A dysprosium-based metal-organic framework: Synthesis, characterization, crystal structure and interaction with calf thymus-DNA and bovine serum albumin View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

BIPLAB MONDAL, BUDDHADEB SEN, ENNIO ZANGRANDO, PABITRA CHATTOPADHYAY

ABSTRACT

A dysprosium-based metallo-organic framework (MOF) containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6} ⋅ 5.5H2O (1) (H2pyda = pyridine-2,6-dicarboxylic acid) was solvothermally synthesized in ethanolic medium and characterized by physico-chemical and spectroscopic tools. A detailed structural analysis of the solid state structure of 1 by single crystal X-ray diffraction study showed a tricapped trigonal prism geometry for lanthanide in the [Dy(pyda)3]3− fragment. The mode of interaction of 1 with calf thymus-DNA and with protein bovine serum albumin (BSA) was investigated by using absorption and emission spectroscopic tools. The apparent association constant of complex 1 with CT-DNA was deduced from an absorption spectral study (Kb= 4.08 × 104 M−1). Spectral and viscosity measurements indicated a groove-binding mode of 1 with CT-DNA, and from spectroscopic study the formation of a metal complex-BSA adduct was assumed to be the result of the interaction of 1 with BSA. Graphical AbstractA dysprosium-based metallo-organic framework containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6}·5.5H2O (1) was solvothermally synthesized and structurally characterized. The mode of interactions of 1 with ct-DNA and BSA protein was investigated using physico-chemical and spectroscopic tools. A dysprosium-based metallo-organic framework containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6}·5.5H2O (1) was solvothermally synthesized and structurally characterized. The mode of interactions of 1 with ct-DNA and BSA protein was investigated using physico-chemical and spectroscopic tools. More... »

PAGES

1115-1124

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12039-014-0627-7

DOI

http://dx.doi.org/10.1007/s12039-014-0627-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036236236


