Investigation of hybrid molecular material prepared by ionic liquid and polyoxometalate anion View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2008-11

AUTHORS

T. Rajkumar, G. Ranga Rao

ABSTRACT

A solid hybrid molecular material containing 1-butyl 3-methyl imidazolium cations and Keggin anions of phosphotungstic acid has been synthesized. It is fully characterized by CHN analysis, FTIR, XRD, UV-Vis-NIR DRS, 31P MAS NMR, TGA and SEM. The FTIR spectrum of the compound shows the fingerprint vibrational bands of both Keggin molecular anions and imidazolium cations. The aromatic C-H stretch region (2700–3250 cm−1) of imidazolium cation is split due to the interaction between the ring C-H and bulky Keggin anion. The red-shift in the UV-Vis spectra and the downfield 31P MAS NMR chemical shift also confirm the electrostatic interaction between the ions in the compound. Near IR spectral region (1000–2500 nm) shows the elimination of water in the compound which is hydrophobic. More... »

PAGES

587-594

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12039-008-0089-x

DOI

http://dx.doi.org/10.1007/s12039-008-0089-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042110555


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Indian Institute of Technology Madras, 600 036, Chennai, India", 
          "id": "http://www.grid.ac/institutes/grid.417969.4", 
          "name": [
            "Department of Chemistry, Indian Institute of Technology Madras, 600 036, Chennai, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rajkumar", 
        "givenName": "T.", 
        "id": "sg:person.015765546475.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015765546475.86"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Indian Institute of Technology Madras, 600 036, Chennai, India", 
          "id": "http://www.grid.ac/institutes/grid.417969.4", 
          "name": [
            "Department of Chemistry, Indian Institute of Technology Madras, 600 036, Chennai, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ranga Rao", 
        "givenName": "G.", 
        "id": "sg:person.016210743620.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016210743620.64"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s10562-007-9279-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009154118", 
          "https://doi.org/10.1007/s10562-007-9279-2"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-11", 
    "datePublishedReg": "2008-11-01", 
    "description": "A solid hybrid molecular material containing 1-butyl 3-methyl imidazolium cations and Keggin anions of phosphotungstic acid has been synthesized. It is fully characterized by CHN analysis, FTIR, XRD, UV-Vis-NIR DRS, 31P MAS NMR, TGA and SEM. The FTIR spectrum of the compound shows the fingerprint vibrational bands of both Keggin molecular anions and imidazolium cations. The aromatic C-H stretch region (2700\u20133250 cm\u22121) of imidazolium cation is split due to the interaction between the ring C-H and bulky Keggin anion. The red-shift in the UV-Vis spectra and the downfield 31P MAS NMR chemical shift also confirm the electrostatic interaction between the ions in the compound. Near IR spectral region (1000\u20132500 nm) shows the elimination of water in the compound which is hydrophobic.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s12039-008-0089-x", 
    "inLanguage": "en", 
    "isAccessibleForFree": true, 
    "isPartOf": [
      {
        "id": "sg:journal.1048512", 
        "issn": [
          "0253-4134", 
          "0973-7103"
        ], 
        "name": "Journal of Chemical Sciences", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "120"
      }
    ], 
    "keywords": [
      "hybrid molecular materials", 
      "imidazolium cation", 
      "Keggin anions", 
      "molecular materials", 
      "MAS NMR chemical shifts", 
      "UV-Vis spectra", 
      "fingerprint vibrational bands", 
      "NMR chemical shifts", 
      "UV-Vis", 
      "elimination of water", 
      "NIR DRS", 
      "polyoxometalate anions", 
      "ionic liquids", 
      "CHN analysis", 
      "MAS NMR", 
      "molecular anions", 
      "chemical shifts", 
      "FTIR spectra", 
      "stretch region", 
      "electrostatic interactions", 
      "vibrational bands", 
      "IR spectral region", 
      "phosphotungstic acid", 
      "anions", 
      "cations", 
      "compounds", 
      "ring C", 
      "spectral region", 
      "FTIR", 
      "spectra", 
      "TGA", 
      "XRD", 
      "NMR", 
      "DRS", 
      "materials", 
      "ions", 
      "SEM", 
      "liquid", 
      "interaction", 
      "water", 
      "acid", 
      "band", 
      "shift", 
      "elimination", 
      "investigation", 
      "analysis", 
      "region", 
      "solid hybrid molecular material", 
      "Keggin molecular anions", 
      "downfield 31P MAS NMR chemical shift"
    ], 
    "name": "Investigation of hybrid molecular material prepared by ionic liquid and polyoxometalate anion", 
    "pagination": "587-594", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1042110555"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s12039-008-0089-x"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s12039-008-0089-x", 
      "https://app.dimensions.ai/details/publication/pub.1042110555"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:10", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_460.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s12039-008-0089-x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0089-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0089-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0089-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0089-x'


 

This table displays all metadata directly associated to this object as RDF triples.

