Synthesis, characterization, Hirshfeld surface analysis and theoretical calculation of new organic–inorganic hybrid material: (C4H7N2)6[As2W18O62]·4H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-04

AUTHORS

Marwa Dhifi, Safa Thabet, Ali Harchani, Amor Haddad

ABSTRACT

New hybrid arsenotungstates based on Dawson polyanions [C4H7N2]6[As2W18O62]·4H2O (1) have been isolated by conventional solution method and characterized by single-crystal X-ray diffraction, infrared spectrum and UV–visible spectroscopies and thermogravimetric analysis. Hirshfeld surface analysis was performed to study the intermolecular interactions. Compound 1 crystallizes in hexagonal system, in a P-3 space group, with cell parameters a = 20.2904(2) Å, b = 20.2904(2) Å, c = 16.8246(2) Å, and a V = 5998.38(11) Å3. Compound 1 exhibits a three-dimensional chain constructed from Well–Dawson anions linked together with (C4H7N2)+ cations and water molecules. More... »

PAGES

777-784

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s13738-018-1554-1

DOI

http://dx.doi.org/10.1007/s13738-018-1554-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110192325


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