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Burdwan", 
          "id": "https://www.grid.ac/institutes/grid.411826.8", 
          "name": [
            "Department of Chemistry, Burdwan University, Golapbag, 713104, Burdwan, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "MONDAL", 
        "givenName": "BIPLAB", 
        "id": "sg:person.013316226667.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013316226667.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Burdwan", 
          "id": "https://www.grid.ac/institutes/grid.411826.8", 
          "name": [
            "Department of Chemistry, Burdwan University, Golapbag, 713104, Burdwan, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "SEN", 
        "givenName": "BUDDHADEB", 
        "id": "sg:person.0624045224.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0624045224.57"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Department of Chemical and Pharmaceutical Sciences, Via Licio Giorgieri 1, 34127, Trieste, Italy"
          ], 
          "type": "Organization"
        }, 
        "familyName": "ZANGRANDO", 
        "givenName": "ENNIO", 
        "id": "sg:person.0645171033.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0645171033.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Burdwan", 
          "id": "https://www.grid.ac/institutes/grid.411826.8", 
          "name": [
            "Department of Chemistry, Burdwan University, Golapbag, 713104, Burdwan, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "CHATTOPADHYAY", 
        "givenName": "PABITRA", 
        "id": "sg:person.0706274065.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0706274065.54"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1080/00958972.2012.727208", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002382623"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jinorgbio.2006.05.002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002738669"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.718337", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002757798"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0076-6879(97)76066-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004907170"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11243-011-9512-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006029453", 
          "https://doi.org/10.1007/s11243-011-9512-0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2010.08.005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007834599"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.762975", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011536305"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.inoche.2007.07.015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012324468"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2011.03.027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012513386"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.683485", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013045219"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-8545(00)00241-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013324531"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b305705b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013993187"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.718075", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014295767"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2009.02.040", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014921889"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889899006020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015082962"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b605428e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015994855"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.744002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016177870"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b512638j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017846422"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b406082m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023069865"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b406082m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023069865"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1010-6030(97)00106-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023248053"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2011.08.025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027439165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200300610", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027885687"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.685165", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028702151"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.4236/jbnb.2012.34047", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029368567"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molstruc.2007.02.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030731866"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr8003983", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036704836"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr8003983", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036704836"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.736970", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040316714"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/aoc.1122", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041619341"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2011.649265", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042412214"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2012.713944", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043484155"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jmr.300020404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043767264"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jmr.300020404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043767264"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jssc.2004.07.035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046875874"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2012.12.031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051178769"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-2836(61)80047-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052252272"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr9900432", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053825976"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr9900432", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053825976"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar020022l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055149615"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar020022l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055149615"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/bi00061a015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055159270"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/bi00154a001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055162917"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic048159q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055556514"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic048159q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055556514"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic060550j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055559233"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic060550j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055559233"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00190a046", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055712844"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00268a057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055718985"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01640a067", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055815560"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja036635q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055834014"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja036635q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055834014"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2014-07", 
    "datePublishedReg": "2014-07-01", 
    "description": "A dysprosium-based metallo-organic framework (MOF) containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6} \u22c5 5.5H2O (1) (H2pyda = pyridine-2,6-dicarboxylic acid) was solvothermally synthesized in ethanolic medium and characterized by physico-chemical and spectroscopic tools. A detailed structural analysis of the solid state structure of 1 by single crystal X-ray diffraction study showed a tricapped trigonal prism geometry for lanthanide in the [Dy(pyda)3]3\u2212 fragment. The mode of interaction of 1 with calf thymus-DNA and with protein bovine serum albumin (BSA) was investigated by using absorption and emission spectroscopic tools. The apparent association constant of complex 1 with CT-DNA was deduced from an absorption spectral study (Kb= 4.08 \u00d7 104 M\u22121). Spectral and viscosity measurements indicated a groove-binding mode of 1 with CT-DNA, and from spectroscopic study the formation of a metal complex-BSA adduct was assumed to be the result of the interaction of 1 with BSA. Graphical AbstractA dysprosium-based metallo-organic framework containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6}\u00b75.5H2O (1) was solvothermally synthesized and structurally characterized. The mode of interactions of 1 with ct-DNA and BSA protein was investigated using physico-chemical and spectroscopic tools. A dysprosium-based metallo-organic framework containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6}\u00b75.5H2O (1) was solvothermally synthesized and structurally characterized. The mode of interactions of 1 with ct-DNA and BSA protein was investigated using physico-chemical and spectroscopic tools.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s12039-014-0627-7", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1048512", 
        "issn": [
          "0253-4134", 
          "0973-7103"
        ], 
        "name": "Journal of Chemical Sciences", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "126"
      }
    ], 
    "name": "A dysprosium-based metal-organic framework: Synthesis, characterization, crystal structure and interaction with calf thymus-DNA and bovine serum albumin", 
    "pagination": "1115-1124", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "ac9d26ddd5bafc345888683cfd39ae94d9c97c767af1fab79929f9507fd03643"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s12039-014-0627-7"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1036236236"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s12039-014-0627-7", 
      "https://app.dimensions.ai/details/publication/pub.1036236236"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T16:45", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8669_00000523.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs12039-014-0627-7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s12039-014-0627-7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s12039-014-0627-7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s12039-014-0627-7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s12039-014-0627-7'


 

This table displays all metadata directly associated to this object as RDF triples.

