N-Centered Odd-Electron Ions Formation from Collision-Induced Dissociation of Electrospray Ionization Generated Even-Electron Ions: Single Electron Transfer via Ion/Neutral Complex in ... View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2011-09

AUTHORS

Yunfeng Chai, Hezhi Sun, Yuanjiang Pan, Cuirong Sun

ABSTRACT

Single electron transfer (SET) via ion/neutral complex (INC) was proposed and confirmed to be the key step in the formation of N-centered odd-electron ions from fragmentation of protonated even-electron ions in the present study. Upon collisional activation, the model compounds, protonated N,N'-dibenzylpiperazine and protonated N-benzylpiperazines initially dissociated to form intermediate INCs consisting of N-benzylpiperazine (or piperazine) and benzyl cation. In these ion/neutral complexes, SET reaction and direct separation as well as other reactions were observed and characterized experimentally and theoretically. Density functional theory calculations demonstrated that the energy requirement for homolysis of the precursor ion was so large that it could not be achieved, whereas the heterolytic dissociation followed by electron transfer via INC was energetically preferred. The SET process occurred only when the radical products were more stable than the separation products. The energy barrier for SET in the compounds studied was roughly estimated by comparison with other competing reactions. When the INC contained electron donor with lower ionization energy and electron acceptor with higher electron affinity, the SET reaction was more efficient. More... »

PAGES

1526-1533

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s13361-011-0176-y

DOI

http://dx.doi.org/10.1007/s13361-011-0176-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019509546

