Identification of a new fragment ion type in the collision-induced dissociation spectra of peptides: Formation of a2-16 ions View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

1993-05

AUTHORS

K. R. Thornburg, K. L. Schey, D. R. Knapp

ABSTRACT

The identification of an ion observed in the high-energy collision-induced dissociation spectra of several model peptides is reported. The ion, observed at m/z 99 for the peptide pentaalanine (Ala5) and designated a2-16, is shown to have an elemental formula of C5H9NO by high-resolution peak matching. The precursor ion spectrum of the a2-16 ion and product ion spectra of the a2 and the a2+ 1 ions for Ala5 suggest that this ion is formed by the loss of 17 u (presumably NH3) from the a2+1 ion and, to a lesser extent, by loss of 28 u (presumably CO) from the b2-16 ion. On the basis of the data presented and other experimental evidence, a structure and mechanism for the formation of the a2-16 ion is proposed. More... »

PAGES

424-427

Identifiers

URI

http://scigraph.springernature.com/pub.10.1016/1044-0305(93)85008-l

DOI

http://dx.doi.org/10.1016/1044-0305(93)85008-l

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019666400

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/24234940


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