119 TRIPLES      22 PREDICATES      77 URIs      68 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s12039-008-0089-x schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N6c2e786a0c314a13bd632423a4b84819
4 schema:citation sg:pub.10.1007/s10562-007-9279-2
5 schema:datePublished 2008-11
6 schema:datePublishedReg 2008-11-01
7 schema:description A solid hybrid molecular material containing 1-butyl 3-methyl imidazolium cations and Keggin anions of phosphotungstic acid has been synthesized. It is fully characterized by CHN analysis, FTIR, XRD, UV-Vis-NIR DRS, 31P MAS NMR, TGA and SEM. The FTIR spectrum of the compound shows the fingerprint vibrational bands of both Keggin molecular anions and imidazolium cations. The aromatic C-H stretch region (2700–3250 cm−1) of imidazolium cation is split due to the interaction between the ring C-H and bulky Keggin anion. The red-shift in the UV-Vis spectra and the downfield 31P MAS NMR chemical shift also confirm the electrostatic interaction between the ions in the compound. Near IR spectral region (1000–2500 nm) shows the elimination of water in the compound which is hydrophobic.
8 schema:genre article
9 schema:inLanguage en
10 schema:isAccessibleForFree true
11 schema:isPartOf N654453fe4c91405283fb7398e9c2ea09
12 Ne0346ba052dc48bf8985eeb8ade77899
13 sg:journal.1048512
14 schema:keywords CHN analysis
15 DRS
16 FTIR
17 FTIR spectra
18 IR spectral region
19 Keggin anions
20 Keggin molecular anions
21 MAS NMR
22 MAS NMR chemical shifts
23 NIR DRS
24 NMR
25 NMR chemical shifts
26 SEM
27 TGA
28 UV-Vis
29 UV-Vis spectra
30 XRD
31 acid
32 analysis
33 anions
34 band
35 cations
36 chemical shifts
37 compounds
38 downfield 31P MAS NMR chemical shift
39 electrostatic interactions
40 elimination
41 elimination of water
42 fingerprint vibrational bands
43 hybrid molecular materials
44 imidazolium cation
45 interaction
46 investigation
47 ionic liquids
48 ions
49 liquid
50 materials
51 molecular anions
52 molecular materials
53 phosphotungstic acid
54 polyoxometalate anions
55 region
56 ring C
57 shift
58 solid hybrid molecular material
59 spectra
60 spectral region
61 stretch region
62 vibrational bands
63 water
64 schema:name Investigation of hybrid molecular material prepared by ionic liquid and polyoxometalate anion
65 schema:pagination 587-594
66 schema:productId N480e29e1cb6646b7ae46d24e30ba0cd0
67 Nb364e89903df4779982ffc2a07e1fb85
68 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042110555
69 https://doi.org/10.1007/s12039-008-0089-x
70 schema:sdDatePublished 2021-11-01T18:10
71 schema:sdLicense https://scigraph.springernature.com/explorer/license/
72 schema:sdPublisher N2af9ac6994a443479be9f61ed8196d3a
73 schema:url https://doi.org/10.1007/s12039-008-0089-x
74 sgo:license sg:explorer/license/
75 sgo:sdDataset articles
76 rdf:type schema:ScholarlyArticle
77 N2af9ac6994a443479be9f61ed8196d3a schema:name Springer Nature - SN SciGraph project
78 rdf:type schema:Organization
79 N4536986e56e94940a11353b420fede06 rdf:first sg:person.016210743620.64
80 rdf:rest rdf:nil
81 N480e29e1cb6646b7ae46d24e30ba0cd0 schema:name doi
82 schema:value 10.1007/s12039-008-0089-x
83 rdf:type schema:PropertyValue
84 N654453fe4c91405283fb7398e9c2ea09 schema:volumeNumber 120
85 rdf:type schema:PublicationVolume
86 N6c2e786a0c314a13bd632423a4b84819 rdf:first sg:person.015765546475.86
87 rdf:rest N4536986e56e94940a11353b420fede06
88 Nb364e89903df4779982ffc2a07e1fb85 schema:name dimensions_id
89 schema:value pub.1042110555
90 rdf:type schema:PropertyValue
91 Ne0346ba052dc48bf8985eeb8ade77899 schema:issueNumber 6
92 rdf:type schema:PublicationIssue
93 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
94 schema:name Chemical Sciences
95 rdf:type schema:DefinedTerm
96 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
97 schema:name Physical Chemistry (incl. Structural)
98 rdf:type schema:DefinedTerm
99 sg:journal.1048512 schema:issn 0253-4134
100 0973-7103
101 schema:name Journal of Chemical Sciences
102 schema:publisher Springer Nature
103 rdf:type schema:Periodical
104 sg:person.015765546475.86 schema:affiliation grid-institutes:grid.417969.4
105 schema:familyName Rajkumar
106 schema:givenName T.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015765546475.86
108 rdf:type schema:Person
109 sg:person.016210743620.64 schema:affiliation grid-institutes:grid.417969.4
110 schema:familyName Ranga Rao
111 schema:givenName G.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016210743620.64
113 rdf:type schema:Person
114 sg:pub.10.1007/s10562-007-9279-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009154118
115 https://doi.org/10.1007/s10562-007-9279-2
116 rdf:type schema:CreativeWork
117 grid-institutes:grid.417969.4 schema:alternateName Department of Chemistry, Indian Institute of Technology Madras, 600 036, Chennai, India
118 schema:name Department of Chemistry, Indian Institute of Technology Madras, 600 036, Chennai, India
119 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...