Block copolymer ordering on elastomeric substrates of tunable surface energy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-03-06

AUTHORS

Arzu Hayirlioglu, Manish Kulkarni, Gurpreet Singh, Abdullah M. Al-Enizi, Irina Zvonkina, Alamgir Karim

ABSTRACT

We report a range of surface characteristics from strong and partial dewetting to complete wetting for thin films of cylinder and lamellae forming block copolymers (c-BCP and l-BCP, respectively) of polystyrene-b-polymethylmethacrylate (PS-b-PMMA) on flexible substrates. BCP of various molecular weights (Mw) was applied on elastomeric polydimethylsiloxane (PDMS) substrates of distinct cross-link densities and various surface energy (SE) obtained by exposure to UV-ozone. We demonstrate that lower Mw c-BCP films dewet faster than l-BCP films of higher Mw applied on PDMS of lowest cross-link density and SE < 25 mJ/m2. Partial dewetting was observed for c-BCP films applied on the lowest cross-link density substrates with 25 mJ/m2 < SE < 32 mJ/m2, with a sharper transition from dewetting to wetting for l-BCP films. Finally, complete wetting (stable films) occurred for both c-BCP and l-BCP films on PDMS substrates with lowest cross-link density and SE > 32 mJ/m2, as well as on PDMS of the highest cross-link density with SE > 25 mJ/m2. In this extended SE wetting regime, c-BCP show vertical orientation when applied on both types of cross-linked PDMS in a narrow neutral SE range (39–40) mJ/m2, while being oriented parallel to the substrate when SE > 40 mJ/m2. The ratio of vertically oriented l-BCP however decreases gradually when applied on substrates with a higher SE range (40–65 mJ/m2) in comparison to the sharply transitioning c-BCP orientation, reflecting the intrinsic stability of vertical lamellae over a wider range of substrate SE, consistent with theoretical estimates. These results have important ramifications for design of next-generation flexible electronics utilizing BCP thin films. More... »

PAGES

1-12

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s42247-019-00025-9

DOI

http://dx.doi.org/10.1007/s42247-019-00025-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112587821


