Low-Cost and Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction: Environment-Friendly Three-Dimensional B, N Co-doped Graphene Aerogels View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-01

AUTHORS

Jingrui Han, Yanlin Zhang, Fushuang Niu, Tao Chen, Jingquan Liu, Yuanhong Xu

ABSTRACT

Nitrogen (N) and boron (B) co-doped graphene materials have been certified as promising catalyst for oxygen reduction reaction (ORR), since the dual doping of foreign atoms could induce a unique electronic structure in graphene and create a synergistic coupling effect between heteroatoms. However, previously reported B, N co-doped graphene materials suffered from shortcomings such as needing highly toxic precursors or high cost or complex preparation procedures. Herein, one highly efficient metal-free ORR catalyst, three-dimensional graphene aerogels (GAs) co-doped with B and N using economical and environmentally friendly melamine and boric acid as heteroatom precursors, was prepared through a one-step hydrothermal method. The as-prepared microporous B, N co-doped GAs showed excellent electrochemical catalytic performances for ORR under alkaline condition (0.1 M KOH) with a much more positive onset potential (0.994 V vs. RHE) than most of the existing B, N co-doped ones, a dominant four-electron transfer mechanism (n = 3.73 at 0.6 V), as well as excellent stability. Graphical Abstractᅟ ᅟ More... »

PAGES

1-7

Journal

TITLE

Electrocatalysis

ISSUE

N/A

VOLUME

N/A

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12678-018-0494-y

DOI

http://dx.doi.org/10.1007/s12678-018-0494-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107476168


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Qingdao University", 
          "id": "https://www.grid.ac/institutes/grid.410645.2", 
          "name": [
            "College of Life Sciences, College of Materials Science and Engineering, College Institute for Graphene Applied Technology Innovation, Qingdao University, 266071, Qingdao, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Han", 
        "givenName": "Jingrui", 
        "id": "sg:person.013333753664.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013333753664.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Department of Environmental Monitoring, Guangdong Polytechnic of Environmental Protection Engineering, 528216, Foshan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Yanlin", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Qingdao University", 
          "id": "https://www.grid.ac/institutes/grid.410645.2", 
          "name": [
            "College of Life Sciences, College of Materials Science and Engineering, College Institute for Graphene Applied Technology Innovation, Qingdao University, 266071, Qingdao, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Niu", 
        "givenName": "Fushuang", 
        "id": "sg:person.01020414513.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01020414513.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Qingdao University", 
          "id": "https://www.grid.ac/institutes/grid.410645.2", 
          "name": [
            "College of Life Sciences, College of Materials Science and Engineering, College Institute for Graphene Applied Technology Innovation, Qingdao University, 266071, Qingdao, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chen", 
        "givenName": "Tao", 
        "id": "sg:person.012400074223.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012400074223.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Qingdao University", 
          "id": "https://www.grid.ac/institutes/grid.410645.2", 
          "name": [
            "College of Life Sciences, College of Materials Science and Engineering, College Institute for Graphene Applied Technology Innovation, Qingdao University, 266071, Qingdao, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liu", 
        "givenName": "Jingquan", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Qingdao University", 
          "id": "https://www.grid.ac/institutes/grid.410645.2", 
          "name": [
            "College of Life Sciences, College of Materials Science and Engineering, College Institute for Graphene Applied Technology Innovation, Qingdao University, 266071, Qingdao, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xu", 
        "givenName": "Yuanhong", 
        "id": "sg:person.0775044271.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775044271.00"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.carbon.2013.07.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039397435"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2014.01.120", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050001124"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-01", 
    "datePublishedReg": "2019-01-01", 
    "description": "Nitrogen (N) and boron (B) co-doped graphene materials have been certified as promising catalyst for oxygen reduction reaction (ORR), since the dual doping of foreign atoms could induce a unique electronic structure in graphene and create a synergistic coupling effect between heteroatoms. However, previously reported B, N co-doped graphene materials suffered from shortcomings such as needing highly toxic precursors or high cost or complex preparation procedures. Herein, one highly efficient metal-free ORR catalyst, three-dimensional graphene aerogels (GAs) co-doped with B and N using economical and environmentally friendly melamine and boric acid as heteroatom precursors, was prepared through a one-step hydrothermal method. The as-prepared microporous B, N co-doped GAs showed excellent electrochemical catalytic performances for ORR under alkaline condition (0.1 M KOH) with a much more positive onset potential (0.994 V vs. RHE) than most of the existing B, N co-doped ones, a dominant four-electron transfer mechanism (n = 3.73 at 0.6 V), as well as excellent stability. Graphical Abstract\u115f \u115f", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s12678-018-0494-y", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136054", 
        "issn": [
          "1868-2529", 
          "1868-5994"
        ], 
        "name": "Electrocatalysis", 
        "type": "Periodical"
      }
    ], 
    "name": "Low-Cost and Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction: Environment-Friendly Three-Dimensional B, N Co-doped Graphene Aerogels", 
    "pagination": "1-7", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "1c1e263b27b0208f5c2d08dc370bbffccccb53f08abfa79fea893cc09d7252ea"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s12678-018-0494-y"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1107476168"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s12678-018-0494-y", 
      "https://app.dimensions.ai/details/publication/pub.1107476168"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:40", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000557.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs12678-018-0494-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s12678-018-0494-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s12678-018-0494-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s12678-018-0494-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s12678-018-0494-y'


