Tandem nanocatalyst design: putting two step-reaction sites into one location towards enhanced hydrogen transfer reactions View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-04-23

AUTHORS

Yang You, Hao Huang, Keke Mao, Song Xia, Di Wu, Canyu Hu, Chao Gao, Panyiming Liu, Ran Long, Xiaojun Wu, Yujie Xiong

ABSTRACT

Efficient tandem reactions on a single catalytic nanostructure would be beneficial to improving chemical transformation efficiency and reducing safety implications. It is imperative to identify the active sites for each single step reaction so that the entire reaction process can be optimized by designing and integrating the sites. Herein, hydrogen transfer reaction is taken as a proof-of-concept demonstration to show that the spatial integration of active sites is important to the catalytic efficiency of the entire process in tandem reactions. We identified specific active sites (i.e., various sites at faces versus corners and edges) for formic acid decomposition and alkene/nitrobenzene hydrogenation—the two steps in hydrogen transfer reactions, by employing three different shapes of Pd nanocrystals in tunable sizes. The investigation reveals that the decomposition of formic acid occurs preferentially at the edge sites of cubic nanocrystal and the plane sites of octahedral/tetrahedral nanocrystals, while the hydrogenation takes place mainly at the edge sites of both cubic and octahedral/tetrahedral nanocrystals. The consistency of active edge sites during different step reactions enables cubic nanocrystals to exhibit a higher activity than octahedral nanocrystals in hydrogen transfer reactions, although octahedrons offer comparable activities to cubes in formic acid decomposition and hydrogenation reactions. Guided by these findings, we further improved the overall performance of tandem catalysis by specifically promoting the limiting step through nanocatalyst design. This work provides insights into the rational design of heterogeneous nanocatalysts in tandem reactions. More... »

PAGES

1297-1305

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s40843-019-9428-8

DOI

http://dx.doi.org/10.1007/s40843-019-9428-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1113671057


