Working-in-tandem mechanism of multi-dopants in enhancing electrocatalytic nitrogen reduction reaction performance of carbon-based materials View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2021-01-20

AUTHORS

Wenqing Zhang, Keke Mao, Jingxiang Low, Hengjie Liu, Yanan Bo, Jun Ma, Qiaoxi Liu, Yawen Jiang, Jiuzhong Yang, Yang Pan, Zeming Qi, Ran Long, Li Song, Yujie Xiong

ABSTRACT

Developing carbon-based electrocatalysts with excellent N2 adsorption and activation capability holds the key to achieve highly efficient nitrogen reduction reaction (NRR) for reaching its practical application. Here, we report a highly active electrocatalyst—metal-free pyrrolic-N dominated N, S co-doped carbon (pyrr-NSC) for NRR. Based on theoretical and experimental results, it is confirmed that the N and S-dopants practice a working-in-tandem mechanism on pyrr-NSC, where the N-dopants are utilized to create electropositive C sites for enhancing N2 adsorption and the S-dopants are employed to induce electron backdonation for facilitating N2 activation. The synergistic effect of the pyrrolic-N and S-dopants can also suppress the irritating hydrogen evolution reaction, further boosting the NRR performance. This work gives an indication that the combination of two different dopants on electrocatalyst can enhance NRR performance by working in the two tandem steps—the adsorption and activation of N2 molecules, providing a new strategy for NRR electrocatalyst design. More... »

PAGES

3234-3239

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12274-021-3315-1

DOI

http://dx.doi.org/10.1007/s12274-021-3315-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1134739994