220 TRIPLES      21 PREDICATES      72 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s12039-014-0627-7 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N19dd6d5f4d2e43308fd9810bf8997706
4 schema:citation sg:pub.10.1007/s11243-011-9512-0
5 https://doi.org/10.1002/anie.200300610
6 https://doi.org/10.1002/aoc.1122
7 https://doi.org/10.1002/jmr.300020404
8 https://doi.org/10.1016/j.inoche.2007.07.015
9 https://doi.org/10.1016/j.jinorgbio.2006.05.002
10 https://doi.org/10.1016/j.jssc.2004.07.035
11 https://doi.org/10.1016/j.molstruc.2007.02.020
12 https://doi.org/10.1016/j.poly.2009.02.040
13 https://doi.org/10.1016/j.poly.2010.08.005
14 https://doi.org/10.1016/j.poly.2011.03.027
15 https://doi.org/10.1016/j.poly.2011.08.025
16 https://doi.org/10.1016/j.poly.2012.12.031
17 https://doi.org/10.1016/s0010-8545(00)00241-1
18 https://doi.org/10.1016/s0022-2836(61)80047-8
19 https://doi.org/10.1016/s0076-6879(97)76066-x
20 https://doi.org/10.1016/s1010-6030(97)00106-8
21 https://doi.org/10.1021/ar020022l
22 https://doi.org/10.1021/bi00061a015
23 https://doi.org/10.1021/bi00154a001
24 https://doi.org/10.1021/cr8003983
25 https://doi.org/10.1021/cr9900432
26 https://doi.org/10.1021/ic048159q
27 https://doi.org/10.1021/ic060550j
28 https://doi.org/10.1021/ja00190a046
29 https://doi.org/10.1021/ja00268a057
30 https://doi.org/10.1021/ja01640a067
31 https://doi.org/10.1021/ja036635q
32 https://doi.org/10.1039/b305705b
33 https://doi.org/10.1039/b406082m
34 https://doi.org/10.1039/b512638j
35 https://doi.org/10.1039/b605428e
36 https://doi.org/10.1080/00958972.2011.649265
37 https://doi.org/10.1080/00958972.2012.683485
38 https://doi.org/10.1080/00958972.2012.685165
39 https://doi.org/10.1080/00958972.2012.713944
40 https://doi.org/10.1080/00958972.2012.718075
41 https://doi.org/10.1080/00958972.2012.718337
42 https://doi.org/10.1080/00958972.2012.727208
43 https://doi.org/10.1080/00958972.2012.736970
44 https://doi.org/10.1080/00958972.2012.744002
45 https://doi.org/10.1080/00958972.2012.762975
46 https://doi.org/10.1107/s0021889899006020
47 https://doi.org/10.1107/s0108767307043930
48 https://doi.org/10.4236/jbnb.2012.34047
49 schema:datePublished 2014-07
50 schema:datePublishedReg 2014-07-01
51 schema:description A dysprosium-based metallo-organic framework (MOF) containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6} ⋅ 5.5H2O (1) (H2pyda = pyridine-2,6-dicarboxylic acid) was solvothermally synthesized in ethanolic medium and characterized by physico-chemical and spectroscopic tools. A detailed structural analysis of the solid state structure of 1 by single crystal X-ray diffraction study showed a tricapped trigonal prism geometry for lanthanide in the [Dy(pyda)3]3− fragment. The mode of interaction of 1 with calf thymus-DNA and with protein bovine serum albumin (BSA) was investigated by using absorption and emission spectroscopic tools. The apparent association constant of complex 1 with CT-DNA was deduced from an absorption spectral study (Kb= 4.08 × 104 M−1). Spectral and viscosity measurements indicated a groove-binding mode of 1 with CT-DNA, and from spectroscopic study the formation of a metal complex-BSA adduct was assumed to be the result of the interaction of 1 with BSA. Graphical AbstractA dysprosium-based metallo-organic framework containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6}·5.5H2O (1) was solvothermally synthesized and structurally characterized. The mode of interactions of 1 with ct-DNA and BSA protein was investigated using physico-chemical and spectroscopic tools. A dysprosium-based metallo-organic framework containing calcium ions formulated as {Dy(pyda)3Ca1.5(H2O)6}·5.5H2O (1) was solvothermally synthesized and structurally characterized. The mode of interactions of 1 with ct-DNA and BSA protein was investigated using physico-chemical and spectroscopic tools.
52 schema:genre research_article
53 schema:inLanguage en
54 schema:isAccessibleForFree false
55 schema:isPartOf Nbc6cbd78184b4e25bb4504b10a3a4a81
56 Nedcfd1963a6641cdbf9cd2e5bcd31ca7
57 sg:journal.1048512
58 schema:name A dysprosium-based metal-organic framework: Synthesis, characterization, crystal structure and interaction with calf thymus-DNA and bovine serum albumin
59 schema:pagination 1115-1124
60 schema:productId N3add605bda464cada2fd3f2efdd599b3
61 Na2f833a2de1649dcbb93bcac7a45214c
62 Ne10762bf621b4a71bf786f528914ee52
63 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036236236
64 https://doi.org/10.1007/s12039-014-0627-7
65 schema:sdDatePublished 2019-04-10T16:45
66 schema:sdLicense https://scigraph.springernature.com/explorer/license/
67 schema:sdPublisher N3e99ca398f1340f0ada60a0fcaa3f220
