Crack-free TiO2 films prepared by adjusting processing parameters via liquid phase deposition technique View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2020-02-03

AUTHORS

Jie Li, Hai-Yan Xu, Ai-Guo Wang, Feng-Jun Zhang, Dao-Sheng Sun, Won-Chun Oh

ABSTRACT

TiO2 thin films with controllable morphology and grain size were prepared via a liquid phase deposition (LPD) technique. The effects of the processing parameters including the (NH4)2TiF6 concentration, solution pH, and (NH4)2TiF6:H3BO3 molar ratio on the grain size and morphology of the films were investigated. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy, and ultraviolet–visible spectroscopy. The results showed that the deposition parameters significantly affected the growth and nucleation velocities of the crystalline grains, which resulted in the formation of TiO2 films with different morphologies and grain sizes. The capillary stress among the grains of the film, which resulted in the cracking of the film, depended on the size of the grains. Thus, the cracking of the LPD-derived TiO2 films could be mitigated by adjusting the deposition parameters. More... »

PAGES

206-212

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s43207-020-00019-y

DOI

http://dx.doi.org/10.1007/s43207-020-00019-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1124554811


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.440647.5", 
          "name": [
            "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Li", 
        "givenName": "Jie", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, 230601, Hefei, Anhui, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.440647.5", 
          "name": [
            "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China", 
            "Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, 230601, Hefei, Anhui, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xu", 
        "givenName": "Hai-Yan", 
        "id": "sg:person.013047265721.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013047265721.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.440647.5", 
          "name": [
            "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Ai-Guo", 
        "id": "sg:person.013570203521.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013570203521.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, 230601, Hefei, Anhui, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.440647.5", 
          "name": [
            "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China", 
            "Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, 230601, Hefei, Anhui, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Feng-Jun", 
        "id": "sg:person.011262570721.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011262570721.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China", 
          "id": "http://www.grid.ac/institutes/grid.440647.5", 
          "name": [
            "Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People\u2019s Republic of China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sun", 
        "givenName": "Dao-Sheng", 
        "id": "sg:person.016130657140.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016130657140.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Advanced Materials Science and Engineering, Hanseo University, 31962, Seosan, Korea", 
          "id": "http://www.grid.ac/institutes/grid.411977.d", 
          "name": [
            "Department of Advanced Materials Science and Engineering, Hanseo University, 31962, Seosan, Korea"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Oh", 
        "givenName": "Won-Chun", 
        "id": "sg:person.015032760145.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015032760145.10"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2020-02-03", 
    "datePublishedReg": "2020-02-03", 
    "description": "TiO2 thin films with controllable morphology and grain size were prepared via a liquid phase deposition (LPD) technique. The effects of the processing parameters including the (NH4)2TiF6 concentration, solution pH, and (NH4)2TiF6:H3BO3 molar ratio on the grain size and morphology of the films were investigated. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy, and ultraviolet\u2013visible spectroscopy. The results showed that the deposition parameters significantly affected the growth and nucleation velocities of the crystalline grains, which resulted in the formation of TiO2 films with different morphologies and grain sizes. The capillary stress among the grains of the film, which resulted in the cracking of the film, depended on the size of the grains. Thus, the cracking of the LPD-derived TiO2 films could be mitigated by adjusting the deposition parameters.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s43207-020-00019-y", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.8267175", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.8280793", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1137865", 
        "issn": [
          "1229-7801", 
          "2234-0491"
        ], 
        "name": "Journal of the Korean Ceramic Society", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "57"
      }
    ], 
    "keywords": [
      "liquid phase deposition technique", 
      "TiO2 films", 
      "grain size", 
      "processing parameters", 
      "deposition parameters", 
      "deposition technique", 
      "TiO2 thin films", 
      "capillary stress", 
      "crystalline grains", 
      "thin films", 
      "ultraviolet-visible spectroscopy", 
      "nucleation velocity", 
      "controllable morphology", 
      "films", 
      "cracking", 
      "solution pH", 
      "ray diffraction", 
      "electron microscopy", 
      "prepared samples", 
      "different morphologies", 
      "grains", 
      "parameters", 
      "morphology", 
      "molar ratio", 
      "velocity", 
      "size", 
      "diffraction", 
      "technique", 
      "microscopy", 
      "stress", 
      "spectroscopy", 
      "ratio", 
      "pH", 
      "formation", 
      "results", 
      "effect", 
      "concentration", 
      "samples", 
      "growth", 
      "LPD", 
      "phase deposition (LPD) technique", 
      "H3BO3 molar ratio", 
      "Crack-free TiO2 films"
    ], 
    "name": "Crack-free TiO2 films prepared by adjusting processing parameters via liquid phase deposition technique", 
    "pagination": "206-212", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1124554811"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s43207-020-00019-y"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s43207-020-00019-y", 
      "https://app.dimensions.ai/details/publication/pub.1124554811"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:53", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_847.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s43207-020-00019-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s43207-020-00019-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s43207-020-00019-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s43207-020-00019-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s43207-020-00019-y'


