable linked data format.

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    RDF/XML is a standard XML format for linked data.

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