Oximato bridged RhIII2MII and RhIIIMI species (MII = Mn, Co, Ni; MI = Cu, Ag) View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2008-01

AUTHORS

Indranil Bhattacharyya, Sanjib Ganguly, Bikash Kumar Panda, Animesh Chakravorty

ABSTRACT

The reaction of [RhCl2(HPhL)(PhL)] with MII(ClO4)2·6H2O in presence of alkali has furnished trinuclear [RhCl2(PhL)2]2M(H2O)2·H2O (HPhL is phenylazobenzaldoxime; M = Mn, Co, Ni). A similar reaction with MI(PPh3)2NO3 yielded binuclear [RhCl2(PhL)2]M(PPh3)2 (M = Cu, Ag). In these molecules the oximato group acts as a bridge between RhIII (bonded at N) and MII or MI (bonded at O). In structurally characterized [RhIIICl2(PhL)2]2Mn(H2O)2.H2O the centrosymmetric distorted octahedral MnO6 coordination sphere is spanned by four oximato oxygen atoms and two water molecules lying in trans position. In the lattice the neighbouring molecules are held together by H2O⋯H2O⋯H2O hydrogen bonds generating infinite zigzag chains. The manganese atoms lie parallel to the C-axis, the shortest Mn...Mn distance being 7.992 Å. Magnetic exchange interactions if any are small as seen in room temperature magnetic moments. The manganese system displays a strong EPR signal near g = 2.00. In the complex [RhCl2(PhL)2]Cu(PPh3)2 the copper atom is coordinated to two oximato oxygen atoms and the two phosphorus atoms in a distorted tetrahedral geometry. The softness of the phosphine ligand is believed to sustain the stable coordination of hard oximato oxygen to soft CuI. The coordination sphere of the RhIII atom in both the complexes is uniformly trans-RhN4Cl2. More... »

PAGES

87-93

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s12039-008-0011-6

DOI

http://dx.doi.org/10.1007/s12039-008-0011-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013327485


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bhattacharyya", 
        "givenName": "Indranil", 
        "id": "sg:person.011150434125.58", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011150434125.58"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ganguly", 
        "givenName": "Sanjib", 
        "id": "sg:person.01072454365.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072454365.62"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Panda", 
        "givenName": "Bikash Kumar", 
        "id": "sg:person.07575671167.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07575671167.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India", 
          "id": "http://www.grid.ac/institutes/grid.417929.0", 
          "name": [
            "Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chakravorty", 
        "givenName": "Animesh", 
        "id": "sg:person.012503014436.35", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012503014436.35"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2008-01", 
    "datePublishedReg": "2008-01-01", 
    "description": "The reaction of [RhCl2(HPhL)(PhL)] with MII(ClO4)2\u00b76H2O in presence of alkali has furnished trinuclear [RhCl2(PhL)2]2M(H2O)2\u00b7H2O (HPhL is phenylazobenzaldoxime; M = Mn, Co, Ni). A similar reaction with MI(PPh3)2NO3 yielded binuclear [RhCl2(PhL)2]M(PPh3)2 (M = Cu, Ag). In these molecules the oximato group acts as a bridge between RhIII (bonded at N) and MII or MI (bonded at O). In structurally characterized [RhIIICl2(PhL)2]2Mn(H2O)2.H2O the centrosymmetric distorted octahedral MnO6 coordination sphere is spanned by four oximato oxygen atoms and two water molecules lying in trans position. In the lattice the neighbouring molecules are held together by H2O\u22efH2O\u22efH2O hydrogen bonds generating infinite zigzag chains. The manganese atoms lie parallel to the C-axis, the shortest Mn...Mn distance being 7.992 \u00c5. Magnetic exchange interactions if any are small as seen in room temperature magnetic moments. The manganese system displays a strong EPR signal near g = 2.00. In the complex [RhCl2(PhL)2]Cu(PPh3)2 the copper atom is coordinated to two oximato oxygen atoms and the two phosphorus atoms in a distorted tetrahedral geometry. The softness of the phosphine ligand is believed to sustain the stable coordination of hard oximato oxygen to soft CuI. The coordination sphere of the RhIII atom in both the complexes is uniformly trans-RhN4Cl2.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s12039-008-0011-6", 
    "inLanguage": "en", 
    "isAccessibleForFree": true, 
    "isPartOf": [
      {
        "id": "sg:journal.1048512", 
        "issn": [
          "0253-4134", 
          "0973-7103"
        ], 
        "name": "Journal of Chemical Sciences", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "120"
      }
    ], 
    "keywords": [
      "complexes", 
      "molecules", 
      "species", 
      "EPR signal", 
      "oximato oxygen atoms", 
      "ligands", 
      "hydrogen bonds", 
      "interaction", 
      "trans", 
      "water molecules", 
      "MII", 
      "coordination sphere", 
      "oxygen atoms", 
      "chain", 
      "signals", 
      "room temperature magnetic moments", 
      "presence", 
      "infinite zigzag chains", 
      "strong EPR signal", 
      "presence of alkali", 
      "oximato group", 
      "tetrahedral geometry", 
      "trans position", 
      "copper atoms", 
      "phosphine ligands", 
      "oximato oxygen", 
      "zigzag chains", 
      "short Mn", 
      "magnetic exchange interactions", 
      "manganese system", 
      "phosphorus atom", 
      "reaction", 
      "similar reaction", 
      "manganese atoms", 
      "axis", 
      "stable coordination", 
      "oxygen", 
      "atoms", 
      "bonds", 
      "distance", 
      "bridge", 
      "position", 
      "coordination", 
      "MI", 
      "Mn", 
      "group", 
      "exchange interaction", 
      "system", 
      "trinuclear", 
      "RhIII", 
      "magnetic moment", 
      "oximato", 
      "centrosymmetric", 
      "CuI.", 
      "alkali", 
      "sphere", 
      "softness", 
      "lattice", 
      "geometry", 
      "moment"
    ], 
    "name": "Oximato bridged RhIII2MII and RhIIIMI species (MII = Mn, Co, Ni; MI = Cu, Ag)", 
    "pagination": "87-93", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1013327485"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s12039-008-0011-6"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s12039-008-0011-6", 
      "https://app.dimensions.ai/details/publication/pub.1013327485"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:25", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_468.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s12039-008-0011-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0011-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0011-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0011-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s12039-008-0011-6'