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Akron", 
          "id": "https://www.grid.ac/institutes/grid.265881.0", 
          "name": [
            "Department of Polymer Engineering, University of Akron, 44325, Akron, OH, USA", 
            "Avery Dennison Corporation, 44060, Mentor, OH, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hayirlioglu", 
        "givenName": "Arzu", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Indian Institute of Technology Kanpur", 
          "id": "https://www.grid.ac/institutes/grid.417965.8", 
          "name": [
            "Indian Institute of Technology, Kanpur, 208016, Kanpur, UP, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kulkarni", 
        "givenName": "Manish", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Intel (United States)", 
          "id": "https://www.grid.ac/institutes/grid.419318.6", 
          "name": [
            "Department of Polymer Engineering, University of Akron, 44325, Akron, OH, USA", 
            "Intel Corporation, 97124, Hillsboro, OR, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Singh", 
        "givenName": "Gurpreet", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "King Saud University", 
          "id": "https://www.grid.ac/institutes/grid.56302.32", 
          "name": [
            "Chemistry Department, Faculty of Science, King Saud University, 2455, 11451, Riyadh, Saudi Arabia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Al-Enizi", 
        "givenName": "Abdullah M.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Houston", 
          "id": "https://www.grid.ac/institutes/grid.266436.3", 
          "name": [
            "Department of Chemical and Biomolecular Engineering, University of Houston, 77203, Houston, TX, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zvonkina", 
        "givenName": "Irina", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Houston", 
          "id": "https://www.grid.ac/institutes/grid.266436.3", 
          "name": [
            "Department of Chemical and Biomolecular Engineering, University of Houston, 77203, Houston, TX, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Karim", 
        "givenName": "Alamgir", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/adma.200304906", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001575616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcis.2016.06.017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002470288"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.eurpolymj.2016.01.010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005484927"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.eurpolymj.2016.01.010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005484927"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pssc.200982419", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009896836"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2006.131", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010301980", 
          "https://doi.org/10.1038/nnano.2006.131"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2006.131", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010301980", 
          "https://doi.org/10.1038/nnano.2006.131"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature01775", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011592620", 
          "https://doi.org/10.1038/nature01775"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature01775", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011592620", 
          "https://doi.org/10.1038/nature01775"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.memsci.2007.08.014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019254518"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.41050", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024183698"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1140/epje/i2001-10060-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025849637", 
          "https://doi.org/10.1140/epje/i2001-10060-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcis.2002.8594", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031864573"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcis.2002.8594", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031864573"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac0346712", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036892903"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac0346712", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036892903"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.1969.070130815", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038497416"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/marc.200390001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043143413"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pi.783", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043765958"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200801065", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046790921"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200902722", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047871049"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200902722", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047871049"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1106604", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048175803"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.mser.2004.12.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050553412"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1182383", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050910744"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1182383", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050910744"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la00029a031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056138264"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la000822+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056140872"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la000822+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056140872"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la049562c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056148085"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la049562c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056148085"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la981693o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056170750"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la981693o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056170750"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma035805g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056189042"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma035805g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056189042"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma052335c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056191530"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma052335c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056191530"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma060456m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056191897"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma060456m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056191897"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma101247c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056194328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma101247c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056194328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma301004j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056196477"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma900110w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056203734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma900110w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056203734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma901350w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056204259"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma901350w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056204259"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma980705+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056208697"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma980705+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056208697"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma990483v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056209854"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma990483v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056209854"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1370565", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057699926"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1383805", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057701356"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1695731", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057766969"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2719027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057860082"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.474994", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058059040"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.479653", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058071881"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.480469", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058075777"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.68.75", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060805019"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.68.75", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060805019"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.76.2503", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060812871"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.76.2503", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060812871"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.79.237", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060815888"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.79.237", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060815888"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1157626", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062457708"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1168108", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062459229"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.275.5305.1458", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062555987"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.276.5317.1401", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062556858"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.biomaterials.2017.08.033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1091223467"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1098960806", 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cej.2018.01.062", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100318347"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cej.2018.01.062", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100318347"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.matlet.2018.03.114", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101561332"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.snb.2018.03.151", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101828721"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-03-06", 
    "datePublishedReg": "2019-03-06", 
    "description": "We report a range of surface characteristics from strong and partial dewetting to complete wetting for thin films of cylinder and lamellae forming block copolymers (c-BCP and l-BCP, respectively) of polystyrene-b-polymethylmethacrylate (PS-b-PMMA) on flexible substrates. BCP of various molecular weights (Mw) was applied on elastomeric polydimethylsiloxane (PDMS) substrates of distinct cross-link densities and various surface energy (SE) obtained by exposure to UV-ozone. We demonstrate that lower Mw c-BCP films dewet faster than l-BCP films of higher Mw applied on PDMS of lowest cross-link density and SE < 25 mJ/m2. Partial dewetting was observed for c-BCP films applied on the lowest cross-link density substrates with 25 mJ/m2 < SE < 32 mJ/m2, with a sharper transition from dewetting to wetting for l-BCP films. Finally, complete wetting (stable films) occurred for both c-BCP and l-BCP films on PDMS substrates with lowest cross-link density and SE > 32 mJ/m2, as well as on PDMS of the highest cross-link density with SE > 25 mJ/m2. In this extended SE wetting regime, c-BCP show vertical orientation when applied on both types of cross-linked PDMS in a narrow neutral SE range (39\u201340) mJ/m2, while being oriented parallel to the substrate when SE > 40 mJ/m2. The ratio of vertically oriented l-BCP however decreases gradually when applied on substrates with a higher SE range (40\u201365 mJ/m2) in comparison to the sharply transitioning c-BCP orientation, reflecting the intrinsic stability of vertical lamellae over a wider range of substrate SE, consistent with theoretical estimates. These results have important ramifications for design of next-generation flexible electronics utilizing BCP thin films.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s42247-019-00025-9", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1320448", 
        "issn": [
          "2522-5731", 
          "2522-574X"
        ], 
        "name": "Emergent Materials", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "2"
      }
    ], 
    "name": "Block copolymer ordering on elastomeric substrates of tunable surface energy", 
    "pagination": "1-12", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s42247-019-00025-9"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "b8d9e8b79891c8021c0d91fee1dec329a7cff8b4f7dfab912f58786fd6fd3a84"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112587821"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s42247-019-00025-9", 
      "https://app.dimensions.ai/details/publication/pub.1112587821"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T09:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000376_0000000376/records_56176_00000006.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs42247-019-00025-9"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s42247-019-00025-9'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s42247-019-00025-9'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s42247-019-00025-9'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s42247-019-00025-9'


