Design, characterization and mechanical properties of new Na+, CO32−-apatite/alginate/C60 fullerene hybrid biocomposites View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2021-01-26

AUTHORS

Nataliia Strutynska, Anna Malyshenko, Nina Tverdokhleb, Maxim Evstigneev, Ludmila Vovchenko, Yuriy Prylutskyy, Nikolai Slobodyanik, Uwe Ritter

ABSTRACT

Nanoparticles (20–50 nm) of Na+, CO32−-containing calcium phosphate (Na: 1.49 wt% and C: 1.53 wt%) with apatite-type structure were prepared by precipitation method from aqueous solution. According to FTIR spectroscopy data, the partial substitution of phosphate by carbonate (B-type) realized in the apatite-type structure. Obtained Na+, CO32−-hydroxyapatite (HAP) was used for the preparation of hybrid biocomposites with Alginate (Alg) with weight ratio HAP: Alg = 1:1 or 2:1 and C60 fullerene (C60; from 0.2 to 4 wt%) and their mechanical properties were determined. It was found, that sample with weight ratio HAP: Alg = 2:1 and containing 4.0 wt% of C60 has the highest Young's modulus 429 MPa comparing with other determined samples. The structure modeling of the investigated system showed that the formation of triple complexes Na+, CO32−-HAP–Alg–C60 is stabilized by solvophobic and stacking interactions. The created biocomposites can be used as an effective implant material for bone restoration. More... »

PAGES

422-429

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s43207-020-00107-z

DOI

http://dx.doi.org/10.1007/s43207-020-00107-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1134892919


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