Walnut-inspired microsized porous silicon/graphene core–shell composites for high-performance lithium-ion battery anodes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-12

AUTHORS

Wei Zhai, Qing Ai, Lina Chen, Shiyuan Wei, Deping Li, Lin Zhang, Pengchao Si, Jinkui Feng, Lijie Ci

ABSTRACT

Silicon is considered an exceptionally promising alternative to the most commonly used material, graphite, as an anode for next-generation lithium-ion batteries, as it has high energy density owing to its high theoretical capacity and abundant storage. Here, microsized walnut-like porous silicon/reduced graphene oxide (P-Si/rGO) core–shell composites are successfully prepared via in situ reduction followed by a dealloying process. The composites show specific capacities of more than 2,100 mAh·g−1 at a current density of 1,000 mA·g−1, 1,600 mAh·g−1 at 2,000 mA·g−1, 1,500 mAh·g−1 at 3,000 mA·g−1, 1,200 mAh·g−1 at 4,000 mA·g−1, and 950 mAh·g−1 at 5,000 mA·g−1, and maintain a value of 1,258 mAh·g−1 after 300 cycles at a current density of 1,000 mA·g−1. Their excellent rate performance and cycling stability can be attributed to the unique structural design: 1) The graphene shell dramatically improves the conductivity and stabilizes the solid–electrolyte interface layers; 2) the inner porous structure supplies sufficient space for silicon expansion; 3) the nanostructure of silicon can prevent the pulverization resulting from volume expansion stress. Notably, this in situ reduction method can be applied as a universal formula to coat graphene on almost all types of metals and alloys of various sizes, shapes, and compositions without adding any reagents to afford energy storage materials, graphene-based catalytic materials, graphene-enhanced composites, etc. More... »

PAGES

4274-4283

Journal

TITLE

Nano Research

ISSUE

12

VOLUME

10

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12274-017-1584-5

DOI

http://dx.doi.org/10.1007/s12274-017-1584-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1086156768