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "You", 
        "givenName": "Yang", 
        "id": "sg:person.01157173346.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01157173346.33"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Huang", 
        "givenName": "Hao", 
        "id": "sg:person.011573774737.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011573774737.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China", 
          "id": "http://www.grid.ac/institutes/grid.440650.3", 
          "name": [
            "School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mao", 
        "givenName": "Keke", 
        "id": "sg:person.0706525746.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0706525746.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xia", 
        "givenName": "Song", 
        "id": "sg:person.07372524330.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07372524330.97"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wu", 
        "givenName": "Di", 
        "id": "sg:person.0732554276.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732554276.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hu", 
        "givenName": "Canyu", 
        "id": "sg:person.01165733230.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01165733230.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gao", 
        "givenName": "Chao", 
        "id": "sg:person.01277070523.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01277070523.33"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liu", 
        "givenName": "Panyiming", 
        "id": "sg:person.010765465330.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010765465330.00"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Long", 
        "givenName": "Ran", 
        "id": "sg:person.0640412546.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0640412546.43"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wu", 
        "givenName": "Xiaojun", 
        "id": "sg:person.0734146202.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0734146202.61"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xiong", 
        "givenName": "Yujie", 
        "id": "sg:person.0600113217.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0600113217.27"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/nchem.1018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053103963", 
          "https://doi.org/10.1038/nchem.1018"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11426-018-9322-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1106054848", 
          "https://doi.org/10.1007/s11426-018-9322-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-015-0722-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022814395", 
          "https://doi.org/10.1007/s12274-015-0722-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1734", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026610046", 
          "https://doi.org/10.1038/nmat1734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-016-1053-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011220084", 
          "https://doi.org/10.1007/s12274-016-1053-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2010.235", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017581888", 
          "https://doi.org/10.1038/nnano.2010.235"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41560-018-0229-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1106420896", 
          "https://doi.org/10.1038/s41560-018-0229-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2011.42", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009316962", 
          "https://doi.org/10.1038/nnano.2011.42"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.1621", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041494845", 
          "https://doi.org/10.1038/nchem.1621"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-04-23", 
    "datePublishedReg": "2019-04-23", 
    "description": "Efficient tandem reactions on a single catalytic nanostructure would be beneficial to improving chemical transformation efficiency and reducing safety implications. It is imperative to identify the active sites for each single step reaction so that the entire reaction process can be optimized by designing and integrating the sites. Herein, hydrogen transfer reaction is taken as a proof-of-concept demonstration to show that the spatial integration of active sites is important to the catalytic efficiency of the entire process in tandem reactions. We identified specific active sites (i.e., various sites at faces versus corners and edges) for formic acid decomposition and alkene/nitrobenzene hydrogenation\u2014the two steps in hydrogen transfer reactions, by employing three different shapes of Pd nanocrystals in tunable sizes. The investigation reveals that the decomposition of formic acid occurs preferentially at the edge sites of cubic nanocrystal and the plane sites of octahedral/tetrahedral nanocrystals, while the hydrogenation takes place mainly at the edge sites of both cubic and octahedral/tetrahedral nanocrystals. The consistency of active edge sites during different step reactions enables cubic nanocrystals to exhibit a higher activity than octahedral nanocrystals in hydrogen transfer reactions, although octahedrons offer comparable activities to cubes in formic acid decomposition and hydrogenation reactions. Guided by these findings, we further improved the overall performance of tandem catalysis by specifically promoting the limiting step through nanocatalyst design. This work provides insights into the rational design of heterogeneous nanocatalysts in tandem reactions.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s40843-019-9428-8", 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.9416742", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.8153776", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.8900316", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.8158906", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1135897", 
        "issn": [
          "2095-8226", 
          "2199-4501"
        ], 
        "name": "Science China Materials", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "62"
      }
    ], 
    "keywords": [
      "hydrogen transfer reactions", 
      "formic acid decomposition", 
      "transfer reactions", 
      "tandem reaction", 
      "edge sites", 
      "active site", 
      "tetrahedral nanocrystals", 
      "step reaction", 
      "acid decomposition", 
      "cubic nanocrystals", 
      "efficient tandem reaction", 
      "specific active sites", 
      "single-step reaction", 
      "active edge sites", 
      "entire reaction process", 
      "nanocatalyst design", 
      "catalytic nanostructures", 
      "heterogeneous nanocatalyst", 
      "octahedral nanocrystals", 
      "tandem catalysis", 
      "hydrogenation reactions", 
      "nitrobenzene hydrogenation", 
      "tunable size", 
      "Pd nanocrystals", 
      "rational design", 
      "formic acid", 
      "catalytic efficiency", 
      "reaction process", 
      "plane sites", 
      "nanocrystals", 
      "high activity", 
      "comparable activity", 
      "reaction", 
      "hydrogenation", 
      "nanocatalysts", 
      "concept demonstration", 
      "decomposition", 
      "catalysis", 
      "nanostructures", 
      "octahedra", 
      "Herein", 
      "transformation efficiency", 
      "different shapes", 
      "sites", 
      "acid", 
      "step", 
      "efficiency", 
      "activity", 
      "process", 
      "overall performance", 
      "entire process", 
      "size", 
      "investigation", 
      "shape", 
      "work", 
      "insights", 
      "design", 
      "cube", 
      "performance", 
      "demonstration", 
      "proof", 
      "integration", 
      "place", 
      "safety implications", 
      "spatial integration", 
      "location", 
      "implications", 
      "findings", 
      "consistency"
    ], 
    "name": "Tandem nanocatalyst design: putting two step-reaction sites into one location towards enhanced hydrogen transfer reactions", 
    "pagination": "1297-1305", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1113671057"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s40843-019-9428-8"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s40843-019-9428-8", 
      "https://app.dimensions.ai/details/publication/pub.1113671057"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:38", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_792.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s40843-019-9428-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s40843-019-9428-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s40843-019-9428-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s40843-019-9428-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s40843-019-9428-8'


 

This table displays all metadata directly associated to this object as RDF triples.

