Studies on rovibrational energies in the ground state of nitrogen molecule using an algebraic approach View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-04

AUTHORS

Qunchao Fan, Weiguo Sun, Huidong Li, Hao Feng

ABSTRACT

An Algebraic Method (AMr) is used to evaluate rotational spectrum constants and energies using a known accurate experimental/theoretical rovibrational energy subset of a given rovibrational band for a diatomic electronic state. The AMr has been applied to study the rovibrational energies up to j = 40 in vibrational bands from v = 0 to 8 of X1Σg+ electronic state of N2 molecule. Calculations show that (i) the AMr not only reproduces the accurate experimental/theoretical energies, but also generates rotational constants and the Evj’s of high-lying rovibtational excited states; (ii) The accuracies of the rotational spectrum constants and energies are uniquely determined by the quality of the input experimental/theoretical data. More... »

PAGES

237-243

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12648-012-0054-x

DOI

http://dx.doi.org/10.1007/s12648-012-0054-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038481055


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