Interaction of Short Chain Phenylalkanoic Acids Within Cationic and Anionic Surfactants View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-07

AUTHORS

Kashif Naeem, S. W. H. Shah, Bushra Naseem, Syed Sakhawat Shah

ABSTRACT

Short chain phenylalkanoic acids have been investigated by UV spectroscopy to ascertain their solubilization into cationic surfactant, cetyltrimethylammonium bromide (CTAB), and anionic surfactant, sodium dodecyl sulfate (SDS). The increasing surfactant concentrations caused bathochromic shift in the spectra of additive acids. CTAB exhibited greater λmax shift, whereas λmax values are slightly altered in SDS solution. Moreover, the critical micelle concentration (CMC) of CTAB with and without phenylalkanoic acids was determined by conductivity measurements. The λmax and CMC data were used to calculate the electronic transition energy (ΔET) and Gibbs free energy change of micellization of CTAB in presence of additive acids. More... »

PAGES

1339-1346

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s13369-012-0240-3

DOI

http://dx.doi.org/10.1007/s13369-012-0240-3

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https://app.dimensions.ai/details/publication/pub.1027536640


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