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/21953256


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Zhejiang University", 
          "id": "https://www.grid.ac/institutes/grid.13402.34", 
          "name": [
            "Department of Chemistry, Zhejiang University, 310027, Hangzhou, Zhejiang, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chai", 
        "givenName": "Yunfeng", 
        "id": "sg:person.01172511456.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172511456.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zhejiang University", 
          "id": "https://www.grid.ac/institutes/grid.13402.34", 
          "name": [
            "Department of Chemistry, Zhejiang University, 310027, Hangzhou, Zhejiang, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sun", 
        "givenName": "Hezhi", 
        "id": "sg:person.0761361337.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0761361337.26"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zhejiang University", 
          "id": "https://www.grid.ac/institutes/grid.13402.34", 
          "name": [
            "Department of Chemistry, Zhejiang University, 310027, Hangzhou, Zhejiang, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pan", 
        "givenName": "Yuanjiang", 
        "id": "sg:person.0646446001.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0646446001.43"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zhejiang University", 
          "id": "https://www.grid.ac/institutes/grid.13402.34", 
          "name": [
            "Department of Chemistry, Zhejiang University, 310027, Hangzhou, Zhejiang, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sun", 
        "givenName": "Cuirong", 
        "id": "sg:person.01016253347.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01016253347.88"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/oms.1210150202", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001850734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/oms.1210150202", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001850734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.200601561", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002212320"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mas.1280070402", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002635286"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mas.1280070402", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002635286"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/rcm.4108", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003664026"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/rcm.4108", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003664026"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0009-2614(94)87099-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004706251"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1770", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005103148"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1016/j.jasms.2009.09.023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009566121", 
          "https://doi.org/10.1016/j.jasms.2009.09.023"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1091", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010866282"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.5012/jkcs.2005.49.3.247", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011328555"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1706", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011336287"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1706", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011336287"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/rcm.4393", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011480804"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b907236e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013458444"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.theochem.2006.03.012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018728321"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1016/j.jasms.2009.12.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018799776", 
          "https://doi.org/10.1016/j.jasms.2009.12.005"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/rcm.3271", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024865611"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1731", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028890745"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1731", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028890745"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1234", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029696933"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1600", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030413544"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1016/j.jasms.2009.11.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031196915", 
          "https://doi.org/10.1016/j.jasms.2009.11.004"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/oms.1210270404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031475097"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/oms.1210270404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031475097"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1089", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034420614"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jphotochem.2005.12.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036181460"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/oms.1210160408", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041706650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/oms.1210160408", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041706650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/oms.1210260419", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043324382"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/oms.1210260419", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043324382"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.537", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044636917"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ijms.2010.10.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045349681"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mas.1280110302", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045986203"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mas.1280110302", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045986203"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1016/j.jasms.2008.08.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046169980", 
          "https://doi.org/10.1016/j.jasms.2008.08.002"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1847", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048431198"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1847", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048431198"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1672", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049608681"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1672", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049608681"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jms.1461", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051303185"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr068070x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053773437"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr068070x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053773437"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar00012a002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055148241"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar00115a004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055149056"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar700256a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055151734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar700256a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055151734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00220a059", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055715305"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00403a064", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055729762"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo100761k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056025101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo100761k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056025101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp031328s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056052886"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp031328s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056052886"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp073950g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056072740"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp073950g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056072740"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp970142o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056124064"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp970142o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056124064"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2011-09", 
    "datePublishedReg": "2011-09-01", 
    "description": "Single electron transfer (SET) via ion/neutral complex (INC) was proposed and confirmed to be the key step in the formation of N-centered odd-electron ions from fragmentation of protonated even-electron ions in the present study. Upon collisional activation, the model compounds, protonated N,N'-dibenzylpiperazine and protonated N-benzylpiperazines initially dissociated to form intermediate INCs consisting of N-benzylpiperazine (or piperazine) and benzyl cation. In these ion/neutral complexes, SET reaction and direct separation as well as other reactions were observed and characterized experimentally and theoretically. Density functional theory calculations demonstrated that the energy requirement for homolysis of the precursor ion was so large that it could not be achieved, whereas the heterolytic dissociation followed by electron transfer via INC was energetically preferred. The SET process occurred only when the radical products were more stable than the separation products. The energy barrier for SET in the compounds studied was roughly estimated by comparison with other competing reactions. When the INC contained electron donor with lower ionization energy and electron acceptor with higher electron affinity, the SET reaction was more efficient.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s13361-011-0176-y", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.4951202", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.6977045", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1100508", 
        "issn": [
          "1044-0305", 
          "1879-1123"
        ], 
        "name": "Journal of The American Society for Mass Spectrometry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "22"
      }
    ], 
    "name": "N-Centered Odd-Electron Ions Formation from Collision-Induced Dissociation of Electrospray Ionization Generated Even-Electron Ions: Single Electron Transfer via Ion/Neutral Complex in the Fragmentation of Protonated N,N\u2032-Dibenzylpiperazines and Protonated N-Benzylpiperazines", 
    "pagination": "1526-1533", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "5cf4f523d8738d62212f35024deeaab0038ec1029320a86071e7636bc859c4a9"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "21953256"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "9010412"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s13361-011-0176-y"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1019509546"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s13361-011-0176-y", 
      "https://app.dimensions.ai/details/publication/pub.1019509546"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T23:26", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8693_00000521.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs13361-011-0176-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s13361-011-0176-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s13361-011-0176-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s13361-011-0176-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s13361-011-0176-y'


 

This table displays all metadata directly associated to this object as RDF triples.

