Synthesis and chromogenic behavior exploration of a new calix[4]arene derivative View Full Text


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Article Info

DATE

2015-05-23

AUTHORS

Shahabuddin Memon, Ashfaque Ali Bhatti, Asif Ali Bhatti, Ümmühan Ocak, Miraç Ocak

ABSTRACT

Presence of heavy metals is one of the major sources of environmental contamination. The widespread pollution of highly poisonous heavy metals can endanger our ecosystem thus posing a great threat to human health. Selective sensing and quantification of these toxins are fascinating areas of current research. In this regard, present work highlights the synthesis of 5,11,17,23-tetra-tert-butyl-25,27-di((2-amido(1-anthracene)ethyl)amidomethoxycalix[4]arene (3) and exploration of its selective chromogenic behavior toward toxic Hg2+. Complexation study of (3) was carried out by examining the effect of various metal ions including Li+, Na+, K+, Cs+, Ag+, Ba2+, Ca2+, Mn2+, Mg2+, Sr2+, Ni2+, Cd2+, Co2+, Cu2+, Hg2+, Pb2+, Zn2+, Fe2+, Fe3+ and Al3+ using UV–visible spectroscopy. Selective chromogenic ability of ligand (3) shows a remarkable sensitivity for Hg2+ even in the presence of various co-existing ions. The stoichiometric analysis, i.e. Job’s plot reveals that (3) forms a 1:1 complex with Hg2+. The selective chromogenic response for Hg2+ was confirmed by FT-IR spectroscopy.Graphical abstract More... »

PAGES

1739-1746

References to SciGraph publications

  • 1962-01. A pathological study of Minamata disease in Japan in ACTA NEUROPATHOLOGICA
  • 2011-03-04. Analytical Evaluation of Cu2+ Selective Behavior of calix[4]arene Derivative in JOURNAL OF FLUORESCENCE
  • 2003-09. Health Risks of Gold Miners: A Synoptic Review in ENVIRONMENTAL GEOCHEMISTRY AND HEALTH
  • 1981-02. Inorganic mercury (Hg2+) transport through lipid bilayer membranes in THE JOURNAL OF MEMBRANE BIOLOGY
  • 2011-01-08. Hg(II) Selective Complexation by Chromoionophoric Calix[4]arene Derivative in JOURNAL OF FLUORESCENCE
  • 2013-03-06. Bifunctional Calix[4]arene Sensor for Pb(II) and Cr2O72− Ions in JOURNAL OF FLUORESCENCE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s13738-015-0648-2

    DOI

    http://dx.doi.org/10.1007/s13738-015-0648-2

    DIMENSIONS

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