Corrosion Behaviour of a Non-equiatomic CoCrFeNiMo High-Entropy Alloy in H2S-Containing and H2S-Free Environments View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2022-09-20

AUTHORS

Zhu Wang, Guo-Hui Zhang, Yong Yao, Xue-Hua Fan, Jie Jin, Lei Zhang, Yan-Xia Du

ABSTRACT

The corrosion behaviour of a non-equiatomic CoCrFeNiMo high-entropy alloy (HEA) in H2S-containing and H2S-free environments was studied by electrochemical tests, surface characterization, and solution analysis. The results showed that the HEA exhibited primary and secondary passivation in the H2S-free environment, and the transition was owing to the enhanced dissolution of Fe species. Compared with the primary passive film, the Cr/Fe ratio in the secondary passive film increased at the expense of the selective dissolution of Fe. Therefore, the corrosion resistance of HEA decreased with the applied potential. Cr was the most stable element in the film of HEA, regardless of H2S. The presence of H2S accelerated the dissolution of all the cationic elements in the HEA. H2S promoted the formation of thicker but less protective surface film and induced the loss of passivity. More... »

PAGES

1-13

References to SciGraph publications

  • 2017-10-17. The intrinsic mechanism of corrosion resistance for FCC high entropy alloys in SCIENCE CHINA TECHNOLOGICAL SCIENCES
  • 2017-07-29. Investigation of the deterioration of passive films in H2S-containing solutions in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY AND MATERIALS
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/s40195-022-01466-8

    DOI

    http://dx.doi.org/10.1007/s40195-022-01466-8

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