221 TRIPLES      21 PREDICATES      70 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s13361-011-0176-y schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N053784fedc7a43b3a5ba58e838919652
4 schema:citation sg:pub.10.1016/j.jasms.2008.08.002
5 sg:pub.10.1016/j.jasms.2009.09.023
6 sg:pub.10.1016/j.jasms.2009.11.004
7 sg:pub.10.1016/j.jasms.2009.12.005
8 https://doi.org/10.1002/chem.200601561
9 https://doi.org/10.1002/jms.1089
10 https://doi.org/10.1002/jms.1091
11 https://doi.org/10.1002/jms.1234
12 https://doi.org/10.1002/jms.1461
13 https://doi.org/10.1002/jms.1600
14 https://doi.org/10.1002/jms.1672
15 https://doi.org/10.1002/jms.1706
16 https://doi.org/10.1002/jms.1731
17 https://doi.org/10.1002/jms.1770
18 https://doi.org/10.1002/jms.1847
19 https://doi.org/10.1002/jms.537
20 https://doi.org/10.1002/mas.1280070402
21 https://doi.org/10.1002/mas.1280110302
22 https://doi.org/10.1002/oms.1210150202
23 https://doi.org/10.1002/oms.1210160408
24 https://doi.org/10.1002/oms.1210260419
25 https://doi.org/10.1002/oms.1210270404
26 https://doi.org/10.1002/rcm.3271
27 https://doi.org/10.1002/rcm.4108
28 https://doi.org/10.1002/rcm.4393
29 https://doi.org/10.1016/0009-2614(94)87099-3
30 https://doi.org/10.1016/j.ijms.2010.10.006
31 https://doi.org/10.1016/j.jphotochem.2005.12.004
32 https://doi.org/10.1016/j.theochem.2006.03.012
33 https://doi.org/10.1021/ar00012a002
34 https://doi.org/10.1021/ar00115a004
35 https://doi.org/10.1021/ar700256a
36 https://doi.org/10.1021/cr068070x
37 https://doi.org/10.1021/ja00220a059
38 https://doi.org/10.1021/ja00403a064
39 https://doi.org/10.1021/jo100761k
40 https://doi.org/10.1021/jp031328s
41 https://doi.org/10.1021/jp073950g
42 https://doi.org/10.1021/jp970142o
43 https://doi.org/10.1039/b907236e
44 https://doi.org/10.5012/jkcs.2005.49.3.247
45 schema:datePublished 2011-09
46 schema:datePublishedReg 2011-09-01
47 schema:description Single electron transfer (SET) via ion/neutral complex (INC) was proposed and confirmed to be the key step in the formation of N-centered odd-electron ions from fragmentation of protonated even-electron ions in the present study. Upon collisional activation, the model compounds, protonated N,N'-dibenzylpiperazine and protonated N-benzylpiperazines initially dissociated to form intermediate INCs consisting of N-benzylpiperazine (or piperazine) and benzyl cation. In these ion/neutral complexes, SET reaction and direct separation as well as other reactions were observed and characterized experimentally and theoretically. Density functional theory calculations demonstrated that the energy requirement for homolysis of the precursor ion was so large that it could not be achieved, whereas the heterolytic dissociation followed by electron transfer via INC was energetically preferred. The SET process occurred only when the radical products were more stable than the separation products. The energy barrier for SET in the compounds studied was roughly estimated by comparison with other competing reactions. When the INC contained electron donor with lower ionization energy and electron acceptor with higher electron affinity, the SET reaction was more efficient.
48 schema:genre research_article
49 schema:inLanguage en
50 schema:isAccessibleForFree true
51 schema:isPartOf N964e393f0db54292949d895535d8472a
52 Nd63d5fee759c4db7973db794ebd94725
53 sg:journal.1100508
54 schema:name N-Centered Odd-Electron Ions Formation from Collision-Induced Dissociation of Electrospray Ionization Generated Even-Electron Ions: Single Electron Transfer via Ion/Neutral Complex in the Fragmentation of Protonated N,N′-Dibenzylpiperazines and Protonated N-Benzylpiperazines
55 schema:pagination 1526-1533
56 schema:productId Nded1ab1635324a9f8a6f0f0d99d0e022
57 Nef4b6534512b439d9dbed3c584e1b206
58 Nf0a5c9e1000343f69976e4fda146ca1a
59 Nf643816fc5724c20a22c08678197e8d8
60 Nf97a226e4e054e4db4bc413f7991ef78
61 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019509546
62 https://doi.org/10.1007/s13361-011-0176-y
63 schema:sdDatePublished 2019-04-10T23:26
64 schema:sdLicense https://scigraph.springernature.com/explorer/license/
65 schema:sdPublisher N3464f6a2311a49eb84fa5579bcff55e7
66 schema:url http://link.springer.com/10.1007%2Fs13361-011-0176-y
67 sgo:license sg:explorer/license/
68 sgo:sdDataset articles
69 rdf:type schema:ScholarlyArticle
70 N053784fedc7a43b3a5ba58e838919652 rdf:first sg:person.01172511456.25
71 rdf:rest N157b55328b5044c9bc392389e3ad0a43
