2D MOF Nanoflake-Assembled Spherical Microstructures for Enhanced Supercapacitor and Electrocatalysis Performances View Full Text


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Article Info

DATE

2017-10

AUTHORS

Huicong Xia, Jianan Zhang, Zhao Yang, Shiyu Guo, Shihui Guo, Qun Xu

ABSTRACT

Metal-organic frameworks (MOFs) are of great interest as potential electrochemically active materials. However, few studies have been conducted into understanding whether control of the shape and components of MOFs can optimize their electrochemical performances due to the rational realization of their shapes. Component control of MOFs remains a significant challenge. Herein, we demonstrate a solvothermal method to realize nanostructure engineering of 2D nanoflake MOFs. The hollow structures with Ni/Co- and Ni-MOF (denoted as Ni/Co-MOF nanoflakes and Ni-MOF nanoflakes) were assembled for their electrochemical performance optimizations in supercapacitors and in the oxygen reduction reaction (ORR). As a result, the Ni/Co-MOF nanoflakes exhibited remarkably enhanced performance with a specific capacitance of 530.4 F g-1 at 0.5 A g-1 in 1 M LiOH aqueous solution, much higher than that of Ni-MOF (306.8 F g-1) and ZIF-67 (168.3 F g-1), a good rate capability, and a robust cycling performance with no capacity fading after 2000 cycles. Ni/Co-MOF nanoflakes also showed improved electrocatalytic performance for the ORR compared to Ni-MOF and ZIF-67. The present work highlights the significant role of tuning 2D nanoflake ensembles of Ni/Co-MOF in accelerating electron and charge transportation for optimizing energy storage and conversion devices. More... »

PAGES

43

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s40820-017-0144-6

DOI

http://dx.doi.org/10.1007/s40820-017-0144-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084040795

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30393738


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