Environmental boundary and formation mechanism of different types of H2S corrosion products on pipeline steel View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-04

AUTHORS

Lei Zhang, Hui-xin Li, Feng-xian Shi, Jian-wei Yang, Li-hua Hu, Min-xu Lu

ABSTRACT

To establish an adequate thermodynamic model for the mechanism of formation of hydrogen sulfide (H2S) corrosion products, theoretical and experimental studies were combined in this work. The corrosion products of API X60 pipeline steel formed under different H2S corrosion conditions were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. A thermodynamic model was developed to clarify the environmental boundaries for the formation and transformation of different products. Presumably, a dividing line with a negative slope existed between mackinawite and pyrrhotite. Using experimental data presented in this study combined with previously published results, we validated the model to predict the formation of mackinawite and pyrrhotite on the basis of the laws of thermodynamics. The established relationship is expected to support the investigation of the H2S corrosion mechanism in the oil and gas industry. More... »

PAGES

401-409

References to SciGraph publications

  • 2009-11. Effect of H2S on Fe corrosion in CO2-saturated brine in JOURNAL OF MATERIALS SCIENCE
  • 2016-07. A Novel Emulsion Flow Loop for Investigating the Corrosion of X65 Steel in Emulsions with H2S/CO2 in JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
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    http://scigraph.springernature.com/pub.10.1007/s12613-017-1420-7

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    http://dx.doi.org/10.1007/s12613-017-1420-7

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