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhai", 
        "givenName": "Wei", 
        "id": "sg:person.012621212361.89", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012621212361.89"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ai", 
        "givenName": "Qing", 
        "id": "sg:person.010646631777.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010646631777.76"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chen", 
        "givenName": "Lina", 
        "id": "sg:person.012264030256.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012264030256.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wei", 
        "givenName": "Shiyuan", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Li", 
        "givenName": "Deping", 
        "id": "sg:person.016644673256.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016644673256.87"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Lin", 
        "id": "sg:person.011444212377.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011444212377.51"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Si", 
        "givenName": "Pengchao", 
        "id": "sg:person.0620225260.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0620225260.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Feng", 
        "givenName": "Jinkui", 
        "id": "sg:person.01211517002.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01211517002.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shandong University", 
          "id": "https://www.grid.ac/institutes/grid.27255.37", 
          "name": [
            "SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ci", 
        "givenName": "Lijie", 
        "id": "sg:person.01275404577.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01275404577.73"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/adma.201302877", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000043167"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-016-1106-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001858134", 
          "https://doi.org/10.1007/s12274-016-1106-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-013-0293-y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002565077", 
          "https://doi.org/10.1007/s12274-013-0293-y"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2014.11.094", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004435665"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms5565", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008967033", 
          "https://doi.org/10.1038/ncomms5565"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-010-0081-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010143500", 
          "https://doi.org/10.1007/s12274-010-0081-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c4ta07093c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012813615"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.nanoen.2014.02.011", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018593712"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1149/1.3486161", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018657376"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2006.07.062", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021343429"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s12274-012-0268-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022478683", 
          "https://doi.org/10.1007/s12274-012-0268-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/srep32011", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023631823", 
          "https://doi.org/10.1038/srep32011"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0ee00552e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024220504"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1209150", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026807668"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/smll.201400088", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030471802"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.1802", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030665649", 
          "https://doi.org/10.1038/nchem.1802"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.201401937", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032015495"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2007.411", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032531480", 
          "https://doi.org/10.1038/nnano.2007.411"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn2017167", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033336797"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201503206", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034370105"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/aenm.201300882", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034429842"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200702928", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035114555"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.carbon.2012.10.066", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035144691"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.nanoen.2016.07.031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036201488"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.201501490", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038760951"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl902058c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040185393"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl902058c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040185393"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nenergy.2016.17", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041904886", 
          "https://doi.org/10.1038/nenergy.2016.17"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0378-7753(99)00268-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043436316"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.electacta.2016.05.061", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043722983"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.electacta.2016.05.061", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043722983"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.electacta.2016.05.061", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043722983"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.electacta.2016.05.061", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043722983"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.carbon.2009.12.063", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044219466"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/srep02065", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044722976", 
          "https://doi.org/10.1038/srep02065"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1149/2.092401jes", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046310391"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.carbon.2012.01.074", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048208775"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2014.07.064", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049313221"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp710931h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050705349"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp710931h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050705349"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1849", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052791836", 
          "https://doi.org/10.1038/nmat1849"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b917103g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053515210"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apsusc.2016.10.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053741039"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acsami.5b05970", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055127773"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja301586m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055852102"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja409027s", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055855471"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp072778d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056071999"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp072778d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056071999"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl200412p", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056218497"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl200412p", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056218497"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-12", 
    "datePublishedReg": "2017-12-01", 
    "description": "Silicon is considered an exceptionally promising alternative to the most commonly used material, graphite, as an anode for next-generation lithium-ion batteries, as it has high energy density owing to its high theoretical capacity and abundant storage. Here, microsized walnut-like porous silicon/reduced graphene oxide (P-Si/rGO) core\u2013shell composites are successfully prepared via in situ reduction followed by a dealloying process. The composites show specific capacities of more than 2,100 mAh\u00b7g\u22121 at a current density of 1,000 mA\u00b7g\u22121, 1,600 mAh\u00b7g\u22121 at 2,000 mA\u00b7g\u22121, 1,500 mAh\u00b7g\u22121 at 3,000 mA\u00b7g\u22121, 1,200 mAh\u00b7g\u22121 at 4,000 mA\u00b7g\u22121, and 950 mAh\u00b7g\u22121 at 5,000 mA\u00b7g\u22121, and maintain a value of 1,258 mAh\u00b7g\u22121 after 300 cycles at a current density of 1,000 mA\u00b7g\u22121. Their excellent rate performance and cycling stability can be attributed to the unique structural design: 1) The graphene shell dramatically improves the conductivity and stabilizes the solid\u2013electrolyte interface layers; 2) the inner porous structure supplies sufficient space for silicon expansion; 3) the nanostructure of silicon can prevent the pulverization resulting from volume expansion stress. Notably, this in situ reduction method can be applied as a universal formula to coat graphene on almost all types of metals and alloys of various sizes, shapes, and compositions without adding any reagents to afford energy storage materials, graphene-based catalytic materials, graphene-enhanced composites, etc.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s12274-017-1584-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1042464", 
        "issn": [
          "1998-0124", 
          "1998-0000"
        ], 
        "name": "Nano Research", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "10"
      }
    ], 
    "name": "Walnut-inspired microsized porous silicon/graphene core\u2013shell composites for high-performance lithium-ion battery anodes", 
    "pagination": "4274-4283", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "cc7e72a6c242f38b56218adbd8d0175fc6cebee500774a490cb3dd17e8cc0e9c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s12274-017-1584-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1086156768"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s12274-017-1584-5", 
      "https://app.dimensions.ai/details/publication/pub.1086156768"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:36", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000363_0000000363/records_70031_00000002.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs12274-017-1584-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s12274-017-1584-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s12274-017-1584-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s12274-017-1584-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s12274-017-1584-5'


 

This table displays all metadata directly associated to this object as RDF triples.

