Synthesis and luminescent properties of Ln3+ (Ln3+ = Eu3+, Dy3+) -doped Bi2ZnB2O7 phosphors View Full Text


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Article Info

DATE

2012-02

AUTHORS

Qiuhong Zhang, Jing Wang, Haiyong Ni, Lingli Wang

ABSTRACT

The new phosphors Bi2ZnB2O7: Ln3+ (Ln3+ = Eu3+, Dy3+) were synthesized by solid-state reaction technique. The obtained phosphors were investigated by means of X-ray powder diffraction (XRD), photoluminescence excitation and emission spectra with the aim of enhancing the fundamental knowledge about the luminescent properties of Eu3+ and Dy3+ ions in the Bi2ZnB2O7 host lattice. XRD analysis shows that all these compounds are of a single phase of Bi2ZnB2O7. The excitation and emission spectra of Bi2ZnB2O7: Ln3+ (Ln3+ = Eu3+, Dy3+) at room temperature show the typical 4f-4f transitions of Eu3+ and Dy3+, respectively. The hypersensitive transitions of 5D0→7F2 (Eu3+) and 4F9/2→6H13/2 (Dy3+) are relatively higher than those of the insensitive transitions in Bi2ZnB2O7. It is conceivable that the Bi2ZnB2O7 structure provides asymmetry sites for activators (Eu3+, Dy3+). The optimum concentrations of Eu3+ and Dy3+ ions in Bi2ZnB2O7 phosphors are both x = 0.05. More... »

PAGES

35-38

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http://scigraph.springernature.com/pub.10.1007/s12598-012-0458-y

DOI

http://dx.doi.org/10.1007/s12598-012-0458-y

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