68 schema:url http://link.springer.com/10.1007%2Fs12039-014-0627-7
69 sgo:license sg:explorer/license/
70 sgo:sdDataset articles
71 rdf:type schema:ScholarlyArticle
72 N0f56eed78d484c1796ad2f8dea6d933e schema:name Department of Chemical and Pharmaceutical Sciences, Via Licio Giorgieri 1, 34127, Trieste, Italy
73 rdf:type schema:Organization
74 N19dd6d5f4d2e43308fd9810bf8997706 rdf:first sg:person.013316226667.49
75 rdf:rest Nabf404a64b0f48cc9254f08bef07569a
76 N3add605bda464cada2fd3f2efdd599b3 schema:name doi
77 schema:value 10.1007/s12039-014-0627-7
78 rdf:type schema:PropertyValue
79 N3e99ca398f1340f0ada60a0fcaa3f220 schema:name Springer Nature - SN SciGraph project
80 rdf:type schema:Organization
81 N96c0d0703ce141d88c66ca52ba01a4ce rdf:first sg:person.0706274065.54
82 rdf:rest rdf:nil
83 N9d6ce9eed8b24a88b4e5ab410dbeafc4 rdf:first sg:person.0645171033.45
84 rdf:rest N96c0d0703ce141d88c66ca52ba01a4ce
85 Na2f833a2de1649dcbb93bcac7a45214c schema:name dimensions_id
86 schema:value pub.1036236236
87 rdf:type schema:PropertyValue
88 Nabf404a64b0f48cc9254f08bef07569a rdf:first sg:person.0624045224.57
89 rdf:rest N9d6ce9eed8b24a88b4e5ab410dbeafc4
90 Nbc6cbd78184b4e25bb4504b10a3a4a81 schema:volumeNumber 126
91 rdf:type schema:PublicationVolume
92 Ne10762bf621b4a71bf786f528914ee52 schema:name readcube_id
93 schema:value ac9d26ddd5bafc345888683cfd39ae94d9c97c767af1fab79929f9507fd03643
94 rdf:type schema:PropertyValue
95 Nedcfd1963a6641cdbf9cd2e5bcd31ca7 schema:issueNumber 4
96 rdf:type schema:PublicationIssue
97 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
98 schema:name Chemical Sciences
99 rdf:type schema:DefinedTerm
100 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
101 schema:name Physical Chemistry (incl. Structural)
102 rdf:type schema:DefinedTerm
103 sg:journal.1048512 schema:issn 0253-4134
104 0973-7103
105 schema:name Journal of Chemical Sciences
106 rdf:type schema:Periodical
107 sg:person.013316226667.49 schema:affiliation https://www.grid.ac/institutes/grid.411826.8
108 schema:familyName MONDAL
109 schema:givenName BIPLAB
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013316226667.49
111 rdf:type schema:Person
112 sg:person.0624045224.57 schema:affiliation https://www.grid.ac/institutes/grid.411826.8
113 schema:familyName SEN
114 schema:givenName BUDDHADEB
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0624045224.57
116 rdf:type schema:Person
117 sg:person.0645171033.45 schema:affiliation N0f56eed78d484c1796ad2f8dea6d933e
118 schema:familyName ZANGRANDO
119 schema:givenName ENNIO
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0645171033.45
121 rdf:type schema:Person
122 sg:person.0706274065.54 schema:affiliation https://www.grid.ac/institutes/grid.411826.8
123 schema:familyName CHATTOPADHYAY
124 schema:givenName PABITRA
125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0706274065.54
126 rdf:type schema:Person
127 sg:pub.10.1007/s11243-011-9512-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006029453
128 https://doi.org/10.1007/s11243-011-9512-0
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1002/anie.200300610 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027885687
131 rdf:type schema:CreativeWork
132 https://doi.org/10.1002/aoc.1122 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041619341
133 rdf:type schema:CreativeWork
134 https://doi.org/10.1002/jmr.300020404 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043767264
135 rdf:type schema:CreativeWork
136 https://doi.org/10.1016/j.inoche.2007.07.015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012324468
137 rdf:type schema:CreativeWork
138 https://doi.org/10.1016/j.jinorgbio.2006.05.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002738669
139 rdf:type schema:CreativeWork
140 https://doi.org/10.1016/j.jssc.2004.07.035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046875874
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1016/j.molstruc.2007.02.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030731866
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1016/j.poly.2009.02.040 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014921889
145 rdf:type schema:CreativeWork
146 https://doi.org/10.1016/j.poly.2010.08.005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007834599
147 rdf:type schema:CreativeWork
148 https://doi.org/10.1016/j.poly.2011.03.027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012513386
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1016/j.poly.2011.08.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027439165
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1016/j.poly.2012.12.031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051178769