256 TRIPLES      21 PREDICATES      70 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s12274-017-1584-5 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author Nd1141d34ee67496c9b4e82a902b84d47
4 schema:citation sg:pub.10.1007/s12274-010-0081-x
5 sg:pub.10.1007/s12274-012-0268-4
6 sg:pub.10.1007/s12274-013-0293-y
7 sg:pub.10.1007/s12274-016-1106-x
8 sg:pub.10.1038/nchem.1802
9 sg:pub.10.1038/ncomms5565
10 sg:pub.10.1038/nenergy.2016.17
11 sg:pub.10.1038/nmat1849
12 sg:pub.10.1038/nnano.2007.411
13 sg:pub.10.1038/srep02065
14 sg:pub.10.1038/srep32011
15 https://doi.org/10.1002/adfm.201503206
16 https://doi.org/10.1002/adma.200702928
17 https://doi.org/10.1002/adma.201302877
18 https://doi.org/10.1002/adma.201401937
19 https://doi.org/10.1002/adma.201501490
20 https://doi.org/10.1002/aenm.201300882
21 https://doi.org/10.1002/smll.201400088
22 https://doi.org/10.1016/j.apsusc.2016.10.008
23 https://doi.org/10.1016/j.carbon.2009.12.063
24 https://doi.org/10.1016/j.carbon.2012.01.074
25 https://doi.org/10.1016/j.carbon.2012.10.066
26 https://doi.org/10.1016/j.electacta.2016.05.061
27 https://doi.org/10.1016/j.jpowsour.2006.07.062
28 https://doi.org/10.1016/j.jpowsour.2014.07.064
29 https://doi.org/10.1016/j.jpowsour.2014.11.094
30 https://doi.org/10.1016/j.nanoen.2014.02.011
31 https://doi.org/10.1016/j.nanoen.2016.07.031
32 https://doi.org/10.1016/s0378-7753(99)00268-2
33 https://doi.org/10.1021/acsami.5b05970
34 https://doi.org/10.1021/ja301586m
35 https://doi.org/10.1021/ja409027s
36 https://doi.org/10.1021/jp072778d
37 https://doi.org/10.1021/jp710931h
38 https://doi.org/10.1021/nl200412p
39 https://doi.org/10.1021/nl902058c
40 https://doi.org/10.1021/nn2017167
41 https://doi.org/10.1039/b917103g
42 https://doi.org/10.1039/c0ee00552e
43 https://doi.org/10.1039/c4ta07093c
44 https://doi.org/10.1126/science.1209150
45 https://doi.org/10.1149/1.3486161
46 https://doi.org/10.1149/2.092401jes
47 schema:datePublished 2017-12
48 schema:datePublishedReg 2017-12-01
49 schema:description Silicon is considered an exceptionally promising alternative to the most commonly used material, graphite, as an anode for next-generation lithium-ion batteries, as it has high energy density owing to its high theoretical capacity and abundant storage. Here, microsized walnut-like porous silicon/reduced graphene oxide (P-Si/rGO) core–shell composites are successfully prepared via in situ reduction followed by a dealloying process. The composites show specific capacities of more than 2,100 mAh·g−1 at a current density of 1,000 mA·g−1, 1,600 mAh·g−1 at 2,000 mA·g−1, 1,500 mAh·g−1 at 3,000 mA·g−1, 1,200 mAh·g−1 at 4,000 mA·g−1, and 950 mAh·g−1 at 5,000 mA·g−1, and maintain a value of 1,258 mAh·g−1 after 300 cycles at a current density of 1,000 mA·g−1. Their excellent rate performance and cycling stability can be attributed to the unique structural design: 1) The graphene shell dramatically improves the conductivity and stabilizes the solid–electrolyte interface layers; 2) the inner porous structure supplies sufficient space for silicon expansion; 3) the nanostructure of silicon can prevent the pulverization resulting from volume expansion stress. Notably, this in situ reduction method can be applied as a universal formula to coat graphene on almost all types of metals and alloys of various sizes, shapes, and compositions without adding any reagents to afford energy storage materials, graphene-based catalytic materials, graphene-enhanced composites, etc.
50 schema:genre research_article
51 schema:inLanguage en
52 schema:isAccessibleForFree false
53 schema:isPartOf N610f5bfe28234d25b5eacc3e815e5b87
54 N88345b47e15d4fe3addc33b08e368d08
55 sg:journal.1042464
56 schema:name Walnut-inspired microsized porous silicon/graphene core–shell composites for high-performance lithium-ion battery anodes
57 schema:pagination 4274-4283
58 schema:productId N4fb4b9eaf5bc4fc39451339879052ec5
59 N98089ee7f3df4863af6ca4da2c5bc300
60 Na9b5535c130148e1af91b8dd195ca2b1
61 schema:sameAs https://app.dimensions.ai/details/publication/pub.1086156768
62 https://doi.org/10.1007/s12274-017-1584-5
63 schema:sdDatePublished 2019-04-11T12:36
64 schema:sdLicense https://scigraph.springernature.com/explorer/license/
65 schema:sdPublisher N750a1ccd6fa44ca6a3d473ecb20b27d2
66 schema:url https://link.springer.com/10.1007%2Fs12274-017-1584-5
67 sgo:license sg:explorer/license/
68 sgo:sdDataset articles
69 rdf:type schema:ScholarlyArticle
70 N0000bc0b599847af8d1d401c437e1dd2 rdf:first sg:person.016644673256.87
71 rdf:rest Nf5c362b373e14b0982ae26b5ec71f447
72 N4fb4b9eaf5bc4fc39451339879052ec5 schema:name readcube_id
73 schema:value cc7e72a6c242f38b56218adbd8d0175fc6cebee500774a490cb3dd17e8cc0e9c
74 rdf:type schema:PropertyValue
75 N610f5bfe28234d25b5eacc3e815e5b87 schema:volumeNumber 10
76 rdf:type schema:PublicationVolume
77 N62c2462854fe4bba81d6bfd98b491ab4 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
78 schema:familyName Wei
79 schema:givenName Shiyuan
80 rdf:type schema:Person
81 N750a1ccd6fa44ca6a3d473ecb20b27d2 schema:name Springer Nature - SN SciGraph project