243 TRIPLES      21 PREDICATES      102 URIs      85 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s40843-019-9428-8 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nc964969d27444697a0e881a20e5dba34
4 schema:citation sg:pub.10.1007/s11426-018-9322-9
5 sg:pub.10.1007/s12274-015-0722-1
6 sg:pub.10.1007/s12274-016-1053-6
7 sg:pub.10.1038/nchem.1018
8 sg:pub.10.1038/nchem.1621
9 sg:pub.10.1038/nmat1734
10 sg:pub.10.1038/nnano.2010.235
11 sg:pub.10.1038/nnano.2011.42
12 sg:pub.10.1038/s41560-018-0229-6
13 schema:datePublished 2019-04-23
14 schema:datePublishedReg 2019-04-23
15 schema:description Efficient tandem reactions on a single catalytic nanostructure would be beneficial to improving chemical transformation efficiency and reducing safety implications. It is imperative to identify the active sites for each single step reaction so that the entire reaction process can be optimized by designing and integrating the sites. Herein, hydrogen transfer reaction is taken as a proof-of-concept demonstration to show that the spatial integration of active sites is important to the catalytic efficiency of the entire process in tandem reactions. We identified specific active sites (i.e., various sites at faces versus corners and edges) for formic acid decomposition and alkene/nitrobenzene hydrogenation—the two steps in hydrogen transfer reactions, by employing three different shapes of Pd nanocrystals in tunable sizes. The investigation reveals that the decomposition of formic acid occurs preferentially at the edge sites of cubic nanocrystal and the plane sites of octahedral/tetrahedral nanocrystals, while the hydrogenation takes place mainly at the edge sites of both cubic and octahedral/tetrahedral nanocrystals. The consistency of active edge sites during different step reactions enables cubic nanocrystals to exhibit a higher activity than octahedral nanocrystals in hydrogen transfer reactions, although octahedrons offer comparable activities to cubes in formic acid decomposition and hydrogenation reactions. Guided by these findings, we further improved the overall performance of tandem catalysis by specifically promoting the limiting step through nanocatalyst design. This work provides insights into the rational design of heterogeneous nanocatalysts in tandem reactions.
16 schema:genre article
17 schema:isAccessibleForFree true
18 schema:isPartOf Nd949be07aa414be3a0f878fcc2a73793
19 Nfa03ff0c5fa54974839e1607221a4cdd
20 sg:journal.1135897
21 schema:keywords Herein
22 Pd nanocrystals
23 acid
24 acid decomposition
25 active edge sites
26 active site
27 activity
28 catalysis
29 catalytic efficiency
30 catalytic nanostructures
31 comparable activity
32 concept demonstration
33 consistency
34 cube
35 cubic nanocrystals
36 decomposition
37 demonstration
38 design
39 different shapes
40 edge sites
41 efficiency
42 efficient tandem reaction
43 entire process
44 entire reaction process
45 findings
46 formic acid
47 formic acid decomposition
48 heterogeneous nanocatalyst
49 high activity
50 hydrogen transfer reactions
51 hydrogenation
52 hydrogenation reactions
53 implications
54 insights
55 integration
56 investigation
57 location
58 nanocatalyst design
59 nanocatalysts
60 nanocrystals
61 nanostructures
62 nitrobenzene hydrogenation
63 octahedra
64 octahedral nanocrystals
65 overall performance
66 performance
67 place
68 plane sites
69 process
70 proof
71 rational design
72 reaction
73 reaction process
74 safety implications
75 shape
76 single-step reaction
77 sites
78 size
79 spatial integration
80 specific active sites
81 step
82 step reaction
83 tandem catalysis
84 tandem reaction
85 tetrahedral nanocrystals
86 transfer reactions
87 transformation efficiency
88 tunable size
89 work
90 schema:name Tandem nanocatalyst design: putting two step-reaction sites into one location towards enhanced hydrogen transfer reactions
91 schema:pagination 1297-1305
