Size effects in ion-neutral complex-mediated alkane eliminations from ionized aliphatic ethers View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

1991-08

AUTHORS

David J. McAdoo, Charles E. Hudson, John C. Traeger, Andrew Grose, Lawrence L. Griffin

ABSTRACT

The effects of the size of the ionic and neutral partners on ion-neutral complex-mediated alkane eliminations from ionized aliphatic ethers were determined by obtaining metastable decomposition spectra and photoionization ionization efficiency curves. Increasing the size of the ionic partner decreases the competitiveness of alkane elimination with alkyl loss. This is attributed to decreasing attraction between the partners with increasing distance between the neutral partner and the center of charge in the associated ion. Increasing the size of the neutral partner lowers the threshold for alkane elimination relative to that for simple dissociation when the first threshold is above ΔHf(products). This is attributed to increasing attraction between the partners with increasing polarizability of the radical in the complex. Adding a CH2 to the radical in a complex seems to increase the attraction between the partners by about 24 kJ mol(-1). More... »

PAGES

261-269

Identifiers

URI

http://scigraph.springernature.com/pub.10.1016/1044-0305(91)80017-2

DOI

http://dx.doi.org/10.1016/1044-0305(91)80017-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036876228

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/24242345


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