 

This table displays all metadata directly associated to this object as RDF triples.

139 TRIPLES      21 PREDICATES      86 URIs      78 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s12039-008-0011-6 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N79870e3b91cd4830852c0c3888f6f30b
4 schema:datePublished 2008-01
5 schema:datePublishedReg 2008-01-01
6 schema:description The reaction of [RhCl2(HPhL)(PhL)] with MII(ClO4)2·6H2O in presence of alkali has furnished trinuclear [RhCl2(PhL)2]2M(H2O)2·H2O (HPhL is phenylazobenzaldoxime; M = Mn, Co, Ni). A similar reaction with MI(PPh3)2NO3 yielded binuclear [RhCl2(PhL)2]M(PPh3)2 (M = Cu, Ag). In these molecules the oximato group acts as a bridge between RhIII (bonded at N) and MII or MI (bonded at O). In structurally characterized [RhIIICl2(PhL)2]2Mn(H2O)2.H2O the centrosymmetric distorted octahedral MnO6 coordination sphere is spanned by four oximato oxygen atoms and two water molecules lying in trans position. In the lattice the neighbouring molecules are held together by H2O⋯H2O⋯H2O hydrogen bonds generating infinite zigzag chains. The manganese atoms lie parallel to the C-axis, the shortest Mn...Mn distance being 7.992 Å. Magnetic exchange interactions if any are small as seen in room temperature magnetic moments. The manganese system displays a strong EPR signal near g = 2.00. In the complex [RhCl2(PhL)2]Cu(PPh3)2 the copper atom is coordinated to two oximato oxygen atoms and the two phosphorus atoms in a distorted tetrahedral geometry. The softness of the phosphine ligand is believed to sustain the stable coordination of hard oximato oxygen to soft CuI. The coordination sphere of the RhIII atom in both the complexes is uniformly trans-RhN4Cl2.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree true
10 schema:isPartOf N57eae939f8dc4db09794694ea64f6ae4
11 N701db41a208e4d62975c169d1a1f534e
12 sg:journal.1048512
13 schema:keywords CuI.
14 EPR signal
15 MI
16 MII
17 Mn
18 RhIII
19 alkali
20 atoms
21 axis
22 bonds
23 bridge
24 centrosymmetric
25 chain
26 complexes
27 coordination
28 coordination sphere
29 copper atoms
30 distance
31 exchange interaction
32 geometry
33 group
34 hydrogen bonds
35 infinite zigzag chains
36 interaction
37 lattice
38 ligands
39 magnetic exchange interactions
40 magnetic moment
41 manganese atoms
42 manganese system
43 molecules
44 moment
45 oximato
46 oximato group
47 oximato oxygen
48 oximato oxygen atoms
49 oxygen
50 oxygen atoms
51 phosphine ligands
52 phosphorus atom
53 position
54 presence
55 presence of alkali
56 reaction
57 room temperature magnetic moments
58 short Mn
59 signals
60 similar reaction
61 softness
62 species
63 sphere
64 stable coordination
65 strong EPR signal
66 system
67 tetrahedral geometry
68 trans
69 trans position
70 trinuclear
71 water molecules
72 zigzag chains
73 schema:name Oximato bridged RhIII2MII and RhIIIMI species (MII = Mn, Co, Ni; MI = Cu, Ag)
74 schema:pagination 87-93
75 schema:productId N0d2ec353d7a749afb92ec49a9bf42dac
76 N31ba413fb3ec4a85b446bf690af25f39