 

This table displays all metadata directly associated to this object as RDF triples.

259 TRIPLES      21 PREDICATES      77 URIs      18 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s42247-019-00025-9 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N4aca0cd3b9a64be3b689090db8ff3a13
4 schema:citation sg:pub.10.1038/nature01775
5 sg:pub.10.1038/nnano.2006.131
6 sg:pub.10.1140/epje/i2001-10060-4
7 https://app.dimensions.ai/details/publication/pub.1098960806
8 https://doi.org/10.1002/adfm.200801065
9 https://doi.org/10.1002/adma.200304906
10 https://doi.org/10.1002/adma.200902722
11 https://doi.org/10.1002/app.1969.070130815
12 https://doi.org/10.1002/app.41050
13 https://doi.org/10.1002/marc.200390001
14 https://doi.org/10.1002/pi.783
15 https://doi.org/10.1002/pssc.200982419
16 https://doi.org/10.1006/jcis.2002.8594
17 https://doi.org/10.1016/j.biomaterials.2017.08.033
18 https://doi.org/10.1016/j.cej.2018.01.062
19 https://doi.org/10.1016/j.eurpolymj.2016.01.010
20 https://doi.org/10.1016/j.jcis.2016.06.017
21 https://doi.org/10.1016/j.matlet.2018.03.114
22 https://doi.org/10.1016/j.memsci.2007.08.014
23 https://doi.org/10.1016/j.mser.2004.12.003
24 https://doi.org/10.1016/j.snb.2018.03.151
25 https://doi.org/10.1021/ac0346712
26 https://doi.org/10.1021/la00029a031
27 https://doi.org/10.1021/la000822+
28 https://doi.org/10.1021/la049562c
29 https://doi.org/10.1021/la981693o
30 https://doi.org/10.1021/ma035805g
31 https://doi.org/10.1021/ma052335c
32 https://doi.org/10.1021/ma060456m
33 https://doi.org/10.1021/ma101247c
34 https://doi.org/10.1021/ma301004j
35 https://doi.org/10.1021/ma900110w
36 https://doi.org/10.1021/ma901350w
37 https://doi.org/10.1021/ma980705+
38 https://doi.org/10.1021/ma990483v
39 https://doi.org/10.1063/1.1370565
40 https://doi.org/10.1063/1.1383805
41 https://doi.org/10.1063/1.1695731
42 https://doi.org/10.1063/1.2719027
43 https://doi.org/10.1063/1.474994
44 https://doi.org/10.1063/1.479653
45 https://doi.org/10.1063/1.480469
46 https://doi.org/10.1103/physrevlett.68.75
47 https://doi.org/10.1103/physrevlett.76.2503
48 https://doi.org/10.1103/physrevlett.79.237
49 https://doi.org/10.1126/science.1106604
50 https://doi.org/10.1126/science.1157626
51 https://doi.org/10.1126/science.1168108
52 https://doi.org/10.1126/science.1182383
53 https://doi.org/10.1126/science.275.5305.1458
54 https://doi.org/10.1126/science.276.5317.1401
55 schema:datePublished 2019-03-06
56 schema:datePublishedReg 2019-03-06
57 schema:description We report a range of surface characteristics from strong and partial dewetting to complete wetting for thin films of cylinder and lamellae forming block copolymers (c-BCP and l-BCP, respectively) of polystyrene-b-polymethylmethacrylate (PS-b-PMMA) on flexible substrates. BCP of various molecular weights (Mw) was applied on elastomeric polydimethylsiloxane (PDMS) substrates of distinct cross-link densities and various surface energy (SE) obtained by exposure to UV-ozone. We demonstrate that lower Mw c-BCP films dewet faster than l-BCP films of higher Mw applied on PDMS of lowest cross-link density and SE < 25 mJ/m2. Partial dewetting was observed for c-BCP films applied on the lowest cross-link density substrates with 25 mJ/m2 < SE < 32 mJ/m2, with a sharper transition from dewetting to wetting for l-BCP films. Finally, complete wetting (stable films) occurred for both c-BCP and l-BCP films on PDMS substrates with lowest cross-link density and SE > 32 mJ/m2, as well as on PDMS of the highest cross-link density with SE > 25 mJ/m2. In this extended SE wetting regime, c-BCP show vertical orientation when applied on both types of cross-linked PDMS in a narrow neutral SE range (39–40) mJ/m2, while being oriented parallel to the substrate when SE > 40 mJ/m2. The ratio of vertically oriented l-BCP however decreases gradually when applied on substrates with a higher SE range (40–65 mJ/m2) in comparison to the sharply transitioning c-BCP orientation, reflecting the intrinsic stability of vertical lamellae over a wider range of substrate SE, consistent with theoretical estimates. These results have important ramifications for design of next-generation flexible electronics utilizing BCP thin films.