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Wenqing", 
        "id": "sg:person.010703006647.66", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010703006647.66"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China", 
          "id": "http://www.grid.ac/institutes/grid.440650.3", 
          "name": [
            "School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mao", 
        "givenName": "Keke", 
        "id": "sg:person.0706525746.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0706525746.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Low", 
        "givenName": "Jingxiang", 
        "id": "sg:person.011544674761.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011544674761.71"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liu", 
        "givenName": "Hengjie", 
        "id": "sg:person.011705527001.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011705527001.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bo", 
        "givenName": "Yanan", 
        "id": "sg:person.014633702607.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014633702607.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ma", 
        "givenName": "Jun", 
        "id": "sg:person.01166437473.30", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01166437473.30"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liu", 
        "givenName": "Qiaoxi", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jiang", 
        "givenName": "Yawen", 
        "id": "sg:person.010742077043.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010742077043.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yang", 
        "givenName": "Jiuzhong", 
        "id": "sg:person.011062530253.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011062530253.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pan", 
        "givenName": "Yang", 
        "id": "sg:person.011740043643.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011740043643.57"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Qi", 
        "givenName": "Zeming", 
        "id": "sg:person.01142173564.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01142173564.33"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Long", 
        "givenName": "Ran", 
        "id": "sg:person.0640412546.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0640412546.43"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.511309.f", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Song", 
        "givenName": "Li", 
        "id": "sg:person.01176070666.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01176070666.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Energy, Hefei Comprehensive National Science Center, 230031, Hefei, China", 
          "id": "http://www.grid.ac/institutes/grid.513034.0", 
          "name": [
            "Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China", 
            "Institute of Energy, Hefei Comprehensive National Science Center, 230031, Hefei, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xiong", 
        "givenName": "Yujie", 
        "id": "sg:person.0600113217.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0600113217.27"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/nchem.1476", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041048634", 
          "https://doi.org/10.1038/nchem.1476"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-020-2733-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1126625769", 
          "https://doi.org/10.1007/s12274-020-2733-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-019-2600-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1123578985", 
          "https://doi.org/10.1007/s12274-019-2600-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41467-018-08120-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1111564630", 
          "https://doi.org/10.1038/s41467-018-08120-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms12272", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013871943", 
          "https://doi.org/10.1038/ncomms12272"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-020-3049-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1130750510", 
          "https://doi.org/10.1007/s12274-020-3049-5"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2021-01-20", 
    "datePublishedReg": "2021-01-20", 
    "description": "Developing carbon-based electrocatalysts with excellent N2 adsorption and activation capability holds the key to achieve highly efficient nitrogen reduction reaction (NRR) for reaching its practical application. Here, we report a highly active electrocatalyst\u2014metal-free pyrrolic-N dominated N, S co-doped carbon (pyrr-NSC) for NRR. Based on theoretical and experimental results, it is confirmed that the N and S-dopants practice a working-in-tandem mechanism on pyrr-NSC, where the N-dopants are utilized to create electropositive C sites for enhancing N2 adsorption and the S-dopants are employed to induce electron backdonation for facilitating N2 activation. The synergistic effect of the pyrrolic-N and S-dopants can also suppress the irritating hydrogen evolution reaction, further boosting the NRR performance. This work gives an indication that the combination of two different dopants on electrocatalyst can enhance NRR performance by working in the two tandem steps\u2014the adsorption and activation of N2 molecules, providing a new strategy for NRR electrocatalyst design.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s12274-021-3315-1", 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.9416742", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.8158906", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.8905071", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1042464", 
        "issn": [
          "1998-0124", 
          "1998-0000"
        ], 
        "name": "Nano Research", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "14"
      }
    ], 
    "keywords": [
      "nitrogen reduction reaction", 
      "S dopants", 
      "electrocatalytic nitrogen reduction reaction performance", 
      "NRR performance", 
      "co-doped carbon", 
      "efficient nitrogen reduction reaction", 
      "carbon-based electrocatalysts", 
      "reduction reaction performance", 
      "carbon-based materials", 
      "hydrogen evolution reaction", 
      "N2 adsorption", 
      "reaction performance", 
      "evolution reaction", 
      "N dopants", 
      "reduction reaction", 
      "different dopants", 
      "electrocatalyst design", 
      "electron backdonation", 
      "experimental results", 
      "practical applications", 
      "electrocatalysts", 
      "adsorption", 
      "pyrrolic", 
      "synergistic effect", 
      "activation capability", 
      "performance", 
      "tandem steps", 
      "tandem mechanism", 
      "dopants", 
      "new strategy", 
      "C sites", 
      "materials", 
      "design", 
      "capability", 
      "N2 molecules", 
      "carbon", 
      "applications", 
      "work", 
      "reaction", 
      "mechanism", 
      "step", 
      "results", 
      "working", 
      "combination", 
      "effect", 
      "key", 
      "molecules", 
      "strategies", 
      "sites", 
      "backdonation", 
      "indications", 
      "activation"
    ], 
    "name": "Working-in-tandem mechanism of multi-dopants in enhancing electrocatalytic nitrogen reduction reaction performance of carbon-based materials", 
    "pagination": "3234-3239", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1134739994"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s12274-021-3315-1"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s12274-021-3315-1", 
      "https://app.dimensions.ai/details/publication/pub.1134739994"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:42", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_879.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s12274-021-3315-1"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s12274-021-3315-1'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s12274-021-3315-1'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s12274-021-3315-1'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s12274-021-3315-1'


 

This table displays all metadata directly associated to this object as RDF triples.

