Influence of chromium on the initial corrosion behavior of low alloy steels in the CO2–O2–H2S–SO2 wet–dry corrosion environment of cargo ... View Full Text


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Article Info

DATE

2015-08

AUTHORS

Qing-he Zhao, Wei Liu, Jie Zhao, Dong Zhang, Peng-cheng Liu, Min-xu Lu

ABSTRACT

The influence of Cr on the initial corrosion behavior of low-alloy steels exposed to a CO2–O2–H2S–SO2 wet–dry corrosion environment was investigated using weight-loss measurements, scanning electron microscopy, N2 adsorption tests, X-ray diffraction analysis, and electrochemical impedance spectroscopy. The results show that the corrosion rate increases with increasing Cr content in samples subjected to corrosion for 21 d. However, the rust grain size decreases, its specific surface area increases, and it becomes more compact and denser with increasing Cr content, which indicates the enhanced protectivity of the rust. The results of charge transfer resistance (Rct) calculations indicate that higher Cr contents can accelerate the corrosion during the first 7 d and promote the formation of the enhanced protective inner rust after 14 d; the formed protective inner rust is responsible for the greater corrosion resistance during long-term exposure. More... »

PAGES

829-841

References to SciGraph publications

  • 2011-10. Effect of cooling parameters on the microstructure and properties of Mo-bearing and Cr-bearing steels in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY, AND MATERIALS
  • 2014-04. Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2 in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY, AND MATERIALS
  • 2010-06. Effects of chromium on the corrosion and electrochemical behaviors of ultra high strength steels in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY, AND MATERIALS
  • 2014-11. Effect of vanadium and chromium on the microstructural features of V-Cr-Mn-Ni spheroidal carbide cast irons in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY, AND MATERIALS
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