Spectroscopic characterization of Er3+ doped lead zinc phosphate glass via Judd–Ofelt analysis View Full Text


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Article Info

DATE

2019-06

AUTHORS

Pabitra Mandal, Swarup Chowdhury, Subhankar Ghosh

ABSTRACT

Lead zinc phosphate (LZP) glass doped with 0.6% Er3+ is prepared by a conventional melt quenching technique. Judd–Ofelt (JO) analysis is carried out with an absorption spectrum of the as-prepared glass generating the set of JO parameters: Ω2=2.75×10-20cm-2, Ω4=2.71×10-20cm-2 and Ω6=0.44×10-20cm-2. The magnitude of the spectroscopic quality factor (χp) defined by Ω4/Ω6 obtained in our sample turns out to be 6.16 which is 2–10 times larger than that of other Er3+ doped glasses. The lifetime of 4I13/2 and 4I11/2 levels estimated via the JO parameters is found to provide superior values of 7.25 and 5.51 ms, respectively. The elevated value of Ω4/Ω6 along with the estimated 100% luminescence branching ratio of 4I13/2→4I15/2 transition implies that Er3+ doped LZP can be a promising material as a laser active medium. More... »

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99

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http://scigraph.springernature.com/pub.10.1007/s12034-019-1806-4

DOI

http://dx.doi.org/10.1007/s12034-019-1806-4

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