 

This table displays all metadata directly associated to this object as RDF triples.

144 TRIPLES      21 PREDICATES      68 URIs      60 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s43207-020-00019-y schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N9f5acf07dfa94d7c81ddeb5711ca8506
4 schema:datePublished 2020-02-03
5 schema:datePublishedReg 2020-02-03
6 schema:description TiO2 thin films with controllable morphology and grain size were prepared via a liquid phase deposition (LPD) technique. The effects of the processing parameters including the (NH4)2TiF6 concentration, solution pH, and (NH4)2TiF6:H3BO3 molar ratio on the grain size and morphology of the films were investigated. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy, and ultraviolet–visible spectroscopy. The results showed that the deposition parameters significantly affected the growth and nucleation velocities of the crystalline grains, which resulted in the formation of TiO2 films with different morphologies and grain sizes. The capillary stress among the grains of the film, which resulted in the cracking of the film, depended on the size of the grains. Thus, the cracking of the LPD-derived TiO2 films could be mitigated by adjusting the deposition parameters.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf Na5bba75a2a104ab4892e56efeb0373f4
11 Ncf76d22ea15a457da64695b2707a4017
12 sg:journal.1137865
13 schema:keywords Crack-free TiO2 films
14 H3BO3 molar ratio
15 LPD
16 TiO2 films
17 TiO2 thin films
18 capillary stress
19 concentration
20 controllable morphology
21 cracking
22 crystalline grains
23 deposition parameters
24 deposition technique
25 different morphologies
26 diffraction
27 effect
28 electron microscopy
29 films
30 formation
31 grain size
32 grains
33 growth
34 liquid phase deposition technique
35 microscopy
36 molar ratio
37 morphology
38 nucleation velocity
39 pH
40 parameters
41 phase deposition (LPD) technique
42 prepared samples
43 processing parameters
44 ratio
45 ray diffraction
46 results
47 samples
48 size
49 solution pH
50 spectroscopy
51 stress
52 technique
53 thin films
54 ultraviolet-visible spectroscopy
55 velocity
56 schema:name Crack-free TiO2 films prepared by adjusting processing parameters via liquid phase deposition technique
57 schema:pagination 206-212
58 schema:productId N38885d33bb4640ac9d2d8bb252c543c9
59 N7b2a9d59ab9849688f003cb75cd29b97
60 schema:sameAs https://app.dimensions.ai/details/publication/pub.1124554811
61 https://doi.org/10.1007/s43207-020-00019-y
62 schema:sdDatePublished 2022-01-01T18:53
63 schema:sdLicense https://scigraph.springernature.com/explorer/license/
64 schema:sdPublisher Ne8eb0e47ca2d4d948157875c43ab8531
65 schema:url https://doi.org/10.1007/s43207-020-00019-y
66 sgo:license sg:explorer/license/
67 sgo:sdDataset articles
68 rdf:type schema:ScholarlyArticle
69 N18f5caabe2874adea9dc91cecb3bf013 rdf:first sg:person.015032760145.10
70 rdf:rest rdf:nil
71 N38885d33bb4640ac9d2d8bb252c543c9 schema:name dimensions_id
72 schema:value pub.1124554811
73 rdf:type schema:PropertyValue
74 N5debd0a137d84b9da92f3cbd51a7176b schema:affiliation grid-institutes:grid.440647.5
75 schema:familyName Li
76 schema:givenName Jie
77 rdf:type schema:Person
78 N6c5b9e7e803248e2b54f10cb4e63b591 rdf:first sg:person.011262570721.92
79 rdf:rest N855016f0f3b345efac7cbb3adfebd279
80 N7b2a9d59ab9849688f003cb75cd29b97 schema:name doi
81 schema:value 10.1007/s43207-020-00019-y
82 rdf:type schema:PropertyValue