 

This table displays all metadata directly associated to this object as RDF triples.

96 TRIPLES      21 PREDICATES      27 URIs      17 LITERALS      5 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s12678-018-0494-y schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N186476a3d23446b28835cf090ba17e31
4 schema:citation https://doi.org/10.1016/j.carbon.2013.07.006
5 https://doi.org/10.1016/j.jpowsour.2014.01.120
6 schema:datePublished 2019-01
7 schema:datePublishedReg 2019-01-01
8 schema:description Nitrogen (N) and boron (B) co-doped graphene materials have been certified as promising catalyst for oxygen reduction reaction (ORR), since the dual doping of foreign atoms could induce a unique electronic structure in graphene and create a synergistic coupling effect between heteroatoms. However, previously reported B, N co-doped graphene materials suffered from shortcomings such as needing highly toxic precursors or high cost or complex preparation procedures. Herein, one highly efficient metal-free ORR catalyst, three-dimensional graphene aerogels (GAs) co-doped with B and N using economical and environmentally friendly melamine and boric acid as heteroatom precursors, was prepared through a one-step hydrothermal method. The as-prepared microporous B, N co-doped GAs showed excellent electrochemical catalytic performances for ORR under alkaline condition (0.1 M KOH) with a much more positive onset potential (0.994 V vs. RHE) than most of the existing B, N co-doped ones, a dominant four-electron transfer mechanism (n = 3.73 at 0.6 V), as well as excellent stability. Graphical Abstractᅟ ᅟ
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf sg:journal.1136054
13 schema:name Low-Cost and Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction: Environment-Friendly Three-Dimensional B, N Co-doped Graphene Aerogels
14 schema:pagination 1-7
15 schema:productId N3a0ab9a321e74b679e0b046c230d0620
16 N4be3742c70a44dcaba0cb72137b715bf
17 N86638841d6d8476ca3a632d5c4351723
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1107476168
19 https://doi.org/10.1007/s12678-018-0494-y
20 schema:sdDatePublished 2019-04-10T22:40
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher N6fd927b33f85498383a924cced5c7ff1
23 schema:url https://link.springer.com/10.1007%2Fs12678-018-0494-y
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N0080372f363b4472b9380c7a6276a6b1 rdf:first sg:person.012400074223.81
28 rdf:rest N5ca333b16e694eab8fb587f0238ea970
29 N10af61be0d0949d59b878363c2d62cca schema:affiliation N48faa807436949708a0fcba9bcde2e73
30 schema:familyName Zhang
31 schema:givenName Yanlin
32 rdf:type schema:Person
33 N186476a3d23446b28835cf090ba17e31 rdf:first sg:person.013333753664.22
34 rdf:rest N7c60b4a6093043b5b57a8ff86c4b65cf
35 N34861b89e06f45be8c7d4dfdc8a0ce32 schema:affiliation https://www.grid.ac/institutes/grid.410645.2
36 schema:familyName Liu
37 schema:givenName Jingquan
38 rdf:type schema:Person
39 N3a0ab9a321e74b679e0b046c230d0620 schema:name doi
40 schema:value 10.1007/s12678-018-0494-y