92 schema:productId N87328f9d305642a5a88f323cb0b53940
93 Nbba44c5b69c444cdb02d8cdcd653ca66
94 schema:sameAs https://app.dimensions.ai/details/publication/pub.1113671057
95 https://doi.org/10.1007/s40843-019-9428-8
96 schema:sdDatePublished 2022-12-01T06:38
97 schema:sdLicense https://scigraph.springernature.com/explorer/license/
98 schema:sdPublisher N96910874c0cb42b494fbc428870ecba1
99 schema:url https://doi.org/10.1007/s40843-019-9428-8
100 sgo:license sg:explorer/license/
101 sgo:sdDataset articles
102 rdf:type schema:ScholarlyArticle
103 N078ac7a5e49f49fb98ef1586d667c51e rdf:first sg:person.0706525746.11
104 rdf:rest Nc3b30d09ec3e4fc699727f64dc4ef25d
105 N18877f86a90f494b80710637fe73f71f rdf:first sg:person.011573774737.45
106 rdf:rest N078ac7a5e49f49fb98ef1586d667c51e
107 N2816759a1b5847e79771c97345378e56 rdf:first sg:person.01165733230.24
108 rdf:rest N5dc37e223b25467ebfc63d40af5bc090
109 N5dc37e223b25467ebfc63d40af5bc090 rdf:first sg:person.01277070523.33
110 rdf:rest Ne33560190bd142db904987742f544d0f
111 N87328f9d305642a5a88f323cb0b53940 schema:name dimensions_id
112 schema:value pub.1113671057
113 rdf:type schema:PropertyValue
114 N96910874c0cb42b494fbc428870ecba1 schema:name Springer Nature - SN SciGraph project
115 rdf:type schema:Organization
116 N9ebda0a535aa413bb8604c4fbceb47c7 rdf:first sg:person.0732554276.11
117 rdf:rest N2816759a1b5847e79771c97345378e56
118 Naa29502135384df7af2426230c707df6 rdf:first sg:person.0640412546.43
119 rdf:rest Nb3276b4751ad413eb956521e4f502211
120 Nb3276b4751ad413eb956521e4f502211 rdf:first sg:person.0734146202.61
121 rdf:rest Nfb99fcf620114bbb8e30df07008ff073
122 Nbba44c5b69c444cdb02d8cdcd653ca66 schema:name doi
123 schema:value 10.1007/s40843-019-9428-8
124 rdf:type schema:PropertyValue
125 Nc3b30d09ec3e4fc699727f64dc4ef25d rdf:first sg:person.07372524330.97
126 rdf:rest N9ebda0a535aa413bb8604c4fbceb47c7
127 Nc964969d27444697a0e881a20e5dba34 rdf:first sg:person.01157173346.33
128 rdf:rest N18877f86a90f494b80710637fe73f71f
129 Nd949be07aa414be3a0f878fcc2a73793 schema:volumeNumber 62
130 rdf:type schema:PublicationVolume
131 Ne33560190bd142db904987742f544d0f rdf:first sg:person.010765465330.00
132 rdf:rest Naa29502135384df7af2426230c707df6
133 Nfa03ff0c5fa54974839e1607221a4cdd schema:issueNumber 9
134 rdf:type schema:PublicationIssue
135 Nfb99fcf620114bbb8e30df07008ff073 rdf:first sg:person.0600113217.27
136 rdf:rest rdf:nil
137 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
138 schema:name Chemical Sciences
139 rdf:type schema:DefinedTerm
140 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
141 schema:name Physical Chemistry (incl. Structural)
142 rdf:type schema:DefinedTerm
143 sg:grant.8153776 http://pending.schema.org/fundedItem sg:pub.10.1007/s40843-019-9428-8
144 rdf:type schema:MonetaryGrant
145 sg:grant.8158906 http://pending.schema.org/fundedItem sg:pub.10.1007/s40843-019-9428-8
146 rdf:type schema:MonetaryGrant
147 sg:grant.8900316 http://pending.schema.org/fundedItem sg:pub.10.1007/s40843-019-9428-8
148 rdf:type schema:MonetaryGrant
149 sg:grant.9416742 http://pending.schema.org/fundedItem sg:pub.10.1007/s40843-019-9428-8
150 rdf:type schema:MonetaryGrant
151 sg:journal.1135897 schema:issn 2095-8226
152 2199-4501
153 schema:name Science China Materials
154 schema:publisher Springer Nature
155 rdf:type schema:Periodical
156 sg:person.010765465330.00 schema:affiliation grid-institutes:grid.511309.f
157 schema:familyName Liu
158 schema:givenName Panyiming
159 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010765465330.00
160 rdf:type schema:Person
161 sg:person.01157173346.33 schema:affiliation grid-institutes:grid.511309.f
162 schema:familyName You
163 schema:givenName Yang
164 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01157173346.33
165 rdf:type schema:Person
166 sg:person.011573774737.45 schema:affiliation grid-institutes:grid.511309.f
167 schema:familyName Huang
168 schema:givenName Hao