82 rdf:type schema:Organization
83 N88345b47e15d4fe3addc33b08e368d08 schema:issueNumber 12
84 rdf:type schema:PublicationIssue
85 N98089ee7f3df4863af6ca4da2c5bc300 schema:name dimensions_id
86 schema:value pub.1086156768
87 rdf:type schema:PropertyValue
88 N9c12aa1b04974e88a2454d6ae3c795c8 rdf:first sg:person.010646631777.76
89 rdf:rest Nd8b5137483b44e0b9939dfb5b122e944
90 Na9b5535c130148e1af91b8dd195ca2b1 schema:name doi
91 schema:value 10.1007/s12274-017-1584-5
92 rdf:type schema:PropertyValue
93 Nb645cbdf82db4b58bf9fa16f72c1a999 rdf:first sg:person.01211517002.31
94 rdf:rest Nec904d56499e433d93ae355a12e29615
95 Nd1141d34ee67496c9b4e82a902b84d47 rdf:first sg:person.012621212361.89
96 rdf:rest N9c12aa1b04974e88a2454d6ae3c795c8
97 Nd8b5137483b44e0b9939dfb5b122e944 rdf:first sg:person.012264030256.64
98 rdf:rest Nfd32faa8825f4fec83595a7b7aae93d7
99 Nec904d56499e433d93ae355a12e29615 rdf:first sg:person.01275404577.73
100 rdf:rest rdf:nil
101 Nf58973e834254024a84bcf93cb9ed312 rdf:first sg:person.0620225260.19
102 rdf:rest Nb645cbdf82db4b58bf9fa16f72c1a999
103 Nf5c362b373e14b0982ae26b5ec71f447 rdf:first sg:person.011444212377.51
104 rdf:rest Nf58973e834254024a84bcf93cb9ed312
105 Nfd32faa8825f4fec83595a7b7aae93d7 rdf:first N62c2462854fe4bba81d6bfd98b491ab4
106 rdf:rest N0000bc0b599847af8d1d401c437e1dd2
107 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
108 schema:name Engineering
109 rdf:type schema:DefinedTerm
110 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
111 schema:name Materials Engineering
112 rdf:type schema:DefinedTerm
113 sg:journal.1042464 schema:issn 1998-0000
114 1998-0124
115 schema:name Nano Research
116 rdf:type schema:Periodical
117 sg:person.010646631777.76 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
118 schema:familyName Ai
119 schema:givenName Qing
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010646631777.76
121 rdf:type schema:Person
122 sg:person.011444212377.51 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
123 schema:familyName Zhang
124 schema:givenName Lin
125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011444212377.51
126 rdf:type schema:Person
127 sg:person.01211517002.31 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
128 schema:familyName Feng
129 schema:givenName Jinkui
130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01211517002.31
131 rdf:type schema:Person
132 sg:person.012264030256.64 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
133 schema:familyName Chen
134 schema:givenName Lina
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012264030256.64
136 rdf:type schema:Person
137 sg:person.012621212361.89 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
138 schema:familyName Zhai
139 schema:givenName Wei
140 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012621212361.89
141 rdf:type schema:Person
142 sg:person.01275404577.73 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
143 schema:familyName Ci
144 schema:givenName Lijie
145 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01275404577.73
146 rdf:type schema:Person
147 sg:person.016644673256.87 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
148 schema:familyName Li
149 schema:givenName Deping
150 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016644673256.87
151 rdf:type schema:Person
152 sg:person.0620225260.19 schema:affiliation https://www.grid.ac/institutes/grid.27255.37
153 schema:familyName Si
154 schema:givenName Pengchao
155 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0620225260.19
156 rdf:type schema:Person
157 sg:pub.10.1007/s12274-010-0081-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1010143500
158 https://doi.org/10.1007/s12274-010-0081-x
159 rdf:type schema:CreativeWork
160 sg:pub.10.1007/s12274-012-0268-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022478683
161 https://doi.org/10.1007/s12274-012-0268-4
162 rdf:type schema:CreativeWork
163 sg:pub.10.1007/s12274-013-0293-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1002565077
164 https://doi.org/10.1007/s12274-013-0293-y
165 rdf:type schema:CreativeWork
166 sg:pub.10.1007/s12274-016-1106-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1001858134
167 https://doi.org/10.1007/s12274-016-1106-x
168 rdf:type schema:CreativeWork
169 sg:pub.10.1038/nchem.1802 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030665649
170 https://doi.org/10.1038/nchem.1802
171 rdf:type schema:CreativeWork
172 sg:pub.10.1038/ncomms5565 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008967033
173 https://doi.org/10.1038/ncomms5565
174 rdf:type schema:CreativeWork
175 sg:pub.10.1038/nenergy.2016.17 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041904886
176 https://doi.org/10.1038/nenergy.2016.17
177 rdf:type schema:CreativeWork
178 sg:pub.10.1038/nmat1849 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052791836
179 https://doi.org/10.1038/nmat1849
180 rdf:type schema:CreativeWork
181 sg:pub.10.1038/nnano.2007.411 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032531480
182 https://doi.org/10.1038/nnano.2007.411
183 rdf:type schema:CreativeWork
