Benzene loss from trityl cations—A mechanistic study View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2006-05

AUTHORS

Chagit Denekamp, Moran Yaniv

ABSTRACT

Triarylmethyl cations eliminate substituted benzene in the gas phase, upon activation. The mechanism of this process has been studied using deuterium labeling, substituent effects, and density functional theory calculations. It is shown that this apparently simple dissociation is in fact a complicated stepwise process that involves several consecutive hydride shifts. The combination of experimental evidence and computational results leads to a clear description of transition states and reaction intermediates. More... »

PAGES

730-736

References to SciGraph publications

  • 2003-07. Homolytic cleavages in pyridinium ions, an excited state process in JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1016/j.jasms.2006.02.002

    DOI

    http://dx.doi.org/10.1016/j.jasms.2006.02.002

    DIMENSIONS

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    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/16533605


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