236 TRIPLES      21 PREDICATES      82 URIs      68 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s12274-021-3315-1 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Na69957c53e134fb387177f00ceaa0d6d
4 schema:citation sg:pub.10.1007/s12274-019-2600-8
5 sg:pub.10.1007/s12274-020-2733-9
6 sg:pub.10.1007/s12274-020-3049-5
7 sg:pub.10.1038/nchem.1476
8 sg:pub.10.1038/ncomms12272
9 sg:pub.10.1038/s41467-018-08120-x
10 schema:datePublished 2021-01-20
11 schema:datePublishedReg 2021-01-20
12 schema:description Developing carbon-based electrocatalysts with excellent N2 adsorption and activation capability holds the key to achieve highly efficient nitrogen reduction reaction (NRR) for reaching its practical application. Here, we report a highly active electrocatalyst—metal-free pyrrolic-N dominated N, S co-doped carbon (pyrr-NSC) for NRR. Based on theoretical and experimental results, it is confirmed that the N and S-dopants practice a working-in-tandem mechanism on pyrr-NSC, where the N-dopants are utilized to create electropositive C sites for enhancing N2 adsorption and the S-dopants are employed to induce electron backdonation for facilitating N2 activation. The synergistic effect of the pyrrolic-N and S-dopants can also suppress the irritating hydrogen evolution reaction, further boosting the NRR performance. This work gives an indication that the combination of two different dopants on electrocatalyst can enhance NRR performance by working in the two tandem steps—the adsorption and activation of N2 molecules, providing a new strategy for NRR electrocatalyst design.
13 schema:genre article
14 schema:isAccessibleForFree false
15 schema:isPartOf N4a38f52b70f34afca2b51dfe32b42627
16 Na659bc441d07493b88c014b9f4dd767d
17 sg:journal.1042464
18 schema:keywords C sites
19 N dopants
20 N2 adsorption
21 N2 molecules
22 NRR performance
23 S dopants
24 activation
25 activation capability
26 adsorption
27 applications
28 backdonation
29 capability
30 carbon
31 carbon-based electrocatalysts
32 carbon-based materials
33 co-doped carbon
34 combination
35 design
36 different dopants
37 dopants
38 effect
39 efficient nitrogen reduction reaction
40 electrocatalyst design
41 electrocatalysts
42 electrocatalytic nitrogen reduction reaction performance
43 electron backdonation
44 evolution reaction
45 experimental results
46 hydrogen evolution reaction
47 indications
48 key
49 materials
50 mechanism
51 molecules
52 new strategy
53 nitrogen reduction reaction
54 performance
55 practical applications
56 pyrrolic
57 reaction
58 reaction performance
59 reduction reaction
60 reduction reaction performance
61 results
62 sites
63 step
64 strategies
65 synergistic effect
66 tandem mechanism
67 tandem steps
68 work
69 working
70 schema:name Working-in-tandem mechanism of multi-dopants in enhancing electrocatalytic nitrogen reduction reaction performance of carbon-based materials
71 schema:pagination 3234-3239
72 schema:productId N7f2b11b8c0ad4e0caa6eb504a4d6fed9
73 N82da59b8a74f4532b62d18002d11e78e
74 schema:sameAs https://app.dimensions.ai/details/publication/pub.1134739994
75 https://doi.org/10.1007/s12274-021-3315-1
76 schema:sdDatePublished 2022-12-01T06:42
77 schema:sdLicense https://scigraph.springernature.com/explorer/license/
78 schema:sdPublisher N86c990639cea455580844a839e7b8700
79 schema:url https://doi.org/10.1007/s12274-021-3315-1
80 sgo:license sg:explorer/license/
81 sgo:sdDataset articles
82 rdf:type schema:ScholarlyArticle
83 N0791a361892a4b65adba899427f359db rdf:first sg:person.01142173564.33
84 rdf:rest N39d63ab1bac841daa327ce444275a9eb
85 N13d3de3058c54bb59b56d17c4a1fb484 rdf:first N755aa8e0f7d14717bfcc47843a63c9bc
86 rdf:rest Nc45e0880657c4d1dbe23dc237cd8e74d
87 N2c3eebea50874659b2630a32795dd7af rdf:first sg:person.011705527001.22
88 rdf:rest N7687b55c7c2f4ecba90be0c7cf9ed380