58 schema:genre research_article
59 schema:inLanguage en
60 schema:isAccessibleForFree false
61 schema:isPartOf N1a1494fc21614efeafccf9671f095ab1
62 N388046ca28304f418afa276d8a381349
63 sg:journal.1320448
64 schema:name Block copolymer ordering on elastomeric substrates of tunable surface energy
65 schema:pagination 1-12
66 schema:productId N5d2cd44fc9bd43d29b949e63304c45e1
67 Na0cd80d7490c4aa0874e1ab6bb81e7cd
68 Ncbe603940700426bb9921cb2d6f580e5
69 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112587821
70 https://doi.org/10.1007/s42247-019-00025-9
71 schema:sdDatePublished 2019-04-15T09:19
72 schema:sdLicense https://scigraph.springernature.com/explorer/license/
73 schema:sdPublisher N9c19c803318a431da9e4624a23e261f0
74 schema:url https://link.springer.com/10.1007%2Fs42247-019-00025-9
75 sgo:license sg:explorer/license/
76 sgo:sdDataset articles
77 rdf:type schema:ScholarlyArticle
78 N1a1494fc21614efeafccf9671f095ab1 schema:issueNumber 1
79 rdf:type schema:PublicationIssue
80 N1fc991d697974d5cae2f9b2c1e4e39f8 rdf:first N2c066fa5ec6e4266b8b85347c9278324
81 rdf:rest N9e2d77b020d04afdbb733f47f3978389
82 N2c066fa5ec6e4266b8b85347c9278324 schema:affiliation https://www.grid.ac/institutes/grid.56302.32
83 schema:familyName Al-Enizi
84 schema:givenName Abdullah M.
85 rdf:type schema:Person
86 N388046ca28304f418afa276d8a381349 schema:volumeNumber 2
87 rdf:type schema:PublicationVolume
88 N4aca0cd3b9a64be3b689090db8ff3a13 rdf:first Nbd917138bedd4122ba9b2e7bc23df273
89 rdf:rest Ne07a8c12455d47f7b478199e762e88b5
90 N52f0c94e628847d0824f84c65f0595f1 schema:affiliation https://www.grid.ac/institutes/grid.266436.3
91 schema:familyName Zvonkina
92 schema:givenName Irina
93 rdf:type schema:Person
94 N5d2cd44fc9bd43d29b949e63304c45e1 schema:name doi
95 schema:value 10.1007/s42247-019-00025-9
96 rdf:type schema:PropertyValue
97 N9c19c803318a431da9e4624a23e261f0 schema:name Springer Nature - SN SciGraph project
98 rdf:type schema:Organization
99 N9e2d77b020d04afdbb733f47f3978389 rdf:first N52f0c94e628847d0824f84c65f0595f1
100 rdf:rest Ne691c329140049a385d6cc6dc1decef9
101 Na0cd80d7490c4aa0874e1ab6bb81e7cd schema:name readcube_id
102 schema:value b8d9e8b79891c8021c0d91fee1dec329a7cff8b4f7dfab912f58786fd6fd3a84
103 rdf:type schema:PropertyValue
104 Nb17261a004f34657801840b9cb0d4eb2 schema:affiliation https://www.grid.ac/institutes/grid.417965.8
105 schema:familyName Kulkarni
106 schema:givenName Manish
107 rdf:type schema:Person
108 Nbd917138bedd4122ba9b2e7bc23df273 schema:affiliation https://www.grid.ac/institutes/grid.265881.0
109 schema:familyName Hayirlioglu
110 schema:givenName Arzu
111 rdf:type schema:Person
112 Ncbe603940700426bb9921cb2d6f580e5 schema:name dimensions_id
113 schema:value pub.1112587821
114 rdf:type schema:PropertyValue
115 Ne07a8c12455d47f7b478199e762e88b5 rdf:first Nb17261a004f34657801840b9cb0d4eb2
116 rdf:rest Neddbcbce8f8a49398b6c7ce037e377f9
117 Ne51925d761cc4f0089856864844a6c7a schema:affiliation https://www.grid.ac/institutes/grid.266436.3
118 schema:familyName Karim
119 schema:givenName Alamgir
120 rdf:type schema:Person
121 Ne691c329140049a385d6cc6dc1decef9 rdf:first Ne51925d761cc4f0089856864844a6c7a
122 rdf:rest rdf:nil
123 Necf9e4b47f694752bd596e08647d108a schema:affiliation https://www.grid.ac/institutes/grid.419318.6
124 schema:familyName Singh
125 schema:givenName Gurpreet
126 rdf:type schema:Person
127 Neddbcbce8f8a49398b6c7ce037e377f9 rdf:first Necf9e4b47f694752bd596e08647d108a
128 rdf:rest N1fc991d697974d5cae2f9b2c1e4e39f8
129 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
130 schema:name Engineering
131 rdf:type schema:DefinedTerm
132 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
133 schema:name Materials Engineering
134 rdf:type schema:DefinedTerm
135 sg:journal.1320448 schema:issn 2522-5731
136 2522-574X
137 schema:name Emergent Materials
138 rdf:type schema:Periodical
139 sg:pub.10.1038/nature01775 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011592620
140 https://doi.org/10.1038/nature01775
