Ontology type: schema:ScholarlyArticle
2017-07-05
AUTHORSP. K. Banipal, V. Singh, N. Kaur, R. Sharma, S. Thakur, M. Kaur, T. S. Banipal
ABSTRACTDensities ρ, sound velocities u, viscosities η, and refractive indices nD of 1,4-dioxane + (C1–C10) alkan-1-ols binary liquid mixtures have been measured at 298.15 K as a function of mole fraction by using vibrating-tube digital densimeter, multifrequency ultrasonic interferometer, Ubbelohde-type capillary viscometer and digital refractometer, respectively. From these experimental data, excess molar volumes VmE, excess molar isentropic compressibility Ks,mE, deviation in viscosity ∆η, refractive index ∆nD, excess Gibbs free energy of activation GE of viscous flow, and Grunberg and Nissan parameter d, have been obtained over the whole mole fraction range. The excess properties have been correlated using a Redlich–Kister type equation to obtain their coefficients and standard deviations. These parameters have been discussed in terms of the nature of various molecular interactions and structural effects due to the components of binary mixtures. The effect of increasing complexity of chain length of alkan-1-ols on excess properties has also been discussed. More... »
PAGES479-490
Proceedings of the National Academy of Sciences, India Section A: Physical Sciences
ISSUE4
VOLUME88
http://scigraph.springernature.com/pub.10.1007/s40010-017-0387-0
DOIhttp://dx.doi.org/10.1007/s40010-017-0387-0
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1090354272
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India",
"id": "http://www.grid.ac/institutes/grid.411894.1",
"name": [
"Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India"
],
"type": "Organization"
},
"familyName": "Banipal",
"givenName": "P. K.",
"id": "sg:person.016711051307.54",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016711051307.54"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India",
"id": "http://www.grid.ac/institutes/grid.411894.1",
"name": [
"Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India"
],
"type": "Organization"
},
"familyName": "Singh",
"givenName": "V.",
"id": "sg:person.011321233173.46",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011321233173.46"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India",
"id": "http://www.grid.ac/institutes/grid.411894.1",
"name": [
"Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India"
],
"type": "Organization"
},
"familyName": "Kaur",
"givenName": "N.",
"id": "sg:person.0772143222.77",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0772143222.77"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India",
"id": "http://www.grid.ac/institutes/grid.411894.1",
"name": [
"Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India"
],
"type": "Organization"
},
"familyName": "Sharma",
"givenName": "R.",
"id": "sg:person.01326245727.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01326245727.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India",
"id": "http://www.grid.ac/institutes/grid.411894.1",
"name": [
"Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India"
],
"type": "Organization"
},
"familyName": "Thakur",
"givenName": "S.",
"id": "sg:person.013370557735.73",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013370557735.73"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India",
"id": "http://www.grid.ac/institutes/grid.411894.1",
"name": [
"Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India"
],
"type": "Organization"
},
"familyName": "Kaur",
"givenName": "M.",
"id": "sg:person.0760213664.32",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0760213664.32"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India",
"id": "http://www.grid.ac/institutes/grid.411894.1",
"name": [
"Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India"
],
"type": "Organization"
},
"familyName": "Banipal",
"givenName": "T. S.",
"id": "sg:person.014116234145.42",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014116234145.42"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/s10765-009-0639-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040188937",
"https://doi.org/10.1007/s10765-009-0639-6"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/164799b0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014582460",
"https://doi.org/10.1038/164799b0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10765-005-8101-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1031102975",
"https://doi.org/10.1007/s10765-005-8101-x"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-07-05",
"datePublishedReg": "2017-07-05",
"description": "Densities \u03c1, sound velocities u, viscosities \u03b7, and refractive indices nD of 1,4-dioxane\u00a0+\u00a0(C1\u2013C10) alkan-1-ols binary liquid mixtures have been measured at 298.15\u00a0K as a function of mole fraction by using vibrating-tube digital densimeter, multifrequency ultrasonic interferometer, Ubbelohde-type capillary viscometer and digital refractometer, respectively. From these experimental data, excess molar volumes VmE, excess molar isentropic compressibility Ks,mE, deviation in viscosity \u2206\u03b7, refractive index \u2206nD, excess Gibbs free energy of activation GE of viscous flow, and Grunberg and Nissan parameter d, have been obtained over the whole mole fraction range. The excess properties have been correlated using a Redlich\u2013Kister type equation to obtain their coefficients and standard deviations. These parameters have been discussed in terms of the nature of various molecular interactions and structural effects due to the components of binary mixtures. The effect of increasing complexity of chain length of alkan-1-ols on excess properties has also been discussed.",
"genre": "article",
"id": "sg:pub.10.1007/s40010-017-0387-0",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1136247",
"issn": [
"0369-8203",
"2250-1762"
],
"name": "Proceedings of the National Academy of Sciences, India Section A: Physical Sciences",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "4",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "88"
}
],
"keywords": [
"excess molar isentropic compressibilities KS",
"multifrequency ultrasonic interferometer",
"physico-chemical studies",
"Ubbelohde-type capillary viscometer",
"Gibbs free energy",
"excess properties",
"excess Gibbs free energy",
"binary mixtures",
"chain length",
"molecular interactions",
"refractive index",
"free energy",
"sound velocity u",
"molar isentropic compressibility KS",
"structural effects",
"dioxane",
"liquid mixtures",
"binary liquid mixtures",
"Redlich\u2013Kister type equation",
"ultrasonic interferometer",
"vibrating-tube digital densimeter",
"isentropic compressibility KS",
"mixture",
"capillary viscometer",
"viscosity \u03b7",
"parameter D",
"fraction range",
"properties",
"digital densimeter",
"standard deviation",
"experimental data",
"density \u03c1",
"viscosity",
"viscometer",
"energy",
"interaction",
"viscous flow",
"ME",
"interferometer",
"refractometer",
"range",
"deviation",
"Ge",
"nature",
"fraction",
"velocity u",
"effect",
"coefficient",
"digital refractometer",
"Grunberg",
"length",
"KS",
"parameters",
"type equation",
"components",
"excess molar volumes VmE",
"densimeter",
"VmE",
"equations",
"study",
"terms",
"index",
"function",
"flow",
"data",
"complexity"
],
"name": "Physico-Chemical Studies on Binary Mixtures of 1,4-Dioxane and Alkan-1-ols at 298.15 K",
"pagination": "479-490",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1090354272"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s40010-017-0387-0"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s40010-017-0387-0",
"https://app.dimensions.ai/details/publication/pub.1090354272"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T17:05",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_746.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s40010-017-0387-0"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s40010-017-0387-0'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s40010-017-0387-0'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s40010-017-0387-0'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s40010-017-0387-0'
This table displays all metadata directly associated to this object as RDF triples.
177 TRIPLES
21 PREDICATES
93 URIs
82 LITERALS
6 BLANK NODES