89 N3667a4272640427ba43510d936eebb10 rdf:first sg:person.0600113217.27
90 rdf:rest rdf:nil
91 N39d63ab1bac841daa327ce444275a9eb rdf:first sg:person.0640412546.43
92 rdf:rest N60a4f7604bc6475b9f4b2e19d5f398bc
93 N4a38f52b70f34afca2b51dfe32b42627 schema:volumeNumber 14
94 rdf:type schema:PublicationVolume
95 N60a4f7604bc6475b9f4b2e19d5f398bc rdf:first sg:person.01176070666.37
96 rdf:rest N3667a4272640427ba43510d936eebb10
97 N61d814c5f0654d41aaf377dc61842f70 rdf:first sg:person.0706525746.11
98 rdf:rest Nf9274b056db44f1d9ee629d7b4c40509
99 N641681e8dd06428b922b743f73b48459 rdf:first sg:person.011062530253.12
100 rdf:rest N8cd1111951d5483d997327963cf458ac
101 N755aa8e0f7d14717bfcc47843a63c9bc schema:affiliation grid-institutes:grid.511309.f
102 schema:familyName Liu
103 schema:givenName Qiaoxi
104 rdf:type schema:Person
105 N7687b55c7c2f4ecba90be0c7cf9ed380 rdf:first sg:person.014633702607.27
106 rdf:rest N9601940025f449f4a23662cd2d099d3e
107 N7f2b11b8c0ad4e0caa6eb504a4d6fed9 schema:name dimensions_id
108 schema:value pub.1134739994
109 rdf:type schema:PropertyValue
110 N82da59b8a74f4532b62d18002d11e78e schema:name doi
111 schema:value 10.1007/s12274-021-3315-1
112 rdf:type schema:PropertyValue
113 N86c990639cea455580844a839e7b8700 schema:name Springer Nature - SN SciGraph project
114 rdf:type schema:Organization
115 N8cd1111951d5483d997327963cf458ac rdf:first sg:person.011740043643.57
116 rdf:rest N0791a361892a4b65adba899427f359db
117 N9601940025f449f4a23662cd2d099d3e rdf:first sg:person.01166437473.30
118 rdf:rest N13d3de3058c54bb59b56d17c4a1fb484
119 Na659bc441d07493b88c014b9f4dd767d schema:issueNumber 9
120 rdf:type schema:PublicationIssue
121 Na69957c53e134fb387177f00ceaa0d6d rdf:first sg:person.010703006647.66
122 rdf:rest N61d814c5f0654d41aaf377dc61842f70
123 Nc45e0880657c4d1dbe23dc237cd8e74d rdf:first sg:person.010742077043.07
124 rdf:rest N641681e8dd06428b922b743f73b48459
125 Nf9274b056db44f1d9ee629d7b4c40509 rdf:first sg:person.011544674761.71
126 rdf:rest N2c3eebea50874659b2630a32795dd7af
127 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
128 schema:name Chemical Sciences
129 rdf:type schema:DefinedTerm
130 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
131 schema:name Physical Chemistry (incl. Structural)
132 rdf:type schema:DefinedTerm
133 sg:grant.8158906 http://pending.schema.org/fundedItem sg:pub.10.1007/s12274-021-3315-1
134 rdf:type schema:MonetaryGrant
135 sg:grant.8905071 http://pending.schema.org/fundedItem sg:pub.10.1007/s12274-021-3315-1
136 rdf:type schema:MonetaryGrant
137 sg:grant.9416742 http://pending.schema.org/fundedItem sg:pub.10.1007/s12274-021-3315-1
138 rdf:type schema:MonetaryGrant
139 sg:journal.1042464 schema:issn 1998-0000
140 1998-0124
141 schema:name Nano Research
142 schema:publisher Springer Nature
143 rdf:type schema:Periodical
144 sg:person.010703006647.66 schema:affiliation grid-institutes:grid.511309.f
145 schema:familyName Zhang
146 schema:givenName Wenqing
147 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010703006647.66
148 rdf:type schema:Person
149 sg:person.010742077043.07 schema:affiliation grid-institutes:grid.511309.f
150 schema:familyName Jiang
151 schema:givenName Yawen
152 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010742077043.07
153 rdf:type schema:Person
154 sg:person.011062530253.12 schema:affiliation grid-institutes:grid.511309.f
155 schema:familyName Yang
156 schema:givenName Jiuzhong
157 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011062530253.12
158 rdf:type schema:Person
159 sg:person.01142173564.33 schema:affiliation grid-institutes:grid.511309.f
160 schema:familyName Qi
161 schema:givenName Zeming
162 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01142173564.33
163 rdf:type schema:Person
164 sg:person.011544674761.71 schema:affiliation grid-institutes:grid.511309.f
165 schema:familyName Low
166 schema:givenName Jingxiang