141 rdf:type schema:CreativeWork
142 sg:pub.10.1038/nnano.2006.131 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010301980
143 https://doi.org/10.1038/nnano.2006.131
144 rdf:type schema:CreativeWork
145 sg:pub.10.1140/epje/i2001-10060-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025849637
146 https://doi.org/10.1140/epje/i2001-10060-4
147 rdf:type schema:CreativeWork
148 https://app.dimensions.ai/details/publication/pub.1098960806 schema:CreativeWork
149 https://doi.org/10.1002/adfm.200801065 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046790921
150 rdf:type schema:CreativeWork
151 https://doi.org/10.1002/adma.200304906 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001575616
152 rdf:type schema:CreativeWork
153 https://doi.org/10.1002/adma.200902722 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047871049
154 rdf:type schema:CreativeWork
155 https://doi.org/10.1002/app.1969.070130815 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038497416
156 rdf:type schema:CreativeWork
157 https://doi.org/10.1002/app.41050 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024183698
158 rdf:type schema:CreativeWork
159 https://doi.org/10.1002/marc.200390001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043143413
160 rdf:type schema:CreativeWork
161 https://doi.org/10.1002/pi.783 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043765958
162 rdf:type schema:CreativeWork
163 https://doi.org/10.1002/pssc.200982419 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009896836
164 rdf:type schema:CreativeWork
165 https://doi.org/10.1006/jcis.2002.8594 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031864573
166 rdf:type schema:CreativeWork
167 https://doi.org/10.1016/j.biomaterials.2017.08.033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1091223467
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1016/j.cej.2018.01.062 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100318347
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1016/j.eurpolymj.2016.01.010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005484927
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1016/j.jcis.2016.06.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002470288
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1016/j.matlet.2018.03.114 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101561332
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1016/j.memsci.2007.08.014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019254518
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1016/j.mser.2004.12.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050553412
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1016/j.snb.2018.03.151 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101828721
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1021/ac0346712 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036892903
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1021/la00029a031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056138264
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1021/la000822+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1056140872
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1021/la049562c schema:sameAs https://app.dimensions.ai/details/publication/pub.1056148085
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1021/la981693o schema:sameAs https://app.dimensions.ai/details/publication/pub.1056170750
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1021/ma035805g schema:sameAs https://app.dimensions.ai/details/publication/pub.1056189042
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1021/ma052335c schema:sameAs https://app.dimensions.ai/details/publication/pub.1056191530
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1021/ma060456m schema:sameAs https://app.dimensions.ai/details/publication/pub.1056191897
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1021/ma101247c schema:sameAs https://app.dimensions.ai/details/publication/pub.1056194328