41 rdf:type schema:PropertyValue
42 N48faa807436949708a0fcba9bcde2e73 schema:name Department of Environmental Monitoring, Guangdong Polytechnic of Environmental Protection Engineering, 528216, Foshan, China
43 rdf:type schema:Organization
44 N4be3742c70a44dcaba0cb72137b715bf schema:name readcube_id
45 schema:value 1c1e263b27b0208f5c2d08dc370bbffccccb53f08abfa79fea893cc09d7252ea
46 rdf:type schema:PropertyValue
47 N5ca333b16e694eab8fb587f0238ea970 rdf:first N34861b89e06f45be8c7d4dfdc8a0ce32
48 rdf:rest Ncee38d2a07824738b65c245ff3cbcbfa
49 N5d31c35c3e7d418186fa77f9aeec8bf5 rdf:first sg:person.01020414513.55
50 rdf:rest N0080372f363b4472b9380c7a6276a6b1
51 N6fd927b33f85498383a924cced5c7ff1 schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 N7c60b4a6093043b5b57a8ff86c4b65cf rdf:first N10af61be0d0949d59b878363c2d62cca
54 rdf:rest N5d31c35c3e7d418186fa77f9aeec8bf5
55 N86638841d6d8476ca3a632d5c4351723 schema:name dimensions_id
56 schema:value pub.1107476168
57 rdf:type schema:PropertyValue
58 Ncee38d2a07824738b65c245ff3cbcbfa rdf:first sg:person.0775044271.00
59 rdf:rest rdf:nil
60 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
61 schema:name Chemical Sciences
62 rdf:type schema:DefinedTerm
63 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
64 schema:name Physical Chemistry (incl. Structural)
65 rdf:type schema:DefinedTerm
66 sg:journal.1136054 schema:issn 1868-2529
67 1868-5994
68 schema:name Electrocatalysis
69 rdf:type schema:Periodical
70 sg:person.01020414513.55 schema:affiliation https://www.grid.ac/institutes/grid.410645.2
71 schema:familyName Niu
72 schema:givenName Fushuang
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01020414513.55
74 rdf:type schema:Person
75 sg:person.012400074223.81 schema:affiliation https://www.grid.ac/institutes/grid.410645.2
76 schema:familyName Chen
77 schema:givenName Tao
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012400074223.81
79 rdf:type schema:Person
80 sg:person.013333753664.22 schema:affiliation https://www.grid.ac/institutes/grid.410645.2
81 schema:familyName Han
82 schema:givenName Jingrui
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013333753664.22
84 rdf:type schema:Person
85 sg:person.0775044271.00 schema:affiliation https://www.grid.ac/institutes/grid.410645.2
86 schema:familyName Xu
87 schema:givenName Yuanhong
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775044271.00
89 rdf:type schema:Person
90 https://doi.org/10.1016/j.carbon.2013.07.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039397435
91 rdf:type schema:CreativeWork
92 https://doi.org/10.1016/j.jpowsour.2014.01.120 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050001124
93 rdf:type schema:CreativeWork
94 https://www.grid.ac/institutes/grid.410645.2 schema:alternateName Qingdao University
95 schema:name College of Life Sciences, College of Materials Science and Engineering, College Institute for Graphene Applied Technology Innovation, Qingdao University, 266071, Qingdao, China
96 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...