Cyclopentene-fused [C60]-fullerenes: synthesis and electrochemical properties View Full Text


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Article Info

DATE

2018-05-11

AUTHORS

Ilshat M. Sakhautdinov, Rauilya N. Malikova, Yulya N. Biglova, Rail A. Khusnutdinov, Aynur M. Gumerov, Edvard M. Khamitov, Sergey P. Ivanov, Marat S. Yunusov

ABSTRACT

New cyclopentene-fused [C60]-fullerene derivatives containing terpene moieties have been synthesized by [3 + 2]-addition to fullerene C60. All obtained products were fully characterized by 1H- and 13C-NMR, IR, and MS. The electrochemical properties have been studied by cyclic voltammograms (CV), combined with absorption spectra, which are consistent with those obtained from density functional theory (DFT) calculations. It was found that all fulleropyrrolidines showed very similar absorption spectra, orbital energies, in which electron densities in both the LUMO and HOMO are mainly located on the fullerene cage, suggesting that C60 act as the acceptor. All the compounds exhibited good thermal stability. All determined characteristics of fullerene conjugates were compared to [6,6]-phenyl-C61-butyric acid methyl ester ([60]PCBM), a popular fullerene-containing compound.Graphical abstract More... »

PAGES

1975-1985

References to SciGraph publications

  • 2012-06. Thermal oligomerization of methyl 4-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)buta-2,3-dienoate in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 2006-07-21. Electrochemically formed fullerene-based polymeric films in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s13738-018-1395-y

    DOI

    http://dx.doi.org/10.1007/s13738-018-1395-y

    DIMENSIONS

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