Influence of mixed 2-thiocytosine–ionic surfactants adsorption layers on kinetics and mechanism of Bi(III) ions electro reduction: use of the nanostructured ... View Full Text


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Article Info

DATE

2022-09-13

AUTHORS

Agnieszka Nosal-Wiercińska, Marlena Martyna, Małgorzata Wiśniewska

ABSTRACT

The nanostructured cyclically refreshable liquid amalgam film silver-based electrode (R-AgLAFE) was applied to study of the Bi(III) electrode process in the presence of 2-thiocytosine and selected ionic surfactants. The application of voltammetrictechniques (SWV, CV, DC), as well as electrochemical impedance spectroscopy (EIS) allowed the determination of the kinetic which in turn, defined the 2-thiocytosine catalytic effect and also their correlation in the presence of surfactants. The presence of mixed 2-thiocytosine-CTAB and 2-thiocytosine-SDS adsorption layers affects the mechanism and kinetics of Bi(III) ions electro-reduction process in chlorate(VII). CTAB and SDS change the dynamics of the catalytic impact of 2-thiocytosine on Bi(III) ions electro reduction. In both cases, the Bi–(RS–Hg) complex plays a key role, as it is the 2-thiocytosine that dominates in the establishment of the adsorption equilibria of the studied mixed adsorption layers. More... »

PAGES

1-9

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s13204-022-02605-4

DOI

http://dx.doi.org/10.1007/s13204-022-02605-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1150963998


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