Bentonite filler effect on structure and properties of polystyrene-based composites View Full Text


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Article Info

DATE

2019-02

AUTHORS

Olga V. Alekseeva, Anna N. Rodionova, Nadezhda A. Bagrovskaya, Andrew V. Noskov, Alexander V. Agafonov

ABSTRACT

The current research focuses on the preparation and characterization of polystyrene/bentonite composite materials with improved physicochemical properties and biological activity. Bentonite particles were immobilized into the polystyrene matrix by mechanical dispersion, and composite films were obtained. New data on the structure and properties of polystyrene/bentonite composites were discovered using SEM, optical microscopy, XRD, IR and UV spectrometry, tensile and microbiological testing. The effect of the filling agent on morphology and crystal structure composites was revealed. Insertion of bentonite into polystyrene resulted in an increase in interplanar layer distance in clay. It was found that the adsorption kinetics of methylene blue by pure polymer and the polystyrene/bentonite composite films was controlled by the pseudo-first-order kinetic equation. Isotherms were in good agreement with Langmuir model. For a composite with 5 wt% filler content, the maximum monolayer adsorption capacity was ten times greater than in the unmodified polymer. It was concluded that the modification of polystyrene with bentonite resulted in development of new adsorption-active centers. The strengthening testing results showed that insertion of bentonite (5 wt%) into the polystyrene matrix resulted in improved tensile strength. In addition, the polystyrene/bentonite composite films showed an antifungal effect against Candida albicans. More... »

PAGES

1-11

References to SciGraph publications

  • 2018-09. Complex modification effect of linseed cake as an agricultural waste filler used in high density polyethylene composites in IRANIAN POLYMER JOURNAL
  • 2017-04. Hydroxyethyl cellulose/bentonite/magnetite hybrid materials: structure, physicochemical properties, and antifungal activity in CELLULOSE
  • 2014-09. Preparation, morphology and conductivity of polyacrylonitrile/multi-wall carbon nanotubes composite nanofibers in IRANIAN POLYMER JOURNAL
  • 2014-06. Effect on properties of PVDF-HFP based composite polymer electrolyte doped with nano-SiO2 in IRANIAN POLYMER JOURNAL
  • 2015-09. The mechanism of adsorption of zinc and cadmium ions onto bentonite clay in PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES
  • 2013-06. Preparation of polystyrene–clay nanocomposite by solution intercalation technique in BULLETIN OF MATERIALS SCIENCE
  • 2007-08. Estimation of structural and sorption characteristics of activated bentonite in COLLOID JOURNAL
  • 2018-06. Novel vinyl-modified sepiolite-based polymer nanocomposites: synthesis and characterization in IRANIAN POLYMER JOURNAL
  • 2008-10. Kinetics of formation of hierarchical nanostructures in polystyrene films containing fullerene in DOKLADY PHYSICAL CHEMISTRY
  • 2004-01. Citation review of Lagergren kinetic rate equation on adsorption reactions in SCIENTOMETRICS
  • 2013-03. An investigation of the structural and thermodynamic properties of polystyrene fullerene-containing films in PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES
  • 2015-12. Cellulose nanocrystal–alginate hydrogel beads as novel adsorbents for organic dyes in aqueous solutions in CELLULOSE
  • Journal

    TITLE

    Iranian Polymer Journal

    ISSUE

    N/A

    VOLUME

    N/A

    Author Affiliations

    Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s13726-018-0683-9

    DOI

    http://dx.doi.org/10.1007/s13726-018-0683-9

    DIMENSIONS

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    37 schema:description The current research focuses on the preparation and characterization of polystyrene/bentonite composite materials with improved physicochemical properties and biological activity. Bentonite particles were immobilized into the polystyrene matrix by mechanical dispersion, and composite films were obtained. New data on the structure and properties of polystyrene/bentonite composites were discovered using SEM, optical microscopy, XRD, IR and UV spectrometry, tensile and microbiological testing. The effect of the filling agent on morphology and crystal structure composites was revealed. Insertion of bentonite into polystyrene resulted in an increase in interplanar layer distance in clay. It was found that the adsorption kinetics of methylene blue by pure polymer and the polystyrene/bentonite composite films was controlled by the pseudo-first-order kinetic equation. Isotherms were in good agreement with Langmuir model. For a composite with 5 wt% filler content, the maximum monolayer adsorption capacity was ten times greater than in the unmodified polymer. It was concluded that the modification of polystyrene with bentonite resulted in development of new adsorption-active centers. The strengthening testing results showed that insertion of bentonite (5 wt%) into the polystyrene matrix resulted in improved tensile strength. In addition, the polystyrene/bentonite composite films showed an antifungal effect against Candida albicans.
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