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1016/s0010-8545(00)00241-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013324531
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1016/s0022-2836(61)80047-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052252272
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1016/s0076-6879(97)76066-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1004907170
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1016/s1010-6030(97)00106-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023248053
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1021/ar020022l schema:sameAs https://app.dimensions.ai/details/publication/pub.1055149615
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1021/bi00061a015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055159270
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1021/bi00154a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055162917
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1021/cr8003983 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036704836
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1021/cr9900432 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053825976
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1021/ic048159q schema:sameAs https://app.dimensions.ai/details/publication/pub.1055556514
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1021/ic060550j schema:sameAs https://app.dimensions.ai/details/publication/pub.1055559233
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1021/ja00190a046 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055712844
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1021/ja00268a057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055718985
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1021/ja01640a067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055815560
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1021/ja036635q schema:sameAs https://app.dimensions.ai/details/publication/pub.1055834014
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1039/b305705b schema:sameAs https://app.dimensions.ai/details/publication/pub.1013993187
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1039/b406082m schema:sameAs https://app.dimensions.ai/details/publication/pub.1023069865
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1039/b512638j schema:sameAs https://app.dimensions.ai/details/publication/pub.1017846422
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1039/b605428e schema:sameAs https://app.dimensions.ai/details/publication/pub.1015994855
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1080/00958972.2011.649265 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042412214
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1080/00958972.2012.683485 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013045219
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1080/00958972.2012.685165 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028702151
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1080/00958972.2012.713944 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043484155
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1080/00958972.2012.718075 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014295767
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1080/00958972.2012.718337 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002757798
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1080/00958972.2012.727208 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002382623
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1080/00958972.2012.736970 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040316714
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1080/00958972.2012.744002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016177870
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1080/00958972.2012.762975 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011536305
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1107/s0021889899006020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015082962
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
215 rdf:type schema:CreativeWork
216 https://doi.org/10.4236/jbnb.2012.34047 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029368567
217 rdf:type schema:CreativeWork
218 https://www.grid.ac/institutes/grid.411826.8 schema:alternateName University of Burdwan
219 schema:name Department of Chemistry, Burdwan University, Golapbag, 713104, Burdwan, India
220 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...