72 N157b55328b5044c9bc392389e3ad0a43 rdf:first sg:person.0761361337.26
73 rdf:rest N605d0ca87f1540d783748697c445b501
74 N1bfa0b0e626b4e2bb62b6ad242ba2a9a rdf:first sg:person.01016253347.88
75 rdf:rest rdf:nil
76 N3464f6a2311a49eb84fa5579bcff55e7 schema:name Springer Nature - SN SciGraph project
77 rdf:type schema:Organization
78 N605d0ca87f1540d783748697c445b501 rdf:first sg:person.0646446001.43
79 rdf:rest N1bfa0b0e626b4e2bb62b6ad242ba2a9a
80 N964e393f0db54292949d895535d8472a schema:issueNumber 9
81 rdf:type schema:PublicationIssue
82 Nd63d5fee759c4db7973db794ebd94725 schema:volumeNumber 22
83 rdf:type schema:PublicationVolume
84 Nded1ab1635324a9f8a6f0f0d99d0e022 schema:name readcube_id
85 schema:value 5cf4f523d8738d62212f35024deeaab0038ec1029320a86071e7636bc859c4a9
86 rdf:type schema:PropertyValue
87 Nef4b6534512b439d9dbed3c584e1b206 schema:name pubmed_id
88 schema:value 21953256
89 rdf:type schema:PropertyValue
90 Nf0a5c9e1000343f69976e4fda146ca1a schema:name nlm_unique_id
91 schema:value 9010412
92 rdf:type schema:PropertyValue
93 Nf643816fc5724c20a22c08678197e8d8 schema:name dimensions_id
94 schema:value pub.1019509546
95 rdf:type schema:PropertyValue
96 Nf97a226e4e054e4db4bc413f7991ef78 schema:name doi
97 schema:value 10.1007/s13361-011-0176-y
98 rdf:type schema:PropertyValue
99 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
100 schema:name Chemical Sciences
101 rdf:type schema:DefinedTerm
102 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
103 schema:name Physical Chemistry (incl. Structural)
104 rdf:type schema:DefinedTerm
105 sg:grant.4951202 http://pending.schema.org/fundedItem sg:pub.10.1007/s13361-011-0176-y
106 rdf:type schema:MonetaryGrant
107 sg:grant.6977045 http://pending.schema.org/fundedItem sg:pub.10.1007/s13361-011-0176-y
108 rdf:type schema:MonetaryGrant
109 sg:journal.1100508 schema:issn 1044-0305
110 1879-1123
111 schema:name Journal of The American Society for Mass Spectrometry
112 rdf:type schema:Periodical
113 sg:person.01016253347.88 schema:affiliation https://www.grid.ac/institutes/grid.13402.34
114 schema:familyName Sun
115 schema:givenName Cuirong
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01016253347.88
117 rdf:type schema:Person
118 sg:person.01172511456.25 schema:affiliation https://www.grid.ac/institutes/grid.13402.34
119 schema:familyName Chai
120 schema:givenName Yunfeng
121 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172511456.25
122 rdf:type schema:Person
123 sg:person.0646446001.43 schema:affiliation https://www.grid.ac/institutes/grid.13402.34
124 schema:familyName Pan
125 schema:givenName Yuanjiang
126 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0646446001.43
127 rdf:type schema:Person
128 sg:person.0761361337.26 schema:affiliation https://www.grid.ac/institutes/grid.13402.34
129 schema:familyName Sun
130 schema:givenName Hezhi
131 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0761361337.26
132 rdf:type schema:Person
133 sg:pub.10.1016/j.jasms.2008.08.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046169980
134 https://doi.org/10.1016/j.jasms.2008.08.002
135 rdf:type schema:CreativeWork
136 sg:pub.10.1016/j.jasms.2009.09.023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009566121
137 https://doi.org/10.1016/j.jasms.2009.09.023
138 rdf:type schema:CreativeWork
139 sg:pub.10.1016/j.jasms.2009.11.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031196915
140 https://doi.org/10.1016/j.jasms.2009.11.004
141 rdf:type schema:CreativeWork
142 sg:pub.10.1016/j.jasms.2009.12.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018799776
143 https://doi.org/10.1016/j.jasms.2009.12.005
144 rdf:type schema:CreativeWork
145 https://doi.org/10.1002/chem.200601561 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002212320
146 rdf:type schema:CreativeWork
147 https://doi.org/10.1002/jms.1089 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034420614
148 rdf:type schema:CreativeWork
149 https://doi.org/10.1002/jms.1091 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010866282
150 rdf:type schema:CreativeWork
151 https://doi.org/10.1002/jms.1234 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029696933
152 rdf:type schema:CreativeWork
153 https://doi.org/10.1002/jms.1461 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051303185
154 rdf:type schema:CreativeWork
155 https://doi.org/10.1002/jms.1600 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030413544
156 rdf:type schema:CreativeWork