184 sg:pub.10.1038/srep02065 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044722976
185 https://doi.org/10.1038/srep02065
186 rdf:type schema:CreativeWork
187 sg:pub.10.1038/srep32011 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023631823
188 https://doi.org/10.1038/srep32011
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1002/adfm.201503206 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034370105
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1002/adma.200702928 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035114555
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1002/adma.201302877 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000043167
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1002/adma.201401937 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032015495
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1002/adma.201501490 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038760951
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1002/aenm.201300882 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034429842
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1002/smll.201400088 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030471802
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1016/j.apsusc.2016.10.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053741039
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1016/j.carbon.2009.12.063 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044219466
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1016/j.carbon.2012.01.074 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048208775
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1016/j.carbon.2012.10.066 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035144691
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1016/j.electacta.2016.05.061 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043722983
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1016/j.jpowsour.2006.07.062 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021343429
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1016/j.jpowsour.2014.07.064 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049313221
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1016/j.jpowsour.2014.11.094 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004435665
219 rdf:type schema:CreativeWork
220 https://doi.org/10.1016/j.nanoen.2014.02.011 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018593712
221 rdf:type schema:CreativeWork
222 https://doi.org/10.1016/j.nanoen.2016.07.031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036201488
223 rdf:type schema:CreativeWork
224 https://doi.org/10.1016/s0378-7753(99)00268-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043436316
225 rdf:type schema:CreativeWork
226 https://doi.org/10.1021/acsami.5b05970 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055127773
227 rdf:type schema:CreativeWork
228 https://doi.org/10.1021/ja301586m schema:sameAs https://app.dimensions.ai/details/publication/pub.1055852102
229 rdf:type schema:CreativeWork
230 https://doi.org/10.1021/ja409027s schema:sameAs https://app.dimensions.ai/details/publication/pub.1055855471
231 rdf:type schema:CreativeWork
232 https://doi.org/10.1021/jp072778d schema:sameAs https://app.dimensions.ai/details/publication/pub.1056071999
233 rdf:type schema:CreativeWork
234 https://doi.org/10.1021/jp710931h schema:sameAs https://app.dimensions.ai/details/publication/pub.1050705349
235 rdf:type schema:CreativeWork
236 https://doi.org/10.1021/nl200412p schema:sameAs https://app.dimensions.ai/details/publication/pub.1056218497
237 rdf:type schema:CreativeWork
238 https://doi.org/10.1021/nl902058c schema:sameAs https://app.dimensions.ai/details/publication/pub.1040185393
239 rdf:type schema:CreativeWork
240 https://doi.org/10.1021/nn2017167 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033336797
241 rdf:type schema:CreativeWork
242 https://doi.org/10.1039/b917103g schema:sameAs https://app.dimensions.ai/details/publication/pub.1053515210
243 rdf:type schema:CreativeWork
244 https://doi.org/10.1039/c0ee00552e schema:sameAs https://app.dimensions.ai/details/publication/pub.1024220504
245 rdf:type schema:CreativeWork
246 https://doi.org/10.1039/c4ta07093c schema:sameAs https://app.dimensions.ai/details/publication/pub.1012813615
247 rdf:type schema:CreativeWork
248 https://doi.org/10.1126/science.1209150 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026807668
249 rdf:type schema:CreativeWork
250 https://doi.org/10.1149/1.3486161 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018657376
251 rdf:type schema:CreativeWork
252 https://doi.org/10.1149/2.092401jes schema:sameAs https://app.dimensions.ai/details/publication/pub.1046310391
253 rdf:type schema:CreativeWork
254 https://www.grid.ac/institutes/grid.27255.37 schema:alternateName Shandong University
255 schema:name SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, 250061, Jinan, China
256 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...