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1021/ma301004j schema:sameAs https://app.dimensions.ai/details/publication/pub.1056196477
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1021/ma900110w schema:sameAs https://app.dimensions.ai/details/publication/pub.1056203734
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1021/ma901350w schema:sameAs https://app.dimensions.ai/details/publication/pub.1056204259
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1021/ma980705+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1056208697
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1021/ma990483v schema:sameAs https://app.dimensions.ai/details/publication/pub.1056209854
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1063/1.1370565 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057699926
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1063/1.1383805 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057701356
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1063/1.1695731 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057766969
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1063/1.2719027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057860082
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1063/1.474994 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058059040
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1063/1.479653 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058071881
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1063/1.480469 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058075777
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1103/physrevlett.68.75 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060805019
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1103/physrevlett.76.2503 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060812871
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1103/physrevlett.79.237 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060815888
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1126/science.1106604 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048175803
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1126/science.1157626 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062457708
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1126/science.1168108 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062459229
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1126/science.1182383 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050910744
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1126/science.275.5305.1458 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062555987
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1126/science.276.5317.1401 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062556858
242 rdf:type schema:CreativeWork
243 https://www.grid.ac/institutes/grid.265881.0 schema:alternateName University of Akron
244 schema:name Avery Dennison Corporation, 44060, Mentor, OH, USA
245 Department of Polymer Engineering, University of Akron, 44325, Akron, OH, USA
246 rdf:type schema:Organization
247 https://www.grid.ac/institutes/grid.266436.3 schema:alternateName University of Houston
248 schema:name Department of Chemical and Biomolecular Engineering, University of Houston, 77203, Houston, TX, USA
249 rdf:type schema:Organization
250 https://www.grid.ac/institutes/grid.417965.8 schema:alternateName Indian Institute of Technology Kanpur
251 schema:name Indian Institute of Technology, Kanpur, 208016, Kanpur, UP, India
252 rdf:type schema:Organization
253 https://www.grid.ac/institutes/grid.419318.6 schema:alternateName Intel (United States)
254 schema:name Department of Polymer Engineering, University of Akron, 44325, Akron, OH, USA
255 Intel Corporation, 97124, Hillsboro, OR, USA
256 rdf:type schema:Organization
257 https://www.grid.ac/institutes/grid.56302.32 schema:alternateName King Saud University
258 schema:name Chemistry Department, Faculty of Science, King Saud University, 2455, 11451, Riyadh, Saudi Arabia
259 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...