157 https://doi.org/10.1002/jms.1672 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049608681
158 rdf:type schema:CreativeWork
159 https://doi.org/10.1002/jms.1706 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011336287
160 rdf:type schema:CreativeWork
161 https://doi.org/10.1002/jms.1731 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028890745
162 rdf:type schema:CreativeWork
163 https://doi.org/10.1002/jms.1770 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005103148
164 rdf:type schema:CreativeWork
165 https://doi.org/10.1002/jms.1847 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048431198
166 rdf:type schema:CreativeWork
167 https://doi.org/10.1002/jms.537 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044636917
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1002/mas.1280070402 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002635286
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1002/mas.1280110302 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045986203
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1002/oms.1210150202 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001850734
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1002/oms.1210160408 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041706650
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1002/oms.1210260419 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043324382
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1002/oms.1210270404 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031475097
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1002/rcm.3271 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024865611
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1002/rcm.4108 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003664026
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1002/rcm.4393 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011480804
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1016/0009-2614(94)87099-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004706251
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1016/j.ijms.2010.10.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045349681
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1016/j.jphotochem.2005.12.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036181460
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1016/j.theochem.2006.03.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018728321
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1021/ar00012a002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055148241
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1021/ar00115a004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055149056
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1021/ar700256a schema:sameAs https://app.dimensions.ai/details/publication/pub.1055151734
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1021/cr068070x schema:sameAs https://app.dimensions.ai/details/publication/pub.1053773437
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1021/ja00220a059 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055715305
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1021/ja00403a064 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055729762
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1021/jo100761k schema:sameAs https://app.dimensions.ai/details/publication/pub.1056025101
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1021/jp031328s schema:sameAs https://app.dimensions.ai/details/publication/pub.1056052886
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1021/jp073950g schema:sameAs https://app.dimensions.ai/details/publication/pub.1056072740
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1021/jp970142o schema:sameAs https://app.dimensions.ai/details/publication/pub.1056124064
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1039/b907236e schema:sameAs https://app.dimensions.ai/details/publication/pub.1013458444
216 rdf:type schema:CreativeWork
217 https://doi.org/10.5012/jkcs.2005.49.3.247 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011328555
218 rdf:type schema:CreativeWork
219 https://www.grid.ac/institutes/grid.13402.34 schema:alternateName Zhejiang University
220 schema:name Department of Chemistry, Zhejiang University, 310027, Hangzhou, Zhejiang, China
221 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...