A new calix[4]arene Schiff base sensor for Hg2+ and Au3+ View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-07-16

AUTHORS

Shahabuddin Memon, Ashfaque Ali Bhatti, Asif Ali Bhatti, Ümmühan Ocak, Miraç Ocak

ABSTRACT

This article reports the selective sensing ability of a newly synthesized calix[4]arene Schiff base (C4TSB) derivative. C4TSB exhibited strong turn-off fluorescence affinity for Hg2+ and Au3+. The selective sensing ability of receptor was investigated in the presence of different co-existing competing ions. The limit of detection for Hg2+ and Au3+ was determined as 1.9 × 10−5 and 1.0 × 10−6 M, respectively. Receptor forms 1:1 stoichiometric complex with both metals and their binding constants were calculated as 7.9 × 103 M−1 for Hg2+ and 5.7 × 103 M−1 for Au3+. Complexes were also characterized through FT-IR spectroscopy. More... »

PAGES

2275-2282

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s13738-016-0946-3

DOI

http://dx.doi.org/10.1007/s13738-016-0946-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048035959


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