169 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011573774737.45
170 rdf:type schema:Person
171 sg:person.01165733230.24 schema:affiliation grid-institutes:grid.511309.f
172 schema:familyName Hu
173 schema:givenName Canyu
174 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01165733230.24
175 rdf:type schema:Person
176 sg:person.01277070523.33 schema:affiliation grid-institutes:grid.511309.f
177 schema:familyName Gao
178 schema:givenName Chao
179 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01277070523.33
180 rdf:type schema:Person
181 sg:person.0600113217.27 schema:affiliation grid-institutes:grid.511309.f
182 schema:familyName Xiong
183 schema:givenName Yujie
184 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0600113217.27
185 rdf:type schema:Person
186 sg:person.0640412546.43 schema:affiliation grid-institutes:grid.511309.f
187 schema:familyName Long
188 schema:givenName Ran
189 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0640412546.43
190 rdf:type schema:Person
191 sg:person.0706525746.11 schema:affiliation grid-institutes:grid.440650.3
192 schema:familyName Mao
193 schema:givenName Keke
194 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0706525746.11
195 rdf:type schema:Person
196 sg:person.0732554276.11 schema:affiliation grid-institutes:grid.511309.f
197 schema:familyName Wu
198 schema:givenName Di
199 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732554276.11
200 rdf:type schema:Person
201 sg:person.0734146202.61 schema:affiliation grid-institutes:grid.511309.f
202 schema:familyName Wu
203 schema:givenName Xiaojun
204 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0734146202.61
205 rdf:type schema:Person
206 sg:person.07372524330.97 schema:affiliation grid-institutes:grid.511309.f
207 schema:familyName Xia
208 schema:givenName Song
209 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07372524330.97
210 rdf:type schema:Person
211 sg:pub.10.1007/s11426-018-9322-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1106054848
212 https://doi.org/10.1007/s11426-018-9322-9
213 rdf:type schema:CreativeWork
214 sg:pub.10.1007/s12274-015-0722-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022814395
215 https://doi.org/10.1007/s12274-015-0722-1
216 rdf:type schema:CreativeWork
217 sg:pub.10.1007/s12274-016-1053-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011220084
218 https://doi.org/10.1007/s12274-016-1053-6
219 rdf:type schema:CreativeWork
220 sg:pub.10.1038/nchem.1018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053103963
221 https://doi.org/10.1038/nchem.1018
222 rdf:type schema:CreativeWork
223 sg:pub.10.1038/nchem.1621 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041494845
224 https://doi.org/10.1038/nchem.1621
225 rdf:type schema:CreativeWork
226 sg:pub.10.1038/nmat1734 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026610046
227 https://doi.org/10.1038/nmat1734
228 rdf:type schema:CreativeWork
229 sg:pub.10.1038/nnano.2010.235 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017581888
230 https://doi.org/10.1038/nnano.2010.235
231 rdf:type schema:CreativeWork
232 sg:pub.10.1038/nnano.2011.42 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009316962
233 https://doi.org/10.1038/nnano.2011.42
234 rdf:type schema:CreativeWork
235 sg:pub.10.1038/s41560-018-0229-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1106420896
236 https://doi.org/10.1038/s41560-018-0229-6
237 rdf:type schema:CreativeWork
238 grid-institutes:grid.440650.3 schema:alternateName School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China
239 schema:name School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China
240 rdf:type schema:Organization
241 grid-institutes:grid.511309.f schema:alternateName Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China
242 schema:name Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230026, Hefei, China
243 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...