NiAl–Cr–Mo–W High-Entropy Systems Microstructural Verification, Solidification Considerations and Sliding Wear Response View Full Text


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Article Info

DATE

2022-01-24

AUTHORS

C. Mathiou, K. Giorspyros, E. Georgatis, A. Poulia, A. Avgeropoulos, A. E. Karantzalis

ABSTRACT

Three new high-entropy alloys of the Ni–Al–Cr–Mo–W system were produced by vacuum arc melting and assessed concerning their microstructure and sliding wear resistance. The NiAl content was kept constant at 60 at.%, and three alloys, namely NiAl–25Cr–7.5Mo–7.5W, NiAl–20Cr–10Mo–10W and NiAl–15Cr–12.5Mo–12.5W, were investigated by changing the relative ratios between Cr–Mo–W. All microstructures were found to consist of primary phases, eutectic microconstituent, a small amount of Al–Cr-based intermetallic phases and precipitated phases after spinodal decomposition. Adiabatic conditions, originated from the presence of tungsten with the highest melting point and its leading role in the initiation of solidification, were proved to affect the extent and morphology of features like the eutectic microconstituent. In particular, higher concentrations of W–Mo caused more powerful adiabatic conditions and, thus, thicker eutectic growing radially in a partitioning mode. The sliding wear response of the produced system seems to follow the classical sliding wear laws of Archard. This behaviour is further supported by multiple factors, such as the nature of the oxide phases being formed upon sliding and the integrity and rigidity of the interface between the primary and secondary phases. More... »

PAGES

7-20

References to SciGraph publications

  • 2016-07-25. Experimental Investigation and CALPHAD Assessment of the Eutectic Trough in the System NiAl-Cr-Mo in JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
  • 2018-01-19. Design of non-equiatomic medium-entropy alloys in SCIENTIFIC REPORTS
  • 2002-03. Effect of directionally solidified microstructures on the room-temperature fracture-toughness properties of Ni-33(at. pct)Al-33Cr-1Mo and Ni-33(at. pct)Al-31Cr-3Mo eutectic alloys grown at different solidification rates in METALLURGICAL AND MATERIALS TRANSACTIONS A
  • 1970-10. The effect of alloy additions on the rod-plate transition in the eutectic NiAl−Cr in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2013-09-27. Effect of Aluminum Content on Microstructure and Mechanical Properties of AlxCoCrFeMo0.5Ni High-Entropy Alloys in JOM
  • 2016-02-22. Microstructure and mechanical properties of NiAl-based hypereutectic alloy obtained by liquid metal cooling and zone melted liquid metal cooling directional solidification techniques in JOURNAL OF MATERIALS RESEARCH
  • 2019-09-27. Microstructural verification of the theoretically predicted morphologies of the NiAl–Cr pseudo-binary alloy systems and NiAl–Cr eutectic structure modification by Mo addition in SN APPLIED SCIENCES
  • 1970-05. The effect of solidification rate on structure and high-temperature strength of the eutectic NiAl-Cr in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 1985-10. The effectiveness of oxides in reducing sliding wear of alloys in OXIDATION OF METALS
  • 1995-05. Deformation and fracture of a directionally solidified NiAl–28Cr–6Mo eutectic alloy in JOURNAL OF MATERIALS RESEARCH
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    http://scigraph.springernature.com/pub.10.1007/s13632-021-00816-9

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    http://dx.doi.org/10.1007/s13632-021-00816-9

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