167 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011544674761.71
168 rdf:type schema:Person
169 sg:person.01166437473.30 schema:affiliation grid-institutes:grid.511309.f
170 schema:familyName Ma
171 schema:givenName Jun
172 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01166437473.30
173 rdf:type schema:Person
174 sg:person.011705527001.22 schema:affiliation grid-institutes:grid.511309.f
175 schema:familyName Liu
176 schema:givenName Hengjie
177 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011705527001.22
178 rdf:type schema:Person
179 sg:person.011740043643.57 schema:affiliation grid-institutes:grid.511309.f
180 schema:familyName Pan
181 schema:givenName Yang
182 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011740043643.57
183 rdf:type schema:Person
184 sg:person.01176070666.37 schema:affiliation grid-institutes:grid.511309.f
185 schema:familyName Song
186 schema:givenName Li
187 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01176070666.37
188 rdf:type schema:Person
189 sg:person.014633702607.27 schema:affiliation grid-institutes:grid.511309.f
190 schema:familyName Bo
191 schema:givenName Yanan
192 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014633702607.27
193 rdf:type schema:Person
194 sg:person.0600113217.27 schema:affiliation grid-institutes:grid.513034.0
195 schema:familyName Xiong
196 schema:givenName Yujie
197 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0600113217.27
198 rdf:type schema:Person
199 sg:person.0640412546.43 schema:affiliation grid-institutes:grid.511309.f
200 schema:familyName Long
201 schema:givenName Ran
202 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0640412546.43
203 rdf:type schema:Person
204 sg:person.0706525746.11 schema:affiliation grid-institutes:grid.440650.3
205 schema:familyName Mao
206 schema:givenName Keke
207 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0706525746.11
208 rdf:type schema:Person
209 sg:pub.10.1007/s12274-019-2600-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1123578985
210 https://doi.org/10.1007/s12274-019-2600-8
211 rdf:type schema:CreativeWork
212 sg:pub.10.1007/s12274-020-2733-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1126625769
213 https://doi.org/10.1007/s12274-020-2733-9
214 rdf:type schema:CreativeWork
215 sg:pub.10.1007/s12274-020-3049-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1130750510
216 https://doi.org/10.1007/s12274-020-3049-5
217 rdf:type schema:CreativeWork
218 sg:pub.10.1038/nchem.1476 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041048634
219 https://doi.org/10.1038/nchem.1476
220 rdf:type schema:CreativeWork
221 sg:pub.10.1038/ncomms12272 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013871943
222 https://doi.org/10.1038/ncomms12272
223 rdf:type schema:CreativeWork
224 sg:pub.10.1038/s41467-018-08120-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1111564630
225 https://doi.org/10.1038/s41467-018-08120-x
226 rdf:type schema:CreativeWork
227 grid-institutes:grid.440650.3 schema:alternateName School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China
228 schema:name School of Energy and Environment Science, Anhui University of Technology, 243032, Maanshan, China
229 rdf:type schema:Organization
230 grid-institutes:grid.511309.f schema:alternateName Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China
231 schema:name Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China
232 rdf:type schema:Organization
233 grid-institutes:grid.513034.0 schema:alternateName Institute of Energy, Hefei Comprehensive National Science Center, 230031, Hefei, China
234 schema:name Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, 230041, Hefei, China
235 Institute of Energy, Hefei Comprehensive National Science Center, 230031, Hefei, China
236 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...