77 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013327485
78 https://doi.org/10.1007/s12039-008-0011-6
79 schema:sdDatePublished 2022-05-20T07:25
80 schema:sdLicense https://scigraph.springernature.com/explorer/license/
81 schema:sdPublisher Na5f2d1d23b14451ea846c041de402cf9
82 schema:url https://doi.org/10.1007/s12039-008-0011-6
83 sgo:license sg:explorer/license/
84 sgo:sdDataset articles
85 rdf:type schema:ScholarlyArticle
86 N0d2ec353d7a749afb92ec49a9bf42dac schema:name dimensions_id
87 schema:value pub.1013327485
88 rdf:type schema:PropertyValue
89 N1699f6dbe480453396ad0d26d4681cc2 rdf:first sg:person.01072454365.62
90 rdf:rest N2d391be672c54cc9ab3bb87153966ec5
91 N2d391be672c54cc9ab3bb87153966ec5 rdf:first sg:person.07575671167.37
92 rdf:rest N525df530047f487a8f83a3979b17f522
93 N31ba413fb3ec4a85b446bf690af25f39 schema:name doi
94 schema:value 10.1007/s12039-008-0011-6
95 rdf:type schema:PropertyValue
96 N525df530047f487a8f83a3979b17f522 rdf:first sg:person.012503014436.35
97 rdf:rest rdf:nil
98 N57eae939f8dc4db09794694ea64f6ae4 schema:issueNumber 1
99 rdf:type schema:PublicationIssue
100 N701db41a208e4d62975c169d1a1f534e schema:volumeNumber 120
101 rdf:type schema:PublicationVolume
102 N79870e3b91cd4830852c0c3888f6f30b rdf:first sg:person.011150434125.58
103 rdf:rest N1699f6dbe480453396ad0d26d4681cc2
104 Na5f2d1d23b14451ea846c041de402cf9 schema:name Springer Nature - SN SciGraph project
105 rdf:type schema:Organization
106 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
107 schema:name Chemical Sciences
108 rdf:type schema:DefinedTerm
109 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
110 schema:name Inorganic Chemistry
111 rdf:type schema:DefinedTerm
112 sg:journal.1048512 schema:issn 0253-4134
113 0973-7103
114 schema:name Journal of Chemical Sciences
115 schema:publisher Springer Nature
116 rdf:type schema:Periodical
117 sg:person.01072454365.62 schema:affiliation grid-institutes:grid.417929.0
118 schema:familyName Ganguly
119 schema:givenName Sanjib
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072454365.62
121 rdf:type schema:Person
122 sg:person.011150434125.58 schema:affiliation grid-institutes:grid.417929.0
123 schema:familyName Bhattacharyya
124 schema:givenName Indranil
125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011150434125.58
126 rdf:type schema:Person
127 sg:person.012503014436.35 schema:affiliation grid-institutes:grid.417929.0
128 schema:familyName Chakravorty
129 schema:givenName Animesh
130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012503014436.35
131 rdf:type schema:Person
132 sg:person.07575671167.37 schema:affiliation grid-institutes:grid.417929.0
133 schema:familyName Panda
134 schema:givenName Bikash Kumar
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07575671167.37
136 rdf:type schema:Person
137 grid-institutes:grid.417929.0 schema:alternateName Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India
138 schema:name Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032, Kolkata, India
139 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...