83 N855016f0f3b345efac7cbb3adfebd279 rdf:first sg:person.016130657140.90
84 rdf:rest N18f5caabe2874adea9dc91cecb3bf013
85 N9f5acf07dfa94d7c81ddeb5711ca8506 rdf:first N5debd0a137d84b9da92f3cbd51a7176b
86 rdf:rest Nf1ec383f40a844fb8aa3e8eb67922b89
87 Na5bba75a2a104ab4892e56efeb0373f4 schema:issueNumber 2
88 rdf:type schema:PublicationIssue
89 Ncf76d22ea15a457da64695b2707a4017 schema:volumeNumber 57
90 rdf:type schema:PublicationVolume
91 Ne8eb0e47ca2d4d948157875c43ab8531 schema:name Springer Nature - SN SciGraph project
92 rdf:type schema:Organization
93 Nf0049e03e00140ab8d521981660bd7b7 rdf:first sg:person.013570203521.55
94 rdf:rest N6c5b9e7e803248e2b54f10cb4e63b591
95 Nf1ec383f40a844fb8aa3e8eb67922b89 rdf:first sg:person.013047265721.77
96 rdf:rest Nf0049e03e00140ab8d521981660bd7b7
97 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
98 schema:name Engineering
99 rdf:type schema:DefinedTerm
100 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
101 schema:name Materials Engineering
102 rdf:type schema:DefinedTerm
103 sg:grant.8267175 http://pending.schema.org/fundedItem sg:pub.10.1007/s43207-020-00019-y
104 rdf:type schema:MonetaryGrant
105 sg:grant.8280793 http://pending.schema.org/fundedItem sg:pub.10.1007/s43207-020-00019-y
106 rdf:type schema:MonetaryGrant
107 sg:journal.1137865 schema:issn 1229-7801
108 2234-0491
109 schema:name Journal of the Korean Ceramic Society
110 schema:publisher Springer Nature
111 rdf:type schema:Periodical
112 sg:person.011262570721.92 schema:affiliation grid-institutes:grid.440647.5
113 schema:familyName Zhang
114 schema:givenName Feng-Jun
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011262570721.92
116 rdf:type schema:Person
117 sg:person.013047265721.77 schema:affiliation grid-institutes:grid.440647.5
118 schema:familyName Xu
119 schema:givenName Hai-Yan
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013047265721.77
121 rdf:type schema:Person
122 sg:person.013570203521.55 schema:affiliation grid-institutes:grid.440647.5
123 schema:familyName Wang
124 schema:givenName Ai-Guo
125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013570203521.55
126 rdf:type schema:Person
127 sg:person.015032760145.10 schema:affiliation grid-institutes:grid.411977.d
128 schema:familyName Oh
129 schema:givenName Won-Chun
130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015032760145.10
131 rdf:type schema:Person
132 sg:person.016130657140.90 schema:affiliation grid-institutes:grid.440647.5
133 schema:familyName Sun
134 schema:givenName Dao-Sheng
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016130657140.90
136 rdf:type schema:Person
137 grid-institutes:grid.411977.d schema:alternateName Department of Advanced Materials Science and Engineering, Hanseo University, 31962, Seosan, Korea
138 schema:name Department of Advanced Materials Science and Engineering, Hanseo University, 31962, Seosan, Korea
139 rdf:type schema:Organization
140 grid-institutes:grid.440647.5 schema:alternateName Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People’s Republic of China
141 Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, 230601, Hefei, Anhui, People’s Republic of China
142 schema:name Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, 230022, Hefei, Anhui, People’s Republic of China
143 Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, 230601, Hefei, Anhui, People’s Republic of China
144 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...