A new strategy to synthesize hypercross-linked conjugated polystyrene and its application towards CO2 sorption View Full Text


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Article Info

DATE

2015-07-28

AUTHORS

Rajangam Vinodh, Aziz Abidov, Mei Mei Peng, Cadiam Mohan Babu, Muthiahpillai Palanichamy, Wang Seog Cha, Hyun-Tae Jang

ABSTRACT

Polystyrene is cross-linked to generate micropores for sorption applications. Herein, we report, hypercross-linking of polystyrene in the presence of Friedel-Crafts catalyst, FeCl3 without a cross-linker. For comparison, polystyrene was also hypercross-linked with a cross-linker, dimethoxy methane with the same catalyst. The cross-linking and de-hydrogenation of cross-links to quinonoid formation were confirmed by FT-IR and 13C-NMR techniques. The hyper cross-linked polymers (HCPs) were also characterized by TGA, DRS-UV, SEM, Raman, BET and CO2 sorption techniques. All the HCPs showed a maximum of 5 weight % CO2 sorption at 25 oC and 1 atm. The same polymers could also be applied for the sorption of other air pollutants. More... »

PAGES

1458-1467

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12221-015-5151-y

DOI

http://dx.doi.org/10.1007/s12221-015-5151-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034454496


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